Translational and rotational diffusion of an anisotropic particle in a molecular liquid: Long-time tails and Brownian limit

1985 ◽  
Vol 39 (1-2) ◽  
pp. 215-239 ◽  
Author(s):  
A. J. Masters ◽  
T. Keyes
Keyword(s):  
Rotational Diffusion ◽  
Long Time Tails ◽  
Anisotropic Particle ◽  
Molecular Liquid ◽  
Brownian Limit ◽  
Long Time ◽  
Translational And Rotational Diffusion

Diffusion effects of hydrogen bond fluctuations. I. The long time regime of the translational and rotational diffusion of water

1989 ◽  
Vol 91 (2) ◽  
pp. 1179-1190 ◽  
Author(s):  
Davide Bertolini ◽  
Mario Cassettari ◽  
Mauro Ferrario ◽  
Paolo Grigolini ◽  
Giuseppe Salvetti ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Rotational Diffusion ◽  
Diffusion Effects ◽  
Time Regime ◽  
Long Time ◽  
Translational And Rotational Diffusion

scholarly journals Shape-designed frustration by local polymorphism in a near-equilibrium colloidal glass

2015 ◽  
Vol 112 (39) ◽  
pp. 12063-12068 ◽  
Author(s):  
Kun Zhao ◽  
Thomas G. Mason
Keyword(s):  
Rotational Diffusion ◽  
2D Systems ◽  
Entropy Maximization ◽  
Glass Forming ◽  
Disordered Structure ◽  
Long Time ◽  
Translational And Rotational Diffusion ◽  
Colloidal Glass

We show that hard, convex, lithographic, prismatic kite platelets, each having three 72° vertices and one 144° vertex, preferentially form a disordered and arrested 2D glass when concentrated quasi-statically in a monolayer while experiencing thermal Brownian fluctuations. By contrast with 2D systems of other hard convex shapes, such as squares, rhombs, and pentagons, which readily form crystals at high densities, 72° kites retain a liquid-like disordered structure that becomes frozen-in as their long-time translational and rotational diffusion become highly bounded, yielding a 2D colloidal glass. This robust glass-forming propensity arises from competition between highly diverse few-particle local polymorphic configurations (LPCs) that have incommensurate features and symmetries. Thus, entropy maximization is consistent with the preservation of highly diverse LPCs en route to the arrested glass.

Experimental observation of “long time tails”?

1976 ◽  
Vol 55 (7) ◽  
pp. 391-392 ◽  
Author(s):  
J.P. Boon ◽  
A. Bouiller
Keyword(s):  
Experimental Observation ◽  
Long Time Tails ◽  
Long Time

scholarly journals Modeling Macromolecular Crowding through Translational and Rotational Diffusion of Small Molecular Probes

2016 ◽  
Vol 110 (3) ◽  
pp. 50a
Author(s):  
Megan Currie ◽  
Brenden Berry ◽  
Taylor Ward ◽  
Erin D. Sheets ◽  
Ahmed A. Heikal
Keyword(s):  
Rotational Diffusion ◽  
Macromolecular Crowding ◽  
Molecular Probes ◽  
Translational And Rotational Diffusion

scholarly journals Translational and rotational diffusion of micrometer-sized solid domains in lipid membranes

Soft Matter ◽  
2012 ◽  
Vol 8 (29) ◽  
pp. 7552 ◽  
Author(s):  
Eugene P. Petrov ◽  
Rafayel Petrosyan ◽  
Petra Schwille
Keyword(s):  
Lipid Membranes ◽  
Rotational Diffusion ◽  
Translational And Rotational Diffusion
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