Iron(II) Complexes of Chiral Tridentate Nitrogen Donors and their Application in Catalytic Hydrosilylation Reactions

Cedric Groß; Andreas Omlor; Tobias Grimm; Benjamin Oelkers; Yu Sun; Volker Schünemann; Werner R. Thiel

doi:10.1002/zaac.201900310

Iron(II) Complexes of Chiral Tridentate Nitrogen Donors and their Application in Catalytic Hydrosilylation Reactions

Zeitschrift für anorganische und allgemeine Chemie ◽

10.1002/zaac.201900310 ◽

2020 ◽

Vol 646 (13) ◽

pp. 968-977

Author(s):

Cedric Groß ◽

Andreas Omlor ◽

Tobias Grimm ◽

Benjamin Oelkers ◽

Yu Sun ◽

...

Keyword(s):

Nitrogen Donors ◽

Catalytic Hydrosilylation

Download Full-text

Catalytic hydrosilylation of olefins and ketones by base metal complexes bearing a 2,2′:6′,2″-terpyridine ancillary ligand

Inorganica Chimica Acta ◽

10.1016/j.ica.2021.120403 ◽

2021 ◽

Vol 523 ◽

pp. 120403

Author(s):

Katsuaki Kobayashi ◽

Hiroshi Nakazawa

Keyword(s):

Metal Complexes ◽

Base Metal ◽

Ancillary Ligand ◽

Catalytic Hydrosilylation

Download Full-text

Synthesis and characterization of a series of macrocyclic chelates containing oxygen and nitrogen donors: prospects for use as NMR shift agents for alkali-metal cations

Inorganic Chemistry ◽

10.1021/ic00344a006 ◽

1990 ◽

Vol 29 (19) ◽

pp. 3645-3649 ◽

Cited By ~ 25

Author(s):

R. Merritt Sink ◽

Douglas C. Buster ◽

A. Dean Sherry

Keyword(s):

Alkali Metal ◽

Metal Cations ◽

Synthesis And Characterization ◽

Alkali Metal Cations ◽

Nitrogen Donors

Download Full-text

Hydridosilylamido complexes of Ta and Mo isolobal with Berry's zirconocenes: syntheses, β-Si–H agostic interactions, catalytic hydrosilylation, and insight into mechanism

Dalton Transactions ◽

10.1039/c5dt04548g ◽

2016 ◽

Vol 45 (6) ◽

pp. 2554-2561 ◽

Cited By ~ 3

Author(s):

Nicolas A. McLeod ◽

Lyudmila G. Kuzmina ◽

Ilia Korobkov ◽

Judith A. K. Howard ◽

Georgii I. Nikonov

Keyword(s):

Resting State ◽

Mechanistic Studies ◽

Catalytic Hydrosilylation ◽

Insight Into

The β-SiH agostic complex (ArN)2Mo{η3-N(tBu)SiMe2–H}H is a pre-catalyst for hydrosilylation of carbonyls. Mechanistic studies revealed a non-hydride mechanism, with the benzoxy complex 8 being the resting state.

Download Full-text

Displacement of neutral nitrogen donors by chloride in [Pt(SNS)(R-py)](ClO4)2 (SNS=2,6-bis(methylthiomethyl)pyridine; R-py=pyridines): A reactivity comparison between meta- and para-substituted pyridines

Polyhedron ◽

10.1016/j.poly.2008.04.031 ◽

2008 ◽

Vol 27 (11) ◽

pp. 2259-2264 ◽

Cited By ~ 4

Author(s):

Bruno Pitteri ◽

Marco Bortoluzzi

Keyword(s):

Substituted Pyridines ◽

Nitrogen Donors

Download Full-text

Catalytic Hydrosilylation of Alkenes by Iron Complexes Containing Terpyridine Derivatives as Ancillary Ligands

Organometallics ◽

10.1021/om300279t ◽

2012 ◽

Vol 31 (10) ◽

pp. 3825-3828 ◽

Cited By ~ 99

Author(s):

Kouji Kamata ◽

Atsuko Suzuki ◽

Yuta Nakai ◽

Hiroshi Nakazawa

Keyword(s):

Iron Complexes ◽

Ancillary Ligands ◽

Catalytic Hydrosilylation

Download Full-text

ChemInform Abstract: Polymer Supported Ferrocene Derivatives. Catalytic Hydrosilylation of Olefins by Supported Palladium and Platinum Complexes.

ChemInform ◽

10.1002/chin.198811295 ◽

1988 ◽

Vol 19 (11) ◽

Author(s):

W. R. CULLEN ◽

N. F. HAN

Keyword(s):

Platinum Complexes ◽

Ferrocene Derivatives ◽

Palladium And Platinum Complexes ◽

Supported Palladium ◽

Polymer Supported ◽

Catalytic Hydrosilylation

Download Full-text

Fe and Co Complexes of Rigidly Planar Phosphino-Quinoline-Pyridine Ligands for Catalytic Hydrosilylation and Dehydrogenative Silylation

Organometallics ◽

10.1021/acs.organomet.8b00416 ◽

2018 ◽

Vol 37 (16) ◽

pp. 2760-2768 ◽

Cited By ~ 12

Author(s):

Debashis Basu ◽

Ryan Gilbert-Wilson ◽

Danielle L. Gray ◽

Thomas B. Rauchfuss ◽

Aswini K. Dash

Keyword(s):

Pyridine Ligands ◽

Catalytic Hydrosilylation

Download Full-text

Synthesis and Characterization of a 1,3-Phenylene-Bridged N-Alkyl Bis(benzimidazole) CCC-NHC Pincer Ligand Precursor: Homobimetallic Silver and Rhodium Complexes and the Catalytic Hydrosilylation of Phenylacetylene

Organometallics ◽

10.1021/om3008037 ◽

2012 ◽

Vol 32 (1) ◽

pp. 63-69 ◽

Cited By ~ 33

Author(s):

Aron J. Huckaba ◽

T. Keith Hollis ◽

Tyler O. Howell ◽

Henry U. Valle ◽

Yunshan Wu

Keyword(s):

Synthesis And Characterization ◽

Rhodium Complexes ◽

Pincer Ligand ◽

Catalytic Hydrosilylation

Download Full-text

Complexes of chromium(III), cobalt(II) and copper(II) with sulphur or oxygen and nitrogen donors

Transition Metal Chemistry ◽

10.1007/bf01022338 ◽

1987 ◽

Vol 12 (2) ◽

pp. 128-130 ◽

Cited By ~ 12

Author(s):

Pilar Souza ◽

Fabi�n S�nchez-Kaiser ◽

Jos� R. Masaguer ◽

Agueda Arquero

Keyword(s):

Nitrogen Donors

Download Full-text

Catalytic Hydrosilylation of Carbonyls via Re(CO)5Cl Photolysis

Organometallics ◽

10.1021/om2012634 ◽

2012 ◽

Vol 31 (10) ◽

pp. 3880-3887 ◽

Cited By ~ 7

Author(s):

Chun Keong Toh ◽

Yin Ngai Sum ◽

Wai Kit Fong ◽

Siau Gek Ang ◽

Wai Yip Fan

Keyword(s):

Catalytic Hydrosilylation

Download Full-text