Catalytic Hydrosilylation of Carbonyls via Re(CO)5Cl Photolysis

2012 ◽  
Vol 31 (10) ◽  
pp. 3880-3887 ◽  
Author(s):  
Chun Keong Toh ◽  
Yin Ngai Sum ◽  
Wai Kit Fong ◽  
Siau Gek Ang ◽  
Wai Yip Fan
Keyword(s):  
Catalytic Hydrosilylation

Hydridosilylamido complexes of Ta and Mo isolobal with Berry's zirconocenes: syntheses, β-Si–H agostic interactions, catalytic hydrosilylation, and insight into mechanism

2016 ◽  
Vol 45 (6) ◽  
pp. 2554-2561 ◽  
Author(s):  
Nicolas A. McLeod ◽  
Lyudmila G. Kuzmina ◽  
Ilia Korobkov ◽  
Judith A. K. Howard ◽  
Georgii I. Nikonov
Keyword(s):  
Resting State ◽  
Mechanistic Studies ◽  
Catalytic Hydrosilylation ◽  
Insight Into

The β-SiH agostic complex (ArN)2Mo{η3-N(tBu)SiMe2–H}H is a pre-catalyst for hydrosilylation of carbonyls. Mechanistic studies revealed a non-hydride mechanism, with the benzoxy complex 8 being the resting state.

Catalytic Hydrosilylation of Alkenes by Iron Complexes Containing Terpyridine Derivatives as Ancillary Ligands

2012 ◽  
Vol 31 (10) ◽  
pp. 3825-3828 ◽  
Author(s):  
Kouji Kamata ◽  
Atsuko Suzuki ◽  
Yuta Nakai ◽  
Hiroshi Nakazawa
Keyword(s):  
Iron Complexes ◽  
Ancillary Ligands ◽  
Catalytic Hydrosilylation

Fe and Co Complexes of Rigidly Planar Phosphino-Quinoline-Pyridine Ligands for Catalytic Hydrosilylation and Dehydrogenative Silylation

2018 ◽  
Vol 37 (16) ◽  
pp. 2760-2768 ◽  
Author(s):  
Debashis Basu ◽  
Ryan Gilbert-Wilson ◽  
Danielle L. Gray ◽  
Thomas B. Rauchfuss ◽  
Aswini K. Dash
Keyword(s):  
Pyridine Ligands ◽  
Catalytic Hydrosilylation

scholarly journals The design of second generation MOP-phosphonites: efficient chiral hydrosilylation of functionalised styrenes

2016 ◽  
Vol 45 (5) ◽  
pp. 1886-1890 ◽  
Author(s):  
James T. Fleming ◽  
Arne Ficks ◽  
Paul G. Waddell ◽  
Ross W. Harrington ◽  
Lee J. Higham
Keyword(s):  
Second Generation ◽  
Secondary Alcohols ◽  
Catalytic Hydrosilylation

A series of enantiopure MOP-phosphonite ligands, with tailored steric profiles, have been synthesised and are proven to be very successful in high-yielding, regio- and enantioselective catalytic hydrosilylation reactions of substituted styrenes, affording important chiral secondary alcohols.

scholarly journals Carboxylate-Functionalized P, N-Ligated Cobalt Catalysts for Alkene Hydrosilylation

2020 ◽  
Vol 17 ◽  
Author(s):  
Yangyang Ma ◽  
Jiayun Li ◽  
Ying Bai ◽  
Jiajian Peng
Keyword(s):  
Activation Energy ◽  
Reaction Time ◽  
Efficient Method ◽  
Cobalt Catalysts ◽  
Carboxyl Groups ◽  
Catalytic Hydrosilylation ◽  
P Ligands

: A series of N, P-ligands bearing carboxyl groups has been synthesized. These have been applied in conjunction with cobalt naphthenate in a facile, economic, and efficient method for the catalytic hydrosilylation of alkenes. In the presence of KOtBu as an additive, the reaction time and activation energy are greatly reduced.

Sign in / Sign up

Export Citation Format

Share Document