Hydrogen permeability and catalytic activity of membranes made from palladium-copper alloys in the dehydrogenation of 1,2-cyclohexanediol

Author(s):  
A. P. Mishchenko ◽  
M. E. Sarylova ◽  
V. M. Gryaznov ◽  
V. S. Smirnov ◽  
N. R. Roshan ◽  
...  
Hydrogen ◽  
2021 ◽  
Vol 2 (3) ◽  
pp. 262-272
Author(s):  
Sebastian DiMauro ◽  
Gabrielle Legall ◽  
Coleman Lubinsky ◽  
Monica Nadeau ◽  
Renee Tait ◽  
...  

Strength, hardness, and ductility characteristics were determined for a series of palladium-copper alloys that compositionally vary from 5 to 25 weight percent copper. Alloy specimens subjected to vacuum annealing showed clear evidence of solid solution strengthening. These specimens showed, as a function of increasing copper content, increased yield strength, ultimate strength, and Vickers microhardness, while their ductility was little affected by compositional differences. Annealed alloy specimens subsequently subjected to exposure to hydrogen at 323 K and PH2 = 1 atm showed evidence of hydrogen embrittlement up to a composition of ~15 wt. % Cu. The magnitude of the hydrogen embrittlement decreased with increasing copper content in the alloy.


1984 ◽  
Vol 15 (16) ◽  
Author(s):  
J. PETRO ◽  
T. MALLAT ◽  
S. SZABO ◽  
F. HANGE

1983 ◽  
Vol 89 (2) ◽  
pp. 423-428 ◽  
Author(s):  
N.R. Roshan ◽  
A.P. Mishchenko ◽  
V.P. Polyakova ◽  
N.I. Parfenova ◽  
E.M. Savitsky ◽  
...  

1969 ◽  
Vol 5 (10) ◽  
pp. 309-312 ◽  
Author(s):  
P. B. Babkova ◽  
A. K. Avetisev ◽  
G. D. Lyubarskii ◽  
A. I. Gel'bshtein

1977 ◽  
Vol 20 (2) ◽  
pp. 149-158 ◽  
Author(s):  
D. Fisher ◽  
D.M. Chisdes ◽  
Ted B. Flanagan

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