X-ray diffraction investigation of nonvalent interactions and coordination in organometallic compounds

1975 ◽  
Vol 15 (4) ◽  
pp. 561-567 ◽  
Author(s):  
L. G. Kuz'mina ◽  
N. G. Bokii ◽  
Yu. T. Struchkov ◽  
V. I. Minkin ◽  
L. P. Olekhnovich ◽  
...  
Keyword(s):  
Organometallic Compounds ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nonvalent Interactions

X-ray diffraction investigation of nonvalent interactions and coordination in organometallic compounds

1974 ◽  
Vol 15 (3) ◽  
pp. 424-429 ◽  
Author(s):  
N. G. Bokii ◽  
Yu. T. Struchkov ◽  
D. N. Kravtsov ◽  
E. M. Rokhlina
Keyword(s):  
Organometallic Compounds ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nonvalent Interactions

X-ray diffraction investigation of nonvalent interactions and coordination in organometallic compounds

1973 ◽  
Vol 14 (3) ◽  
pp. 458-462 ◽  
Author(s):  
N. G. Bokii ◽  
Yu. T. Struchkov ◽  
D. N. Kravtsov ◽  
E. M. Rokhlina
Keyword(s):  
Organometallic Compounds ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nonvalent Interactions

X-ray diffraction investigation of nonvalent interactions and coordination in organometallic compounds

1973 ◽  
Vol 14 (3) ◽  
pp. 463-468 ◽  
Author(s):  
L. G. Kuz'mina ◽  
N. G. Bokii ◽  
Yu. T. Struchkov ◽  
D. N. Kravtsov ◽  
L. S. Golovchenko
Keyword(s):  
Organometallic Compounds ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nonvalent Interactions

X-ray diffraction investigation of nonvalent interactions and coordination in organometallic compounds

1973 ◽  
Vol 14 (2) ◽  
pp. 258-266 ◽  
Author(s):  
N. G. Bokii ◽  
Yu. T. Struchkov ◽  
D. N. Kravtsov ◽  
E. M. Rokhlina
Keyword(s):  
Organometallic Compounds ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nonvalent Interactions

X-ray diffraction investigation of nonvalent interactions and coordination in organometallic compounds

1974 ◽  
Vol 15 (3) ◽  
pp. 419-423 ◽  
Author(s):  
L. G. Kuz'mina ◽  
N. G. Bokii ◽  
Yu. T. Struchkov ◽  
D. N. Kravtsov ◽  
E. M. Rokhlina
Keyword(s):  
Organometallic Compounds ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nonvalent Interactions

A force field for MD simulations on rhenium organometallic compounds developed from enthalpy of sublimation and X-ray diffraction measurements

2019 ◽  
Vol 133 ◽  
pp. 60-69 ◽  
Author(s):  
Carlos E.S. Bernardes ◽  
Mariana T. Donato ◽  
M. Fátima M. Piedade ◽  
Hermínio P. Diogo ◽  
José N. Canongia Lopes ◽  
...  
Keyword(s):  
Force Field ◽  
Organometallic Compounds ◽  
Md Simulations ◽  
Enthalpy Of Sublimation ◽  
X Ray Diffraction ◽  
X Ray

X-ray diffraction study of nonvalence interactions and coordination in organometallic compounds

1977 ◽  
Vol 18 (1) ◽  
pp. 96-103 ◽  
Author(s):  
L. G. Kuz'mina ◽  
N. G. Bokii ◽  
Yu. T. Struchkov ◽  
V. I. Minkin ◽  
L. P. Olekhnovich ◽  
...  
Keyword(s):  
Diffraction Study ◽  
Organometallic Compounds ◽  
X Ray Diffraction ◽  
X Ray

scholarly journals Thiourea-Derived Chelating Ligands and Their Organometallic Compounds: Investigations into Their Anticancer Activity

