Free anion-radicals in the electrochemical reduction of derivatives of 1,4-dihydro-3,5-dinitropyridine

1996 ◽  
Vol 32 (7) ◽  
pp. 800-806
Author(s):  
Ya. Stradyn' ◽  
L. Baumane ◽  
R. Gavars ◽  
B. Vigante ◽  
G. Duburs
Keyword(s):  
Electrochemical Reduction ◽  
Derivatives Of ◽  
Anion Radicals

Electrochemical reduction of para-substituted 2-acyl-5-phenylfuranes in dimethylformamide

1981 ◽  
Vol 46 (2) ◽  
pp. 498-502 ◽  
Author(s):  
Jozef Černák ◽  
František Tomanovič ◽  
Andrej Staško ◽  
Anna Fedosyevna Oleinikova ◽  
Jaroslav Kováč
Keyword(s):  
Electrochemical Reduction ◽  
Unpaired Electron ◽  
Anion Radical ◽  
Electron Wave ◽  
Epr Method ◽  
Electron Center ◽  
Nitrogen Nucleus ◽  
Nitro Derivatives ◽  
Stable Anion ◽  
Derivatives Of

para Substituted chloro, bromo, and nitro derivatives of 2-acyl-5-phenylfurane are reduced polarographically in a one-electron wave to the corresponding anion radicals, which were studied by the EPR method. The reduction of nitro derivatives, studied by the Kalousek switch, is reversible and leads to a stable anion radical with an unpaired electron center on the nitrogen nucleus; the reduction of the halogen derivatives is only partly reversible and leads to unstable ketyl radicals. The bromo derivatives give polarographic maxima typical for concurrent reactions.

Free radicals in the electrochemical reduction of derivatives of 3,5-dinitro-1,2-dihydropyridine

1997 ◽  
Vol 33 (2) ◽  
pp. 184-189 ◽  
Author(s):  
Ya. Stradyn' ◽  
R. Gavar ◽  
L. Baumane ◽  
B. Vigante ◽  
G. Dubur
Keyword(s):  
Free Radicals ◽  
Electrochemical Reduction ◽  
Derivatives Of

Anion radicals derived from various derivatives of m-dinitroben zene

1974 ◽  
Vol 14 (4) ◽  
pp. 678-681 ◽  
Author(s):  
V. M. Kazakova ◽  
V. B. Piskov
Keyword(s):  
Derivatives Of ◽  
Anion Radicals

Free radicals in the electrochemical reduction of certain mononitro and dinitro derivatives of pyridine

1993 ◽  
Vol 29 (8) ◽  
pp. 918-925
Author(s):  
Ya. Stradyn' ◽  
R. Gavars ◽  
L. Baumane ◽  
B. Vigante ◽  
G. Duburs
Keyword(s):  
Free Radicals ◽  
Electrochemical Reduction ◽  
Derivatives Of

Electrochemical reduction of derivatives of 2,4-dinitrobenzene in acetone and dimethylformamide

1973 ◽  
Vol 7 (2) ◽  
pp. 213-216
Author(s):  
S. S. Gitis ◽  
I. M. Sosonkin ◽  
A. Ya. Kaminskii
Keyword(s):  
Electrochemical Reduction ◽  
Derivatives Of
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