Simultaneous electrochemical removal of copper and chemical oxygen demand using a packed-bed electrode cell

1986 ◽  
Vol 16 (1) ◽  
pp. 121-126 ◽  
Author(s):  
Katsuki Kusakabe ◽  
Hiroshi Nishida ◽  
Shigeharu Morooka ◽  
Yasuo Kato
2011 ◽  
Vol 63 (11) ◽  
pp. 2685-2691 ◽  
Author(s):  
Lizhang Wang ◽  
Yuemin Zhao ◽  
Qingyu Gao ◽  
Cheng Qian ◽  
Yunlong Hu

The electro-oxidation of aromatic compounds in 4,4′-diaminostilbene-2,2′-disulfonic (DSD) acid wastewater on IrO2–Ta2O5/Ti anodes was studied. The current efficiency was evaluated in terms of chemical oxygen demand (COD) by introducing a new factor, the fraction of the Faradaic current to the total cell current (β) through the network analysis of packed bed electrode system (PBEs). Experimental results using an up-flow PBEs at current intensities ranging from 5 to 16 A m−2, flow rates ranging from 20 to 80 L h−1 and inter-electrode distance of 5 to 50 cm are in good agreement with the proposed equation. In addition, lower current density, increasing flow rate and larger inter-electrode distance are beneficial to enhance the current efficiency.


1987 ◽  
Vol 17 (6) ◽  
pp. 1213-1222 ◽  
Author(s):  
Hark Joon Kim ◽  
Katsuki Kusakabe ◽  
Satoko Hokazono ◽  
Shigeharu Morooka ◽  
Yasuo Kato

1986 ◽  
Vol 19 (1) ◽  
pp. 43-47 ◽  
Author(s):  
KATSUKI KUSAKABE ◽  
SHIGEHARU MOROOKA ◽  
YASUO KATO

2013 ◽  
Vol 22 (1) ◽  
pp. 199-203 ◽  
Author(s):  
I.A. Khattab ◽  
M.F. Shaffei ◽  
N.A. Shaaban ◽  
H.S. Hussein ◽  
S.S. Abd El-Rehim

2013 ◽  
Vol 22 (1) ◽  
pp. 205-210 ◽  
Author(s):  
I.A. Khattab ◽  
M.F. Shaffei ◽  
N.A. Shaaban ◽  
H.S. Hussein ◽  
S.S. Abd El-Rehim

2012 ◽  
Vol 66 (2) ◽  
pp. 422-428 ◽  
Author(s):  
Lizhang Wang ◽  
Peng Li ◽  
Qian Yan

A comparative study of phenol oxidation using pure electrolysis (PEs) and sand-based packed-bed electrode systems (SPBEs) was performed under conditions of phenol concentration 800 mg L−1, initial pH 6.5, current density 100 A m−2 and sodium sulfate (Na2SO4) 3.0% (w/w) on IrO2–Ta2O5/Ti anode. The results show quartz sand, a non-conducting material is incapable of expanding the electrode area and the phenol oxidation in SPBEs commences only at the electrode surface. From the theoretical description of the mass transport coefficient and chemical oxygen demand (COD), we confirm that the enhancement of the COD removal efficiency, current and space–time yields in SPBEs is due to the improvement of mass transport properties. The proposed SPBEs shows superiority to the PEs on saving energy at the same applied voltage, however, when operated under the same applied current density the energy consumption of the former would be much higher than that of the latter because of the rise of the applied cell voltage.


2014 ◽  
Vol 23 (1) ◽  
pp. 93-103 ◽  
Author(s):  
I.A. Khattab ◽  
M.F. Shaffei ◽  
N.A. Shaaban ◽  
H.S. Hussein ◽  
S.S. Abd El-Rehim

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