Molecules ◽  
2020 ◽  
Vol 25 (16) ◽  
pp. 3661
Author(s):  
Kelvin K. H. Tong ◽  
Muhammad Hanif ◽  
James H. Lovett ◽  
Katja Hummitzsch ◽  
Hugh H. Harris ◽  
...  
Keyword(s):  
Diffraction Analysis ◽  
Benzimidazole Derivative ◽  
Organometallic Compounds ◽  
Analysis Data ◽  
Biological Evaluation ◽  
X Ray Diffraction ◽  
Metal Centers ◽  
X Ray ◽  
Biological Studies ◽  
Heterocyclic Derivatives

Thiones have been investigated as ligands in metal complexes with catalytic and biological activity. We report the synthesis, characterization, and biological evaluation of a series of MII/III complexes of the general formulae [MII(cym)(L)Cl]X (cym = η6-p-cymene) or [MIII(Cp*)(L)Cl]X (Cp* = η5-pentamethylcyclopentadienyl), where X = Cl− or PF6−, and L represents heterocyclic derivatives of thiourea. The thiones feature a benzyl-triazolyl pendant and they act as bidentate ligands via N,S-coordination to the metal centers. Several derivatives have been investigated by single-crystal X-ray diffraction analysis. NMR investigations showed a counterion-dependent shift of several protons due to the interaction with the counterions. These NMR investigations were complemented with X-ray diffraction analysis data and the effects of different counterions on the secondary coordination sphere were also investigated by DFT calculations. In biological studies, the Ir benzimidazole derivative was found to accumulate in the cytoplasm and it was the most cytotoxic derivative investigated.

Metallkomplexe mit biologisch wichtigen Liganden, LXXIV [1]. Metallorganische Verbindungen von 2-(3-Thienyl)glycin und dessen Derivaten / Metal Complexes with Biologically Important Ligands, LXXIV [1]. Organometallic Compounds of 2-(3-Thienyl)glycine and Derivatives thereof

1994 ◽  
Vol 49 (11) ◽  
pp. 1569-1579 ◽  
Author(s):  
Elfriede Schuhmann ◽  
Christian Robl ◽  
Wolfgang Beck
Keyword(s):  
Methyl Ester ◽  
Metal Complexes ◽  
Phenyl Group ◽  
Organometallic Compounds ◽  
Amino Group ◽  
X Ray Diffraction ◽  
Chelate Complexes ◽  
Tricarbonyl Complex ◽  
X Ray

N.O-Chelate complexes of R,S-2-(3-thienyl)glycinate (L) have been obtained: ML2 (M = Ni, Cu), (n-Bu3P)(Cl)M(L) (M = Pd. Pt), (η3-C3H5)Pd(L), C6H4CH,CHNMe2Pd(L), (η6-p-cymene)(Cl)Ru(L), (η5-C5Me5)(Cl)M(L) (M = Rh, Ir) and (η5-C5H5)(OC)2Mo(L). The methyl ester of R,S-2-(3-thienvl)glycine (L') forms the complexes trans-CT2PdL′2, cis- Cl2Pt(L')2, (η-Bu3P)(Cl2)M(L') (M = Pd, Pt) and (η5-C5Me5)(Cl)2M(L') (M = Rh, Ir) in which the ligand L' is coordinated through the amino group. The structures of (η3-C3H5)Pd(L) and of (η5-C5Me5)(Cl2)Ir(L') have been determined by X-ray diffraction. N- Benzoyl-2-(3-thienylglycine methyl ester reacts with Cr(CO)6 to yield a tricarbonyl complex with an η6-coordinated phenyl group. N-Benzoyl-R,S-2-(3-thienyl)glycinate (L") and (η5- C5H5)2TiCl2 give the diastereoisomers [(η5-C5H5)2Ti(R-L")(R-L")2/(η5-C5H5)2Ti(S-L") (S-L")] and (η5-C5H5)2Ti(R-L")(S-L") with Ti-O-bonds.

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