Magnetic polarization of nuclei in diacyl peroxide decomposition reactions

1972 ◽  
Vol 13 (1) ◽  
pp. 29-34
Author(s):  
A. V. Kessenikh ◽  
G. M. Zhidomirov ◽  
A. L. Buchachenko ◽  
S. V. Rykov
Keyword(s):  
Magnetic Polarization ◽  
Decomposition Reactions ◽  
Diacyl Peroxide ◽  
Peroxide Decomposition

scholarly journals Density Functional Theory Calculations on Copper-Mediated Peroxide Decomposition Reactions: Implications for Jet Fuel Autoxidation

2020 ◽  
Vol 34 (6) ◽  
pp. 7439-7447 ◽  
Author(s):  
Christopher M. Parks ◽  
Ehsan Alborzi ◽  
Simon G. Blakey ◽  
Anthony J. H. M. Meijer ◽  
Mohamed Pourkashanian
Keyword(s):  
Density Functional Theory ◽  
Density Functional ◽  
Density Functional Theory Calculations ◽  
Jet Fuel ◽  
Functional Theory ◽  
Decomposition Reactions ◽  
Peroxide Decomposition

Chemiluminescence from peroxide decomposition reactions. Role of energy transfer

1970 ◽  
Vol 92 (5) ◽  
pp. 1128-1136 ◽  
Author(s):  
Seth R. Abbott ◽  
Stanley. Ness ◽  
David M. Hercules
Keyword(s):  
Energy Transfer ◽  
Decomposition Reactions ◽  
Peroxide Decomposition

STRUCTURAL CRITERIA FOR CHEMILUMINESCENCE IN ACYL PEROXIDE DECOMPOSITION REACTIONS

1965 ◽  
Vol 4 (6) ◽  
pp. 1097-1110 ◽  
Author(s):  
M. M. Rauhut ◽  
D. Sheehan ◽  
R. A. Clarke ◽  
A. M. Semsel
Keyword(s):  
Decomposition Reactions ◽  
Peroxide Decomposition ◽  
Acyl Peroxide

Pyrolysis of trifluoroacetaldehyde, initiated by di-tertiary-butyl peroxide decomposition

1979 ◽  
Vol 57 (17) ◽  
pp. 2201-2210 ◽  
Author(s):  
Leon F. Loucks ◽  
Michael T. H. Liu ◽  
David G. Hooper
Keyword(s):  
Thermal Decomposition ◽  
Decomposition Product ◽  
Reaction Order ◽  
Methyl Radicals ◽  
Reaction Products ◽  
Decomposition Products ◽  
Tertiary Butyl ◽  
Decomposition Reactions ◽  
Peroxide Decomposition ◽  
Butyl Peroxide

The thermal decomposition of 95:5 mixtures of trifluoroacetaldehyde (TFA) and di-tert-butyl peroxide (DTBP) has been studied at 100 Torr over the temperature range of 390 to 440 K. The major decomposition products included CO, CF3H, CH3COCH3, and CH4 while C2F6, CF3CHOHCH3, CF3CH3, CF3COCH3, C2H6, (CF3)2CHOH, and H2 were also found. In addition to the usual reactions for TFA thermal decomposition, reactions of methyl radicals with TFA to form isopropoxyl radicals were found. The alcohol products result from H atom abstraction reactions of the isopropoxyl radicals while CF3COCH3 is a decomposition product. Arrhenius parameters for several reactions were determined: for DTBP decomposition, log k = 15.82 − 37.73/2.303RT; for H abstraction from TFA by CH3, log k = 8.30 − 7.37/2.303RT; for H abstraction from TFA by CF3, log k = 8.98 − 8.61/2.303RT. Consideration has also been given to several rate constant ratios for the formation and decomposition of isopropoxyl radicals.A study of the reaction order for the formation of CF3H, C2F6, and CH4 showed that the orders were 3/2, 1, and 1 respectively for these three products. A reaction mechanism involving 14 individual steps is proposed to explain the reaction products and the observed orders of reaction.

ChemInform Abstract: MECHANISM FOR DIACYL PEROXIDE DECOMPOSITION

1982 ◽  
Vol 13 (48) ◽  
Author(s):  
R. J. LINHARDT ◽  
B. L. MURR ◽  
E. MONTGOMERY ◽  
J. OSBY ◽  
J. SHERBINE
Keyword(s):  
Diacyl Peroxide ◽  
Peroxide Decomposition

Mechanism for diacyl peroxide decomposition

1982 ◽  
Vol 47 (12) ◽  
pp. 2242-2251 ◽  
Author(s):  
R. J. Linhardt ◽  
B. L. Murr ◽  
E. Montgomery ◽  
J. Osby ◽  
J. Sherbine
Keyword(s):  
Diacyl Peroxide ◽  
Peroxide Decomposition

NMR analysis of diacyl peroxide decomposition in methanol in response to temperature and microwave radiation

2012 ◽  
Vol 79 (2) ◽  
pp. 302-306 ◽  
Author(s):  
O. A. Haidukevich ◽  
E. D. Skakovskii ◽  
L. Yu. Tychinskaya ◽  
T. D. Zvereva ◽  
E. A. Dikusar ◽  
...  
Keyword(s):  
Microwave Radiation ◽  
Nmr Analysis ◽  
Diacyl Peroxide ◽  
Peroxide Decomposition ◽  
Response To Temperature
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