Gallium Coordination Polymers Based on Bis-pyridylethylene Containing Neutral and Cationic 1D Chains and 2D Networks

2018 ◽  
Vol 644 (24) ◽  
pp. 1791-1795 ◽  
Author(s):  
Thomas Schäfer ◽  
Klaus Müller-Buschbaum
Keyword(s):  
Coordination Polymers ◽  
1D Chains

A series of divalent metal coordination polymers based on isomeric tetracarboxylic acids: synthesis, structures and magnetic properties

2014 ◽  
Vol 43 (46) ◽  
pp. 17519-17527 ◽  
Author(s):  
Min-Le Han ◽  
Ya-Ping Duan ◽  
Dong-Sheng Li ◽  
Guo-Wang Xu ◽  
Ya-Pan Wu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
Divalent Metal ◽  
Metal Coordination ◽  
3D Network ◽  
Supramolecular Networks ◽  
Metal Coordination Polymers ◽  
1D Chains

A series of M(ii) coordination polymers has been synthesized. 1–3 contain 1D infinite chains, and these 1D chains are further linked by hydrogen bonding to form 3D supramolecular networks. While 4 and 5 show tetra- or penta-nodal 3D network, respectively.

Synthesis, Structure, and Visible Phosphorescence Emission of Novel CuI Coordination Polymers Based on 4,4′-Bis(3-pyridyl)-2,2′-bis(hydroxylmethyl) Biphenyl

2015 ◽  
Vol 68 (2) ◽  
pp. 307 ◽  
Author(s):  
Guo-Xia Jin ◽  
Jian-Ping Ma ◽  
Chuan-Zhi Sun ◽  
Yu-Bin Dong
Keyword(s):  
Coordination Polymers ◽  
Density Functional ◽  
Room Temperature ◽  
Emission Spectra ◽  
Density Functional Theory Calculations ◽  
X Ray Diffraction ◽  
Ligand Charge Transfer ◽  
Yellow Orange ◽  
The Difference ◽  
1D Chains

Four new CuI coordination polymers, [(CuCl)L]n (1), {[(CuCl)2L2]·(H2O)}n (2), [(CuBr)L]n (3), and {[(CuBr)2L2]·(H2O)}n (4), were obtained from a new ligand 4,4′-bis(3-pyridyl)-2,2′-bis(hydroxylmethyl) biphenyl (L) and characterized by single-crystal X-ray diffraction. In 1 and 3, the rhombic [Cu2(μ-X)2] units are connected to each other by the bidentate linkers to form an infinite 1D double chain (X = Cl, Br). Such 1D chains are arranged into a 2D sheet through inter-chain π···π interactions. In 2 and 4, there are similar 1D double chains, but different inter-chain arrangement. Such 1D chains are connected into a 2D layer and further arranged in an ABAB fashion through O–H···X hydrogen bonds. The emission spectra and lifetimes in the microsecond range were measured at room temperature and at 77 K. Complexes 1 and 3 exhibit strong orange and yellow–orange emission in the solid state at room temperature, and were assigned to X-and M-to-ligand charge transfer excited states based on density functional theory calculations. The emission property of 2 and 4 was distinctly different from that of 1 and 3, probably due to the difference in coordination environments of the CuI centres as well as the dissimilar intermolecular arrangement.

scholarly journals [M(C5O5)2(H2O)n]2−as a Building Block for Hetero- and Homo-bimetallic Coordination Polymers: From 1D Chains to 3D Supramolecular Architectures

2009 ◽  
Vol 9 (2) ◽  
pp. 1013-1019 ◽  
Author(s):  
Chih-Chieh Wang ◽  
Meu-Ju Ke ◽  
Cheng-Hsiao Tsai ◽  
I-Hsuan Chen ◽  
Shin-I Lin ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Building Block ◽  
Supramolecular Architectures ◽  
1D Chains

1D chains, 2D networks and 3D interdigitated frameworks of isoorotic acid or 4,4′-bipyridyl and isoorotic acid: syntheses, structures, and sorption properties

