Intensity and kinetics of the fluorescence of vapors of complex organic compounds in a mixture with foreign gases excited with an electron beam

1987 ◽  
Vol 46 (6) ◽  
pp. 573-579 ◽  
Author(s):  
V. V. Gruzinskii ◽  
S. V. Davydov ◽  
A. V. Kukhto
Author(s):  
J. Drucker ◽  
R. Sharma ◽  
J. Kouvetakis ◽  
K.H.J. Weiss

Patterning of metals is a key element in the fabrication of integrated microelectronics. For circuit repair and engineering changes constructive lithography, writing techniques, based on electron, ion or photon beam-induced decomposition of precursor molecule and its deposition on top of a structure have gained wide acceptance Recently, scanning probe techniques have been used for line drawing and wire growth of W on a silicon substrate for quantum effect devices. The kinetics of electron beam induced W deposition from WF6 gas has been studied by adsorbing the gas on SiO2 surface and measuring the growth in a TEM for various exposure times. Our environmental cell allows us to control not only electron exposure time but also the gas pressure flow and the temperature. We have studied the growth kinetics of Au Chemical vapor deposition (CVD), in situ, at different temperatures with/without the electron beam on highly clean Si surfaces in an environmental cell fitted inside a TEM column.


1998 ◽  
Vol 38 (1) ◽  
pp. 87-95 ◽  
Author(s):  
M. Roš ◽  
J. Vrtovšek

A combined anaerobic anoxic aerobic reactor for the treatment of the industrial wastewater that contains nitrogen and complex organic compounds as well as its design procedure is presented. The purpose of our experiments was to find a simple methodology that would provide combined reactor design. The reactor is based on the combination of anaerobic, anoxic and aerobic process in one unit only. It was found that the HRT even under 1 hour in the anaerobic zone is long enough for the efficient transformation of complex organic compounds into readily biodegradable COD which is then used in dentrification process. In the N-NO3 concentration range 1.5-50 mg/l the denitrification rate could be expressed as half-order reaction when the CODrb was in excess. N-NO3 removal efficiency is controlled by the recycle flow from the aerobic to the anoxic zone. Nitrification rate can be expressed as first, half or zero-order reaction with respect to effluent N-NH4 concentration. Nitrification rate depends on the dissolved oxygen concentration and hydrodynamic conditions in the reactor. Case study for design of a pilot plant of the combined reactor for treatment of pre-treated pharmaceutical wastewater is shown. Characteristics of pre-treated wastewater were: COD=200 mg/l, BOD5=20 mg/l, N-Kjeldahl=80 mg/l, N-NH4=70 mg/l, N-NOx<1 mg/l, P-PO4=5 mg/l. Legal requirements for treated wastewater were: COD=<100 mg/l, BOD5<5 mg/l, N-NH4=<1 mg/l, N-NOx=<10 mg/l.


Nukleonika ◽  
2017 ◽  
Vol 62 (3) ◽  
pp. 235-240 ◽  
Author(s):  
Henrietta Nichipor ◽  
Yongxia Sun ◽  
Andrzej G. Chmielewski

Abstract Theoretical study of NOx removal from humid air by a hybrid system (catalyst combined with electron beam) was carried out. The purpose of this work is to study the possibility to decrease energy consumption for NOx removal. The kinetics of radiation catalytic oxidation of NO on the catalyst TiO2 surface under electron beam irradiation was elaborated. Program Scilab 5.3.0 was used for numerical simulations. Influential parameters such as inlet NO concentration, dose, gas fl ow rate, water concentration and catalyst contents that can affect NOx removal efficiency were studied. The results of calculation show that the removal efficiency of NOx might be increased by 8-16% with the presence of a catalyst in the gas irradiated field.


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