Effect of excess gallium and arsenic in the gas phase on the growth of gallium arsenide in the ?111? direction

1972 ◽  
Vol 15 (10) ◽  
pp. 1419-1424
Author(s):  
L. G. Lavrent'eva ◽  
L. G. Nesteryuk ◽  
S. P. Gaidareva
Keyword(s):  
1988 ◽  
Vol 53 (12) ◽  
pp. 2995-3013
Author(s):  
Emerich Erdös ◽  
Jindřich Leitner ◽  
Petr Voňka ◽  
Josef Stejskal ◽  
Přemysl Klíma

For a quantitative description of the epitaxial growth rate of gallium arsenide, two models are proposed including two rate controlling steps, namely the diffusion of components in the gas phase and the surface reaction. In the models considered, the surface reaction involves a reaction triple - or quadruple centre. In both models three mechanisms are considered which differ one from the other by different adsorption - and impact interaction of reacting particles. In every of the six cases, the pertinent rate equations were derived, and the models have been confronted with the experimentally found dependences of the growth rate on partial pressures of components in the feed. The results are discussed with regard to the plausibility of individual mechanisms and of both models, and also with respect to their applicability and the direction of further investigations.


1989 ◽  
Vol 54 (11) ◽  
pp. 2933-2950
Author(s):  
Emerich Erdös ◽  
Petr Voňka ◽  
Josef Stejskal ◽  
Přemysl Klíma

This paper represents a continuation and ending of the kinetic study of the gallium arsenide formation, where a so-called inhomogeneous model is proposed and quantitatively formulated in five variants, in which two kinds of active centres appear. This model is compared both with the experimental data and with the previous sequence of homogeneous models.


ChemInform ◽  
1989 ◽  
Vol 20 (18) ◽  
Author(s):  
M. D. VILISOVA ◽  
E. V. MALISOVA ◽  
G. M. IKONNIKOVA ◽  
L. M. KRASIL'NIKOVA ◽  
V. B. YABZHANOV ◽  
...  
Keyword(s):  

1993 ◽  
Vol 63 (2) ◽  
pp. 214-215 ◽  
Author(s):  
Douglas F. Foster ◽  
Christopher Glidewell ◽  
David J. Cole‐Hamilton

1985 ◽  
Vol 28 (2) ◽  
pp. 172-176
Author(s):  
I. A. Bobrovnikova ◽  
L. G. Lavrent'eva ◽  
S. E. Toropov
Keyword(s):  

1979 ◽  
Vol 22 (6) ◽  
pp. 672-674
Author(s):  
I. V. Ivonin ◽  
L. M. Krasil'nikova ◽  
L. G. Lavrent'eva ◽  
G. F. Lymar'

1984 ◽  
Vol 49 (11) ◽  
pp. 2425-2436 ◽  
Author(s):  
Emerich Erdös ◽  
Petr Voňka ◽  
Josef Stejskal ◽  
Přemysl Klíma

A model is proposed and quantitatively treated of epitaxial growth of gallium arsenide layers, where the rate controlling step consists in the diffusion of reactants through a stagnant gas film adhering to the substrate, and where chemical equilibria are established between the reactants in the main gas stream and at the surface of substrate. The boundary layer theory is applied to the hydrodynamic part of the model which is simplified by introducing a mean effective film thickness, and the system of Ga-As-Cl-H is reduced to six molecular species and to three chemical reactions. With this basis and using estimated values of diffusion coefficients, the growth rates of epitaxial gallium arsenide layers have been a priori computed in dependence of the feed rate, its composition and on temperature. The predicted three dependences are discussed from the view-point of their courses and of the significance of computed results.


1985 ◽  
Vol 50 (8) ◽  
pp. 1774-1783 ◽  
Author(s):  
Emerich Erdös ◽  
Petr Voňka ◽  
Josef Stejskal ◽  
Přemysl Klíma

The growth model of gallium arsenide epitaxial layers has been further extended in two ways. First of all, the location of the substrate in experiments in the reactor has been taken into account, and a general relationship has been derived for dependence of the mean effective thickness of the boundary layer on the distance of the substrate from the leading edge and on the substrate size. Secondly, the effect of rate of the chemical heterogeneous reaction has been investigated in addition to the diffusion rate on the resulting growth velocity of epitaxial gallium arsenide layers. A quantitative model comprising the rates of the both partial processes has been formulated. The theoretical relationships obtained in this way have been confronted with experimental results.


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