Modernized ammonia synthesis column PMK-320-6 by-pass valve

1966 ◽  
Vol 2 (3) ◽  
pp. 220-220
Author(s):  
V. P. Klimov
1981 ◽  
Vol 17 (4) ◽  
pp. 173-174
Author(s):  
Yu. G. Obolentsev ◽  
L. L. Tovazhnyanskii ◽  
A. T. Posmyk ◽  
Ya. S. Teplitskii ◽  
R. R. Khabibullin ◽  
...  

2000 ◽  
Vol 36 (3) ◽  
pp. 422-424
Author(s):  
A. N. Kuzyukov ◽  
V. A. Borisenko ◽  
Yu. Ya. Nikhaenko ◽  
A. V. Tugolukov

Energies ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2847 ◽  
Author(s):  
Leonid Tovazhnyanskyy ◽  
Jiří Jaromir Klemeš ◽  
Petro Kapustenko ◽  
Olga Arsenyeva ◽  
Olexandr Perevertaylenko ◽  
...  

The production of ammonia, consuming up to 5% of natural gas global production, accounts for about 2% of world energy. Worldwide, the Haber–Bosch process is the mainly used method of ammonia catalytic synthesis, involving temperatures up to 600 °C and pressures up to 32 MPa. In this paper, the results of the development and study of the special welded construction of plate heat exchanger (WPHE) for a column of ammonia synthesis are presented. The heat transfer and hydraulic performance of developed WPHE are investigated on a one-pass model in laboratory conditions. An equation for the relation between heat transfer effectiveness and the number of heat transfer units is proposed. A mathematical model of multi-pass WPHE is developed using these results. The validity of this model is confirmed by results of industrial tests performed with the prototype WPHE installed in operating column of ammonia synthesis at temperatures about 500 °C and pressure about 32 MPa. The tests confirmed the reliability of WPHE and its efficiency compared to a tubular heat exchanger. A method of optimal design of WPHE that allows finding the optimal height of corrugations and the number of passes in WPHE for specified conditions of operation is developed.


1982 ◽  
Vol 18 (5) ◽  
pp. 204-207
Author(s):  
Yu. G. Obolentsev ◽  
O. A. Korobchanskii ◽  
L. L. Tovazhnyanskii ◽  
M. S. Chus' ◽  
Ya. S. Teplitskii

2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>


2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>


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