Importance of the purity of the initial materials for the silicate triplex glass production by polymerization

1977 ◽  
Vol 34 (6) ◽  
pp. 357-361
Author(s):  
G. I. Gushchina ◽  
O. I. Seregina ◽  
E. S. Lopatina ◽  
B. Z. Cherkinskii
Author(s):  
Carolyn Swan

Around the year 970 CE, a merchant ship carrying an assortment of goods from East Africa, Persia, India, Sri Lanka, Southeast Asia, and China foundered and sank to the bottom of the Java Sea. Thousands of beads made from many different materials—ceramic, jet, coral, banded stone, lapis lazuli, rock crystal, sapphire, ruby, garnet, pearl, gold, and glass—attest to the long-distance movement and trade of these small and often precious objects throughout the Indian Ocean world. The beads made of glass are of particular interest, as closely-dated examples are very rare and there is some debate as to where glass beads were being made and traded during this period of time. This paper examines 18 glass beads from the Cirebon shipwreck that are now in the collection of Qatar Museums, using a comparative typological and chemical perspective within the context of the 10th-century glass production. Although it remains uncertain where some of the beads were made, the composition of the glass beads points to two major production origins for the glass itself: West Asia and South Asia.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
John S. McCloy ◽  
José Marcial ◽  
Jack S. Clarke ◽  
Mostafa Ahmadzadeh ◽  
John A. Wolff ◽  
...  

AbstractEuropean Bronze and Iron Age vitrified hillforts have been known since the 1700s, but archaeological interpretations regarding their function and use are still debated. We carried out a series of experiments to constrain conditions that led to the vitrification of the inner wall rocks in the hillfort at Broborg, Sweden. Potential source rocks were collected locally and heat treated in the laboratory, varying maximum temperature, cooling rate, and starting particle size. Crystalline and amorphous phases were quantified using X-ray diffraction both in situ, during heating and cooling, and ex situ, after heating and quenching. Textures, phases, and glass compositions obtained were compared with those for rock samples from the vitrified part of the wall, as well as with equilibrium crystallization calculations. ‘Dark glass’ and its associated minerals formed from amphibolite or dolerite rocks melted at 1000–1200 °C under reducing atmosphere then slow cooled. ‘Clear glass’ formed from non-equilibrium partial melting of feldspar in granitoid rocks. This study aids archaeological forensic investigation of vitrified hillforts and interpretation of source rock material by mapping mineralogical changes and glass production under various heating conditions.


1972 ◽  
Vol 29 (12) ◽  
pp. 782-785
Author(s):  
K. T. Bondarev ◽  
F. G. Solinov ◽  
O. A. Golozubov
Keyword(s):  

1954 ◽  
Vol 46 (1) ◽  
pp. 172-174
Author(s):  
R. W. Shute ◽  
B. W. king
Keyword(s):  

2018 ◽  
Vol 931 ◽  
pp. 628-633 ◽  
Author(s):  
Sergey V. Fedosov ◽  
Maxim O. Bakanov ◽  
Sergey N. Nikishov

The work considers mathematical models describing thermal processes in the framework of thermal processing of raw material mixture for cellular glass sponging. It is shown that the existing models do not completely reflect the physical processes occurring in the technology of cellular glass production. It is noted that kinetics of cell formation in cellular glass is a promising trend for improving the cellular glass technology.


Minerals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 819
Author(s):  
Pura Alfonso ◽  
Oriol Tomasa ◽  
Luis Miguel Domenech ◽  
Maite Garcia-Valles ◽  
Salvador Martinez ◽  
...  

Tailings from the Osor fluorite mines release large amounts of potentially toxic elements into the environment. This work is a proposal to remove these waste materials and use them as a raw material in the manufacture of glass. The chemical composition of the tailings was determined by X-ray fluorescence and the mineralogy by X-ray diffraction. Waste materials have SiO2, Al2O3 and CaO contents suitable for a glass production, but Na as NaCO3 has to be added. Two glass formulations, with 80–90% of the residue and 10–20% Na2CO3, have been produced. The crystallization temperatures, obtained by differential thermal analysis, were 875 and 901 °C, and the melting temperatures were 1220 and 1215 °C for the G80-20 and G90-10 glasses, respectively. The transition temperatures of glass were 637 and 628 °C. The crystalline phases formed in the thermal treatment to produce devitrification were nepheline, plagioclase and diopside in the G80-20 glass, and plagioclase and akermanite-gehlenite in the G90-10 glass. The temperatures for the fixed viscosity points, the working temperatures and the coefficient of expansion were obtained. The chemical stability of the glass was tested and results indicate that the potentially toxic elements of the tailings were incorporated into the glass structure.


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