Mixed anhydrides of alkylxanthic and phosphorus-containing acids as antiwear additives for lubricating oils

1972 ◽  
Vol 8 (1) ◽  
pp. 69-71
Author(s):  
L. S. Kharchenko ◽  
Yu. T. Gordash
2021 ◽  
Vol 05 ◽  
pp. 15-22
Author(s):  
N.N. Novotrozhina ◽  
◽  
Yu.B. Ramazanova ◽  
G.A. Gakhramanova ◽  
B.I. Musayeva ◽  
...  

Dithiophosphoric acid esters containing various functional groups have been synthesized. On the basis of allyloxybenzyl- and allyloxymethylbenzylchlorides, as well as sodium diisopropyldithiophosphate, allyloxybenzyl- and allyloxymethylbenzyldialkyldithiophosphates were obtained, respectively. 5-methyl-2-hydroxyphenylcarbonylmethyldiisopropyldithiophosphate was synthesized by the interaction of 5-methyl-2-hydroxy-chloroacetophenone and sodium diisopropyldithiophosphate. The synthesized compounds were studied as anti-wear and anti-seize additives for lubricating oils. Were also investigated their thermo-oxidative and anticorrosive properties. It was found that all synthesized compounds provide an improvement in the anti-wear and anti-seize properties of petroleum oils, and the efficiency depends on the presence of certain functional groups in the molecules of additives.


2017 ◽  
Vol 30 (1) ◽  
pp. 23-32 ◽  
Author(s):  
Zeqi Jiang ◽  
Jianhua Fang ◽  
Boshui Chen ◽  
Kecheng Gu

1979 ◽  
Vol 15 (8) ◽  
pp. 601-603 ◽  
Author(s):  
T. A. Rogachevskaya ◽  
V. L. Lashkhi ◽  
A. B. Vipper ◽  
T. G. Malysheva ◽  
E. V. Kaidala ◽  
...  

1976 ◽  
Vol 12 (9) ◽  
pp. 723-727 ◽  
Author(s):  
V. L. Lashkhi ◽  
A. B. Vipper ◽  
A. A. Markov ◽  
V. A. Trofimov ◽  
F. N. Ermolov

2020 ◽  
Vol 68 (3) ◽  
Author(s):  
Juli Felicio Luiz ◽  
Hugh Spikes

Abstract The film-forming, friction and wear properties of a range of model and commercial ashless P and P/S antiwear additives have been studied. A method has been developed for removing the tribofilms formed by such additives in order to effectively quantify mild wear. In general the P/S additives studied formed thinner tribofilms but gave lower wear than the S-free P ones. In extended wear tests, three P/S additives gave wear as low, or lower, than a primary zinc dialkyldithiophosphate (ZDDP). For almost all lubricants tested the wear rate measured in short tests was considerably higher than that in long tests due to the greater contribution of running-in wear in the former. This highlights the importance of basing antiwear additive choice on reasonably long tests, where running-in becomes only a small component of the wear measured. It has been found that for both P and P/S ashless additives the addition of oil-soluble metal compounds based on Ti and Ca boosts tribofilm formation and can lead to very thick films, comparable to those formed by ZDDP. However, this thick film formation tends to be accompanied by an increase in mixed friction and also does not appear to reduce wear but may even increase it.


2012 ◽  
Vol 10 (18) ◽  
pp. 3677 ◽  
Author(s):  
Jacorien Coetzee ◽  
Graham R. Eastham ◽  
Alexandra M. Z. Slawin ◽  
David J. Cole-Hamilton

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