Electro-oxidation rate ofp-tert-butyltoluene in a bipolar packed-bed electrode cell

1987 ◽  
Vol 17 (6) ◽  
pp. 1213-1222 ◽  
Author(s):  
Hark Joon Kim ◽  
Katsuki Kusakabe ◽  
Satoko Hokazono ◽  
Shigeharu Morooka ◽  
Yasuo Kato
Keyword(s):  
Oxidation Rate ◽  
Packed Bed ◽  
Packed Bed Electrode ◽  
Electrode Cell ◽  
Electro Oxidation

A new strategy for determination of current efficiency during electro-oxidation of aromatic compounds in a packed-bed system

2011 ◽  
Vol 63 (11) ◽  
pp. 2685-2691 ◽  
Author(s):  
Lizhang Wang ◽  
Yuemin Zhao ◽  
Qingyu Gao ◽  
Cheng Qian ◽  
Yunlong Hu
Keyword(s):  
Current Efficiency ◽  
Aromatic Compounds ◽  
Oxygen Demand ◽  
Packed Bed ◽  
Electrode System ◽  
Electrode Distance ◽  
Faradaic Current ◽  
Packed Bed Electrode ◽  
New Strategy ◽  
Electro Oxidation

The electro-oxidation of aromatic compounds in 4,4′-diaminostilbene-2,2′-disulfonic (DSD) acid wastewater on IrO2–Ta2O5/Ti anodes was studied. The current efficiency was evaluated in terms of chemical oxygen demand (COD) by introducing a new factor, the fraction of the Faradaic current to the total cell current (β) through the network analysis of packed bed electrode system (PBEs). Experimental results using an up-flow PBEs at current intensities ranging from 5 to 16 A m−2, flow rates ranging from 20 to 80 L h−1 and inter-electrode distance of 5 to 50 cm are in good agreement with the proposed equation. In addition, lower current density, increasing flow rate and larger inter-electrode distance are beneficial to enhance the current efficiency.

scholarly journals Equivalent resistances for current pathways in a bipolar packed-bed electrode cell.

1986 ◽  
Vol 19 (1) ◽  
pp. 43-47 ◽  
Author(s):  
KATSUKI KUSAKABE ◽  
SHIGEHARU MOROOKA ◽  
YASUO KATO
Keyword(s):  
Packed Bed ◽  
Packed Bed Electrode ◽  
Electrode Cell

Kinetics for electro-oxidation of organic pollutants by using a packed-bed electrode reactor (PBER)

2016 ◽  
Vol 284 ◽  
pp. 240-246 ◽  
Author(s):  
Lizhang Wang ◽  
Bo Wu ◽  
Peng Li ◽  
Bo Zhang ◽  
N. Balasubramanian ◽  
...  
Keyword(s):  
Organic Pollutants ◽  
Packed Bed ◽  
Packed Bed Electrode ◽  
Electro Oxidation

Electrochemical capacitance behavior of a packed bed electrochemical reactor toward phenol electro-oxidation

2014 ◽  
Vol 45 (2) ◽  
pp. 177-184 ◽  
Author(s):  
Peng Li ◽  
Yuemin Zhao ◽  
Lizhang Wang ◽  
Binbin Ding ◽  
Bo Zhang ◽  
...  
Keyword(s):  
Packed Bed ◽  
Electrochemical Reactor ◽  
Electrochemical Capacitance ◽  
Electro Oxidation

scholarly journals A Carbon Nanotube Packed Bed Electrode for Small Molecule Electrosorption: An Electrochemical and Chromatographic Approach for Process Description

2020 ◽  
Vol 10 (3) ◽  
pp. 1133
Author(s):  
Tatjana Trunzer ◽  
Timothy Stummvoll ◽  
Melanie Porzenheim ◽  
Paula Fraga-García ◽  
Sonja Berensmeier
Keyword(s):  
Structural Changes ◽  
Aqueous Media ◽  
Electrical Potential ◽  
Packed Bed ◽  
Electrical Potentials ◽  
Packed Bed Electrode ◽  
Through Flow ◽  
Multi Walled Carbon Nanotubes ◽  
Electrochemical Double Layer ◽  
Walled Carbon Nanotubes

Triggering the interaction of nanomaterials with molecules by means of electrical potentials in aqueous media remains challenging, especially if 3D through-flow systems are used as electrodes, as in potential-controlled liquid chromatography (PCC). In this paper, multi-walled carbon nanotubes (MWCNTs) function as a particulate packed bed electrode in order to study the system’s response to various applied potentials and electrolyte compositions. The process principle was analyzed using chronoamperometry and cyclic voltammetry. Applying an electrical potential to the hydrophilic MWCNTs induces the presence of both capacitive and faradaic currents. This leads, over time, to a degradation of the electrode due to structural changes of the MWCNT matrix and an increase in redox reactions on the surface. The role of the electrochemical double layer (EDL) is highlighted as a main player in the process, directly influencing the adsorption capability of the electrode. The EDL rearrangement time and coverage radius depend on the composition of the mobile phase and on the potential applied. The capacity of the electrode for the target (maleic acid) increases at high positive potentials (+800 mV vs. Ag/AgCl), while the presence of electrolytes leads to a capacity decrease. Our research enhances the understanding of capacitive through-flow cells.

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