Chain transfer constants in the radical telomerization of vinyl chloride, propylene, and ethylene with carbon tetrachloride and chloroform; sensitivity of substitution reactions with cleavage of C-H and C-C1 bonds to polar effects

1969 ◽  
Vol 18 (9) ◽  
pp. 1764-1769
Author(s):  
B. A. �nglin ◽  
T. A. Onishchenko
Keyword(s):  
Carbon Tetrachloride ◽  
Vinyl Chloride ◽  
Chain Transfer ◽  
Substitution Reactions ◽  
Radical Telomerization

Radical telomerization of 3,3,3-trifluoro-1-propene by carbon tetrabromide. Individual chain transfer constants

1987 ◽  
Vol 36 (4) ◽  
pp. 734-737
Author(s):  
T. T. Vasil'eva ◽  
V. A. Kochetkova ◽  
B. V. Nelyubin ◽  
B. I. Dostovalova ◽  
R. Kh. Freidlina
Keyword(s):  
Chain Transfer ◽  
Carbon Tetrabromide ◽  
Radical Telomerization

PHOTOLYSE DE L'IODURE DE VINYLE EN SOLUTION DANS LE TETRACHLORURE DE CARBONE

1964 ◽  
Vol 42 (10) ◽  
pp. 2262-2274 ◽  
Author(s):  
Pierre C. Roberge ◽  
Jan A. Herman
Keyword(s):  
Carbon Tetrachloride ◽  
Vinyl Chloride ◽  
Hydrogen Iodide ◽  
Diffusion Controlled ◽  
Vinyl Iodide

The photolysis of vinyl iodide in carbon tetrachloride solutions gives several products among which the most important are: acetylene, hydrogen iodide, iodine, ethylene, and vinyl chloride. A mechanism based on diffusion-controlled disproportionation of geminate radicals, as first proposed by Hamill, agrees well with the observed phenomena. To explain the diminishing production of ethylene and iodine with increasing concentration of the monomer, it is necessary to postulate a telomerization of the vinyl iodide.

Branch structures in poly(vinyl chloride) and the mechanism of chain transfer to monomer during vinyl chloride polymerization

1983 ◽  
Vol 16 (5) ◽  
pp. 790-807 ◽  
Author(s):  
W. H. Starnes ◽  
Frederic C. Schilling ◽  
I. M. Plitz ◽  
Rudolf E. Cais ◽  
D. J. Freed ◽  
...  
Keyword(s):  
Vinyl Chloride ◽  
Chain Transfer ◽  
Poly Vinyl Chloride

Cyclopentyl methyl ether as a green solvent for reversible-addition fragmentation chain transfer and nitroxide-mediated polymerizations

RSC Advances ◽  
2016 ◽  
Vol 6 (9) ◽  
pp. 7495-7503 ◽  
Author(s):  
Carlos M. R. Abreu ◽  
Pedro Maximiano ◽  
Tamaz Guliashvili ◽  
Julien Nicolas ◽  
Arménio C. Serra ◽  
...  
Keyword(s):  
Vinyl Chloride ◽  
Organic Solvents ◽  
Methyl Ether ◽  
Chain Transfer ◽  
Environmentally Friendly ◽  
Green Solvent ◽  
Reversible Addition

Cyclopentyl methyl ether (CPME) was successfully used as an environmentally friendly alternative to regularly employed organic solvents (e.g., THF, DMSO, DCM and DMF) for the RAFT and NMP polymerizations of vinyl chloride (VC) and styrene (S).

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