Valence states of atoms in gaseous inorganic compounds

1968 ◽  
Vol 9 (4) ◽  
pp. 585-588
Author(s):  
O. P. Charkin ◽  
M. E. Dyatkina
RADIOISOTOPES ◽  
1965 ◽  
Vol 14 (5) ◽  
pp. 353-356
Author(s):  
Tomihisa KAMBARA ◽  
Nobuyuki KASHIHIRA ◽  
Katsuyuki HAGITA ◽  
Chung-huei Ke

1968 ◽  
Vol 9 (5) ◽  
pp. 758-760
Author(s):  
O. P. Charkin ◽  
M. E. Dyatkina

1968 ◽  
Vol 9 (1) ◽  
pp. 92-96
Author(s):  
O. P. Charkin ◽  
M. E. Dyatkina

Author(s):  
Chen Liqing ◽  
Liu Zuqin ◽  
Zhang Wei

Valence state analyses of Fe and Mn in oxides by EPMA have been reported in literature. In this paper, the effects of valence state on intensity ratios ILα/IKα and ILα/ILβ of Cu, Ni, Co, Fe, Mn, Cr and their oxides, and on intensity ratios ILβ2/ILα1 and ILγ1/ILα1 of Mo, Nb, Zr and their oxides were studied. It was observed that intensity ratios change with valence states in accordance with some regularities, and these effects could be utilized for analyzing the valence states of catalysts.Valence state analysis of elements by EPMA is based on the fact that changes in the states of valence electrons in the outer shells of an atom cause corresponding changes in line intensities. The M electrons of Cu, Ni, Co, Fe, Mn, Cr and the N electrons of Mo, Nb, Zr are valence electrons. Line Kα1,2 and six lines of L are produced from the transitions of K-L2,3 and L-M or L-N respectively.


1996 ◽  
Vol 89 (5) ◽  
pp. 1577-1602 ◽  
Author(s):  
THOMAS SORENSEN ◽  
WALTER ENGLAND
Keyword(s):  

2019 ◽  
Vol 55 (3) ◽  
pp. 29-43 ◽  
Author(s):  
P. D. Klochenko ◽  
T. F. Shevchenko ◽  
I. N. Nezbrytskaya ◽  
Ye. P. Belous ◽  
Z. N. Gorbunova ◽  
...  

2014 ◽  
Vol 28 (2) ◽  
pp. 231-237 ◽  
Author(s):  
Lech W. Szajdak ◽  
Jerzy Lipiec ◽  
Anna Siczek ◽  
Artur Nosalewicz ◽  
Urszula Majewska

Abstract The aim of this study was to verify first-order kinetic reaction rate model performance in predicting of leaching of atrazine and inorganic compounds (K+1, Fe+3, Mg+2, Mn+2, NH4 +, NO3 - and PO4 -3) from tilled and orchard silty loam soils. This model provided an excellent fit to the experimental concentration changes of the compounds vs. time data during leaching. Calculated values of the first-order reaction rate constants for the changes of all chemicals were from 3.8 to 19.0 times higher in orchard than in tilled soil. Higher first-order reaction constants for orchard than tilled soil correspond with both higher total porosity and contribution of biological pores in the former. The first order reaction constants for the leaching of chemical compounds enables prediction of the actual compound concentration and the interactions between compound and soil as affected by management system. The study demonstrates the effectiveness of simultaneous chemical and physical analyses as a tool for the understanding of leaching in variously managed soils.


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