Energies of atomic valence states and the thermodynamic properties of gaseous inorganic compounds

1968 ◽  
Vol 8 (3) ◽  
pp. 450-455 ◽  
Author(s):  
O. P. Charkin ◽  
M. E. Dyatkina
Keyword(s):  
Thermodynamic Properties ◽  
Inorganic Compounds ◽  
Valence States ◽  
Atomic Valence

scholarly journals Distribution of Valence States of Recoil Antimony Atoms in Inorganic Compounds

RADIOISOTOPES ◽  
1965 ◽  
Vol 14 (5) ◽  
pp. 353-356
Author(s):  
Tomihisa KAMBARA ◽  
Nobuyuki KASHIHIRA ◽  
Katsuyuki HAGITA ◽  
Chung-huei Ke
Keyword(s):  
Inorganic Compounds ◽  
Valence States

The valence states of atoms in gaseous inorganic compounds

1968 ◽  
Vol 9 (5) ◽  
pp. 758-760
Author(s):  
O. P. Charkin ◽  
M. E. Dyatkina
Keyword(s):  
Inorganic Compounds ◽  
Valence States

Valence states of atoms in gaseous inorganic compounds

1968 ◽  
Vol 9 (4) ◽  
pp. 585-588
Author(s):  
O. P. Charkin ◽  
M. E. Dyatkina
Keyword(s):  
Inorganic Compounds ◽  
Valence States

Electric dipole polarizabilities of atomic valence states

1992 ◽  
Vol 46 (5) ◽  
pp. 2356-2362 ◽  
Author(s):  
Kerstin Andersson ◽  
Andrzej J. Sadlej
Keyword(s):  
Electric Dipole ◽  
Valence States ◽  
Dipole Polarizabilities ◽  
Atomic Valence

Valence states of atoms in gaseous inorganic compounds

1968 ◽  
Vol 9 (1) ◽  
pp. 92-96
Author(s):  
O. P. Charkin ◽  
M. E. Dyatkina
Keyword(s):  
Inorganic Compounds ◽  
Valence States

The resonance valence state

1968 ◽  
Vol 303 (1473) ◽  
pp. 233-257 ◽  
Keyword(s):  
Linear Combination ◽  
Valence State ◽  
State Energy ◽  
Valence Bond ◽  
Alternative Definition ◽  
Valence States ◽  
Spectral Term ◽  
Definition Of ◽  
Valence Configuration ◽  
Atomic Valence

An alternative definition of the atomic valence state is proposed. It is based upon a valence-bond wavefunction for molecules AX n , in which equivalence of the bonds is secured by allowing resonance among pairing schemes for ligand orbitals at X paired to natural s, p and d orbitals at A. The valence state of A is then either the lowest term of the valence configuration, for example, 7 F of sulphur in SF 6 , or is a linear combination of terms of highest multiplicity. The valence state energy is directly available from spectral term values in many important examples. The resonance valence state has a number of advantages, including easier availability of energies, over the usual perfect-pairing valence state, which is a linear combination of terms belonging to each of a number of different electron configurations. The two valence states are compared, and the resonance valence state analysed in several examples including AX 4 in T d , D 2d and S 4 symmetries.

Sign in / Sign up

Export Citation Format

Share Document