Structural study of phosphorus-containing butadienes. 3. Molecular and crystal structure of the dibromoneopentylglycol and bis-1,3,5-tribromophenyl esters of 3,4-dichloro-1,2-butadiene-2-phosphonic acid

1990 ◽  
Vol 39 (3) ◽  
pp. 504-507
Author(s):  
V. E. Shklover ◽  
V. I. Petrov ◽  
Yu. T. Struchkov
Keyword(s):  
Crystal Structure ◽  
Structural Study ◽  
Phosphonic Acid ◽  
Molecular And Crystal Structure ◽  
Phosphorus Containing

Beiträge zur Strukturchemie phosphorhaltiger Ketten und Ringe, XIII [1]. Die Molekül- und Kristallstruktur von 3,4,9,10-Tetraisopropylpentacyclo[ 6.4.0.02,6.05,12.07,11]dodecaphosphan, P12(i-Pr)4 / Structural Chemistry of Phosphorus-Containing Chains and Rings, XIII [1]. The Molecular and Crystal Structure of 3,4,9,10-Tetraisopropylpentacyclo[6.4.0.02,6.05,12.07,11]dodecaphosphane, P12(iPr)4

1986 ◽  
Vol 41 (5) ◽  
pp. 548-552 ◽  
Author(s):  
Karl-Friedrich Tebbe ◽  
Magda Fehér
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Structural Unit ◽  
Structural Chemistry ◽  
Molecular And Crystal Structure ◽  
Triclinic Space Group ◽  
Space Group ◽  
X Ray ◽  
Phosphorus Containing

Abstract The structure of P12(iPr)4, C12H28P12 , has been determined by single crystal X-ray techniques (Rf = 0.026, wRf = 0.029 for 3549 observed reflections with |Fo| ≥ 4σ(Fo)). The compound crystallizes in the triclinic space group P1 with a = 879.8, b = 1088.5, c = 1414.1 pm, α = 93.01, β - 107.61, γ = 92.92° and Z = 2. The molecule contains a polycyclic P12-unit of nearly C2v symmetry, which represents an essential structural unit of Hittorf’s phosphorus.

scholarly journals Molekül- und Kristallstruktur von 1.1-Dimethylsilylentitanocendichlorid, (CH3)2Si(C5H4)2TiCl2 / Molecular and Crystal Structure of l,r-Dimethylsilylene Titanocene Dichloride, (CH3)2Si(C5H4)2TiCl2

1981 ◽  
Vol 36 (10) ◽  
pp. 1208-1210 ◽  
Author(s):  
Hartmut Köpf ◽  
Joachim Pickardt
Keyword(s):  
Molecular Structure ◽  
Crystal Structure ◽  
Structure Determination ◽  
Titanocene Dichloride ◽  
Molecular And Crystal Structure ◽  
Monoclinic Space Group ◽  
Crystal Data ◽  
Space Group ◽  
X Ray ◽  
Structural Dimensions

Abstract The molecular structure of the bridged [1]-titanocenophane 1,1'-dimethylsilylene titanocene dichloride, (CH3)2Si(C5H4)2TiCl2, has been investigated by an X-ray structure determination. Crystal data: monoclinic, space group C2/c, Z = 4, a = 1332.9(3), 6 = 988.7(3), c = 1068.9(3) pm, β = 113.43(2)°. The results are compared with the structural dimensions of similar compounds: 1,1'-methylene titanocene dichloride, CH2(C5H4)TiCl2, with the unbridged titanocene dichloride, (C5H5)2TiCl2 and the ethylene-bridged compound (CH2)2(C5H4)2TiCl2

Sign in / Sign up

Export Citation Format

Share Document