2015 ◽  
Vol 2 (3) ◽  
pp. 278-289 ◽  
Author(s):  
Ritesh Haldar ◽  
K. L. Gurunatha ◽  
Nivedita Sikdar ◽  
Tapas Kumar Maji
Keyword(s):  
Transition Metals ◽  
Coordination Polymers ◽  
Sorption Properties ◽  
1D Chains

Five new coordination polymers, from 1D chains to a 2D sheet and finally 3D porous frameworks, have been synthesized with different transition metals. The 3D interdigitated framework of Ni(ii) is explored further for stepwise CO2 and C2H2 storage.

scholarly journals Coordination Polymers in Dicyanamido-Cadmium(II) with Diverse Network Dimensionalities

Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 181
Author(s):  
Franz A. Mautner ◽  
Patricia V. Jantscher ◽  
Roland C. Fischer ◽  
Ana Torvisco ◽  
Klaus Reichmann ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Coordination Polymer ◽  
Coordination Polymers ◽  
Structural Characterization ◽  
Mononuclear Complex ◽  
3D Network ◽  
Polymeric Chains ◽  
1D Chains ◽  
3D Networks

The synthesis and structural characterization of six dicyanamido-cadmium(II) complexes are reported: catena-[Cd(μ1,3-dca)(μ1,5-dca)(3-ampy)] (1), catena-[Cd3(μ1,3,5-dca)2(μ1,5-dca)4(pyNO)2(H2O)2] (2), catena-{Cd(H2O)2(μ1,5-dca)2](2,6-lut-NO)} (3), catena-[Cd(Me2en)(μ1,5-dca)2] (4), catena-[Cd(Me4en)(μ1,5-dca)2] (5), and [Cd(1,8-damnp)2(dca)2] (6), where dca = dicyanamide anion, 3-ampy = 3-aminopyridine, pyNO = pyridine-N-oxide, 2,6-lut-NO = 2,6-lutidine-N-oxide, Me2en = N,N-dimethyl-ethylenediamine, Me4en = N,N,N′,N′-tetramethyl-ethylenediamine, and 1,8-damnp = 1,8-diaminonaphthaline. The coordination polymers have different dimensionalities: 1 and 5 form 3D networks structures; 3 and 4 form polymeric 1D chains and 1DD double chains, respectively. Ribbons of three fused polymeric chains are observed in 2. In 6, the mononuclear complex units form a hydrogen-bonded supramolecular 3D network. In the coordination polymer compounds, the dca linkers display three bonding modes: the most common μ1,5-dca and the least popular μ1,3- and μ1,3,5-dca bonding. The luminescence emission and thermal properties of the complexes were investigated.

Multi-Dimensional Transition-Metal Coordination Polymers of 4,4′-Bipyridine-N,N′-dioxide: 1D Chains and 2D Sheets

2008 ◽  
Vol 47 (19) ◽  
pp. 8652-8664 ◽  
Author(s):  
Junhua Jia ◽  
Alexander J. Blake ◽  
Neil R. Champness ◽  
Peter Hubberstey ◽  
Claire Wilson ◽  
...  
Keyword(s):  
Transition Metal ◽  
Coordination Polymers ◽  
Metal Coordination ◽  
Metal Coordination Polymers ◽  
1D Chains

scholarly journals Effect of anion on Ag(i)meso-helical chains formed with 4,4′-dipyridyl ketone: solventversusanion bridging and anion effects on the strength of ligand binding

CrystEngComm ◽  
2014 ◽  
Vol 16 (21) ◽  
pp. 4587-4601 ◽  
Author(s):  
Komal M. Patil ◽  
Scott A. Cameron ◽  
Stephen C. Moratti ◽  
Lyall R. Hanton
Keyword(s):  
Ligand Binding ◽  
Coordination Polymers ◽  
Dipyridyl Ketone ◽  
1D Chains

Related coordination polymers with varying Ag : L ratios produced a series (1 : 1) that was not sensitive to anion and another (1 : 2) that displayed sensitivity to the anion showing a transition from 1D chains to 2D nets.

Sign in / Sign up

Export Citation Format

Share Document