Excess volumes of mixing for some primary alcohols with secondary amines at 293.15 K and 323.15 K

1982 ◽  
Vol 113 (10) ◽  
pp. 1119-1126 ◽  
Author(s):  
László Domonkos ◽  
Ferenc Ratkovics
Keyword(s):  
Excess Volumes ◽  
Secondary Amines ◽  
Primary Alcohols ◽  
Volumes Of Mixing

Densities and Excess Volumes of Fused Halides

1975 ◽  
Vol 30 (1) ◽  
pp. 64-68 ◽  
Author(s):  
H. C. Brookes ◽  
R. L. Paul
Keyword(s):  
Mole Fraction ◽  
Linear Dependence ◽  
Alkali Halide ◽  
Experimental Error ◽  
Van Der Waals ◽  
Excess Volumes ◽  
Van Der Waals Interactions ◽  
Solution Theory ◽  
Conformal Solution Theory ◽  
Volumes Of Mixing

Abstract Densities of molten AgBr-AX (A = Li, Na, K, Rb, Cs; X = Br or Cl), AgBr-AgCl, KBr-NaBr, KBr-CsBr, KCl-KBr, and KCl-CsBr mixtures have been measured at 0.5 mole fraction using the method of Archimedean displacement. The excess volumes of mixing are all positive, except for the AgBr-LiBr system. Attempts to relate the excess volumes of the binary AgBr-ABr systems to the second order conformal solution theory of Reiss, Katz, and Kleppa are unsuccessful, since V E is large even when the diameter difference parameter, δ12, is close to zero. However, the excess volumes of the reciprocal AgBr-ACl systems at 0.5 mole fraction are found, within experimental error, to have a linear dependence on δ12. The positive deviations from conformal solution theory which occur for the alkali halide mixtures have been interpreted in terms of non-Coulombic polarisation and van der Waals interactions.

Some excess volumes of mixing

1973 ◽  
Vol 5 (3) ◽  
pp. 361-364 ◽  
Author(s):  
B.R. Sharma ◽  
P.P. Singh
Keyword(s):  
Excess Volumes ◽  
Volumes Of Mixing
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