Sensitivity to polar effects of reactions of homolytic substitution with cleavage of the C-Br bond and chain transfer constants in the radical telomerization of vinyl chloride with CBrCl3

1971 ◽  
Vol 20 (12) ◽  
pp. 2542-2548
Author(s):  
B. A. Anglin ◽  
T. A. Onishchenko ◽  
R. Kh. Freidlina
Keyword(s):  
Vinyl Chloride ◽  
Chain Transfer ◽  
Radical Telomerization ◽  
Homolytic Substitution

Radical telomerization of 3,3,3-trifluoro-1-propene by carbon tetrabromide. Individual chain transfer constants

1987 ◽  
Vol 36 (4) ◽  
pp. 734-737
Author(s):  
T. T. Vasil'eva ◽  
V. A. Kochetkova ◽  
B. V. Nelyubin ◽  
B. I. Dostovalova ◽  
R. Kh. Freidlina
Keyword(s):  
Chain Transfer ◽  
Carbon Tetrabromide ◽  
Radical Telomerization

Branch structures in poly(vinyl chloride) and the mechanism of chain transfer to monomer during vinyl chloride polymerization

1983 ◽  
Vol 16 (5) ◽  
pp. 790-807 ◽  
Author(s):  
W. H. Starnes ◽  
Frederic C. Schilling ◽  
I. M. Plitz ◽  
Rudolf E. Cais ◽  
D. J. Freed ◽  
...  
Keyword(s):  
Vinyl Chloride ◽  
Chain Transfer ◽  
Poly Vinyl Chloride

Cyclopentyl methyl ether as a green solvent for reversible-addition fragmentation chain transfer and nitroxide-mediated polymerizations

RSC Advances ◽  
2016 ◽  
Vol 6 (9) ◽  
pp. 7495-7503 ◽  
Author(s):  
Carlos M. R. Abreu ◽  
Pedro Maximiano ◽  
Tamaz Guliashvili ◽  
Julien Nicolas ◽  
Arménio C. Serra ◽  
...  
Keyword(s):  
Vinyl Chloride ◽  
Organic Solvents ◽  
Methyl Ether ◽  
Chain Transfer ◽  
Environmentally Friendly ◽  
Green Solvent ◽  
Reversible Addition

Cyclopentyl methyl ether (CPME) was successfully used as an environmentally friendly alternative to regularly employed organic solvents (e.g., THF, DMSO, DCM and DMF) for the RAFT and NMP polymerizations of vinyl chloride (VC) and styrene (S).

Sign in / Sign up

Export Citation Format

Share Document