Locally equilibrium diffusion processes. I. Geometry of local thermodynamic equilibrium states

1989 ◽  
Vol 28 (5) ◽  
pp. 543-564 ◽  
Author(s):  
Andrzej Trzęsowski
Keyword(s):  
Thermodynamic Equilibrium ◽  
Diffusion Processes ◽  
Local Thermodynamic Equilibrium ◽  
Equilibrium States

scholarly journals Entropy and the Second Law of Thermodynamics—The Nonequilibrium Perspective

Entropy ◽  
2020 ◽  
Vol 22 (7) ◽  
pp. 793
Author(s):  
Henning Struchtrup
Keyword(s):  
Thermodynamic Equilibrium ◽  
Nonequilibrium Thermodynamics ◽  
Local Thermodynamic Equilibrium ◽  
Thermodynamic Temperature ◽  
Second Law Of Thermodynamics ◽  
Equilibrium States ◽  
Second Law ◽  
Rest State ◽  
The Stability

An alternative to the Carnot-Clausius approach for introducing entropy and the second law of thermodynamics is outlined that establishes entropy as a nonequilibrium property from the onset. Five simple observations lead to entropy for nonequilibrium and equilibrium states, and its balance. Thermodynamic temperature is identified, its positivity follows from the stability of the rest state. It is shown that the equations of engineering thermodynamics are valid for the case of local thermodynamic equilibrium, with inhomogeneous states. The main findings are accompanied by examples and additional discussion to firmly imbed classical and engineering thermodynamics into nonequilibrium thermodynamics.

Blackbody Radiation, Boltzmann Statistics, Temperature, and Thermodynamic Equilibrium

2017 ◽  
Author(s):  
Kelly Chance ◽  
Randall V. Martin
Keyword(s):  
Thermodynamic Equilibrium ◽  
Local Thermodynamic Equilibrium ◽  
Photophysical Properties ◽  
Blackbody Radiation ◽  
Boltzmann Constant ◽  
Noise Sources ◽  
Atmospheric Molecules ◽  
Tightly Coupled ◽  
Boltzmann Statistics ◽  
Planck’S Law

Blackbody radiation, temperature, and thermodynamic equilibrium give a tightly coupled description of systems (atmospheres, volumes, surfaces) that obey Boltzmann statistics. They provide descriptions of systems when Boltzmann statistics apply, either approximately or nearly exactly. These apply most of the time in the Earth’s stratosphere and troposphere, and in other planetary atmospheres as long as the density is sufficient that collisions among atmospheric molecules, rather than photochemical and photophysical properties, determine the energy populations of the ensemble of molecules. Thermodynamic equilibrium and the approximation of local thermodynamic equilibrium are introduced. Boltzmann statistics, blackbody radiation, and Planck’s law are described. The chapter introduces the Rayleigh-Jeans limit, description of noise sources as temperatures, Kirchoff’s law, the Stefan-Boltzmann constant, and Wien’s law.

Diagnosing Fe Plasma In Non-Local Thermodynamic Equilibrium

2013 ◽  
Vol 82 (2) ◽  
pp. 024501
Author(s):  
Xiao-Ying Han ◽  
Fei-Lu Wang ◽  
Ze-Qing Wu ◽  
Jun Yan ◽  
Gang Zhao
Keyword(s):  
Thermodynamic Equilibrium ◽  
Local Thermodynamic Equilibrium ◽  
Non Local

scholarly journals Observations of Molecules in Stellar Atmospheres - Chemistry Near Thermal Equilibrium

1987 ◽  
Vol 120 ◽  
pp. 583-598
Author(s):  
David L. Lambert
Keyword(s):  
Thermodynamic Equilibrium ◽  
Thermal Equilibrium ◽  
Local Thermodynamic Equilibrium ◽  
Stellar Atmospheres ◽  
Red Giants ◽  
The Sun ◽  
Carbon Stars ◽  
General Review ◽  
Elemental Abundances

A general review is given of the astrophysical information obtainable from observations of molecules in stellar photospheres. Through selected examples, the use of molecules as thermometers (e.g., the OH 3 μm V-R lines in the Sun and α Ori) and as probes of the isotopic (e.g., iMg in metal-poor dwarfs, 12C/13C in cool carbon stars) and elemental abundances (e.g., CNO in red giants) is sketched. All of the (carefully) selected analyses assume that local thermodynamic equilibrium (LTE) prevails.

scholarly journals On the violation of local thermodynamic equilibrium in the plasma jet of an argon arc two-jet plasmatron

2019 ◽  
Vol 85 (1II)) ◽  
pp. 145-150
Author(s):  
A. S. Cherevko ◽  
A. A. Morozova
Keyword(s):  
Energy Level ◽  
Equilibrium State ◽  
Thermodynamic Equilibrium ◽  
Local Thermodynamic Equilibrium ◽  
Plasma Jet ◽  
Saha Equation ◽  
Radiation Processes ◽  
Unconventional Method

The degree and nature of the violation of local thermodynamic equilibrium (LTE) in the analytical zone of a plasma jet generated by an argon arc two-jet plasmatron (TJP) was estimated using an unconventional method based on determination of the nonequilibrium parameterbiequal to the ratio of the experimentally determined actual population of the energy level (ni) of the element to the population of the same level calculated from the Saha equation (nis). Partial ionizing deviation of plasma under study from the equilibrium state takes place only when low-lying atomic levels are overpopulated. The distinct dependence ofbion the ionization potential of the considered element (e.g., Ca, Mg, and Be) is shown. The results were interpreted in the light of the increasing role of radiation processes upon excitation of spectra in the argon arc two-jet plasmatron.

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