1D chains, 2D networks and 3D interdigitated frameworks of isoorotic acid or 4,4′-bipyridyl and isoorotic acid: syntheses, structures, and sorption properties

2015 ◽  
Vol 2 (3) ◽  
pp. 278-289 ◽  
Author(s):  
Ritesh Haldar ◽  
K. L. Gurunatha ◽  
Nivedita Sikdar ◽  
Tapas Kumar Maji

Five new coordination polymers, from 1D chains to a 2D sheet and finally 3D porous frameworks, have been synthesized with different transition metals. The 3D interdigitated framework of Ni(ii) is explored further for stepwise CO2 and C2H2 storage.

2015 ◽  
Vol 2 (2) ◽  
pp. 136-140 ◽  
Author(s):  
Xiao-Lin Qi ◽  
Jia-Wen Ye ◽  
Rui-Biao Lin ◽  
Pei-Qin Liao ◽  
Si-Yang Liu ◽  
...  

Two genuine supramolecular isomers with a unique type of structural difference and completely different porous properties have been synthesized and characterized.


2014 ◽  
Vol 43 (46) ◽  
pp. 17519-17527 ◽  
Author(s):  
Min-Le Han ◽  
Ya-Ping Duan ◽  
Dong-Sheng Li ◽  
Guo-Wang Xu ◽  
Ya-Pan Wu ◽  
...  

A series of M(ii) coordination polymers has been synthesized. 1–3 contain 1D infinite chains, and these 1D chains are further linked by hydrogen bonding to form 3D supramolecular networks. While 4 and 5 show tetra- or penta-nodal 3D network, respectively.


2006 ◽  
Vol 79 (10) ◽  
pp. 1593-1599 ◽  
Author(s):  
G. R. Anpilogova ◽  
A. I. Vorob’eva ◽  
S. A. Onina ◽  
R. A. Khisamutdinov ◽  
Yu. I. Murinov ◽  
...  

CrystEngComm ◽  
2014 ◽  
Vol 16 (33) ◽  
pp. 7790-7801 ◽  
Author(s):  
Tao Ding ◽  
Li-Di Ren ◽  
Xiao-Di Du ◽  
Li Quan ◽  
Zi-Wei Gao ◽  
...  

Using a rigid ligand, pyridine-3,5-bis(phenyl-4-carboxylic) acid, six new coordination polymers have been synthesized and characterized, and their magnetic, photoluminescence and gas adsorption properties have been studied.


CrystEngComm ◽  
2013 ◽  
Vol 15 (9) ◽  
pp. 1689 ◽  
Author(s):  
Libo Li ◽  
Jiangfeng Yang ◽  
Qiang Zhao ◽  
Jinping Li

2015 ◽  
Vol 68 (2) ◽  
pp. 307 ◽  
Author(s):  
Guo-Xia Jin ◽  
Jian-Ping Ma ◽  
Chuan-Zhi Sun ◽  
Yu-Bin Dong

Four new CuI coordination polymers, [(CuCl)L]n (1), {[(CuCl)2L2]·(H2O)}n (2), [(CuBr)L]n (3), and {[(CuBr)2L2]·(H2O)}n (4), were obtained from a new ligand 4,4′-bis(3-pyridyl)-2,2′-bis(hydroxylmethyl) biphenyl (L) and characterized by single-crystal X-ray diffraction. In 1 and 3, the rhombic [Cu2(μ-X)2] units are connected to each other by the bidentate linkers to form an infinite 1D double chain (X = Cl, Br). Such 1D chains are arranged into a 2D sheet through inter-chain π···π interactions. In 2 and 4, there are similar 1D double chains, but different inter-chain arrangement. Such 1D chains are connected into a 2D layer and further arranged in an ABAB fashion through O–H···X hydrogen bonds. The emission spectra and lifetimes in the microsecond range were measured at room temperature and at 77 K. Complexes 1 and 3 exhibit strong orange and yellow–orange emission in the solid state at room temperature, and were assigned to X-and M-to-ligand charge transfer excited states based on density functional theory calculations. The emission property of 2 and 4 was distinctly different from that of 1 and 3, probably due to the difference in coordination environments of the CuI centres as well as the dissimilar intermolecular arrangement.


2015 ◽  
Vol 2 (5) ◽  
pp. 485-485
Author(s):  
Ritesh Haldar ◽  
K. L. Gurunatha ◽  
Nivedita Sikdar ◽  
Tapas Kumar Maji

Correction for ‘1D chains, 2D networks and 3D interdigitated frameworks of isoorotic acid or 4,4′-bipyridyl and isoorotic acid: syntheses, structures, and sorption properties’ by Ritesh Haldar et al., Inorg. Chem. Front., 2015, 2, 278–289.


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