The effect of carbon black filling and cross-linking in stretched SBR networks: a 2H-NMR study

1991 ◽  
Vol 25 (3) ◽  
pp. 365-371 ◽  
Author(s):  
G. Simon
Keyword(s):  
2H Nmr ◽  
Langmuir ◽  
2021 ◽  
Author(s):  
Suhad Sbeih ◽  
Priti S. Mohanty ◽  
Anand Yethiraj ◽  
Michael R. Morrow

ChemInform ◽  
2010 ◽  
Vol 22 (25) ◽  
pp. no-no
Author(s):  
C. A. KLUG ◽  
C. P. SLICHTER ◽  
J. H. SINFELT
Keyword(s):  
2H Nmr ◽  

2011 ◽  
Vol 100 (3) ◽  
pp. 627a
Author(s):  
Catherine Tardy-Laporte ◽  
Alexandre A. Arnold ◽  
Isabelle Marcotte

1971 ◽  
Vol 44 (1) ◽  
pp. 199-213 ◽  
Author(s):  
Gerard Kraus

Abstract It is shown that various modulus values of carbon black reinforced rubber are functions of the product of the actual black loading and a structure dependent factor. The structure factor appears to be a linear function of the so-called 24M4 value of the dibutylphthalate absorption and is independent of elongation, temperature, and degree of cross-linking over the ranges covered by the data reported. An interpretation of the results is offered based on the idea of polymer occluded in the interstices of primary structure aggregates and thereby shielded from deformation. Structure-concentration equivalence can only be demonstrated with carbon blacks differing in (primary) structure alone. Deviations are observed whenever the carbon blacks compared vary significantly in specific surface area and surface chemical activity.


Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1992 ◽  
Author(s):  
Alexey Kondyurin ◽  
Anastasia Eliseeva ◽  
Alexander Svistkov

A model of rubber with a cross-linked rubber layer on a carbon black filler has been proposed. The cross-links are the result of free radical reactions generated by carbon atoms with unpaired electrons at the edge of graphitic sheets in a carbon black filler. The experimental study of the cross-linking reactions in polyisoprene was done on a flat carbonized surface after ion beam implantation. The cross-linking process in the polyisoprene macromolecules between two particles was simulated. The model with a cross-linked rubber layer on a carbon filler as a “glassy layer” explains the mechanical properties of the rubber materials.


1988 ◽  
Vol 88 (4) ◽  
pp. 2139-2147 ◽  
Author(s):  
Th. Dries ◽  
F. Fujara ◽  
M. Kiebel ◽  
E. Rössler ◽  
H. Sillescu
Keyword(s):  
2H Nmr ◽  

1978 ◽  
Vol 32a ◽  
pp. 1-5 ◽  
Author(s):  
Bo Berglund ◽  
Jörgen Tegenfeldt ◽  
Hilda Kvila ◽  
Arne F. Andresen ◽  
Olav Smidsrød ◽  
...  
Keyword(s):  
2H Nmr ◽  

1977 ◽  
Vol 28 (2) ◽  
pp. 313-316 ◽  
Author(s):  
Werner Niederberger ◽  
Yves Tricot
Keyword(s):  
2H Nmr ◽  

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