Preparation, Crystal Structure, and Thermal Decomposition of Two Novel Energetic Compounds [Ni(IMI)6](L)2 (L = ClO4- and NO3-) and one Carbonate Compound [Ni(IMI)6](CO3)·5H2O (IMI = Imidazole)

2011 ◽  
Vol 637 (14-15) ◽  
pp. 2252-2259 ◽  
Author(s):  
Bi-Dong Wu ◽  
Shi-Wei Wang ◽  
Li Yang ◽  
Tong-Lai Zhang ◽  
Jian-Guo Zhang ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thermal Decomposition ◽  
Energetic Compounds

ChemInform Abstract: BaN3Cl: Synthesis, Crystal Structure, Vibrational Spectra and Thermal Decomposition of Barium Azide Chloride.

ChemInform ◽  
2009 ◽  
Vol 40 (2) ◽  
Author(s):  
Bjoern Blaschkowski ◽  
Harald Balzer ◽  
Hans-Lothar Keller ◽  
Thomas Schleid
Keyword(s):  
Crystal Structure ◽  
Thermal Decomposition ◽  
Vibrational Spectra

Studies on (non) energetic compounds. Part-14: Thermal decomposition of dimethylanilinium chlorides

1999 ◽  
Vol 338 (1-2) ◽  
pp. 45-55 ◽  
Author(s):  
Gurdip Singh ◽  
Inder Pal Singh Kapoor ◽  
Jaspreet Kaur
Keyword(s):  
Thermal Decomposition ◽  
Energetic Compounds

On the dimorphism of Pr6Mo10O39

2017 ◽  
Vol 72 (11) ◽  
pp. 765-774
Author(s):  
Daniel Rudolph ◽  
Sonja Laufer ◽  
Ingo Hartenbach
Keyword(s):  
Crystal Structure ◽  
Thermal Decomposition ◽  
Single Crystals ◽  
Main Product ◽  
Molar Ratio ◽  
Coordination Environment ◽  
Space Group ◽  
Coordination Numbers ◽  
Dense Modification

AbstractAttempts to synthesize Pr4Mo7O27 using Pr, Pr6O11 and MoO3 in a molar ratio of 8:6:77 led to a main product of scheelite-type Pr0.667[MoO4] and few single crystals of the triclinic A-type Pr6Mo10O39. The latter crystallizes in space group P1̅ (a=945.25(1), b=1058.49(2), c=1815.16(3) pm; α=104.149(1), β=95.220(1), γ=102.617(1)°, Z=2). Its crystal structure comprises six crystallographically independent Pr3+ cations, eight tetrahedral [MoO4]2− units, and one [Mo2O7]2− entity. The cations display coordination numbers of seven (1×) and eight (5×), while the [MoO4]2− tetrahedra are surrounded by five Pr3+ cations each. The [Mo2O7]2− anions exhibit a coordination environment of seven Pr3+ cations. The attempt to synthesize PrF[MoO4] using PrOF (from in situ thermal decomposition of PrF[CO3]) as reagent did not lead to the desired product but to monoclinic B-type Pr6Mo10O39. This slightly less dense modification compared to its triclinic analogue crystallizes in space group C2/c (a=1247.93(3), b=1989.68(6), c=1392.52 (4) pm, β=100.505(2)°, Z=4) with three crystallographically independent Pr3+ cations, four [MoO4]2− tetrahedra, and again one [Mo2O7]2− unit in the crystal structure. Thus, both Pr6Mo10O39 modifications are better described with the structured formula Pr6[MoO4]8[Mo2O7]. The coordination numbers around the Pr3+ cations are seven (1×) and eight (2×) while all four [MoO4]2− anions are again surrounded by five Pr3+ cations each. Six of the latter represent the coordination environment around the [Mo2O7]2− entities. Besides the thorough comparison of the crystal structures single crystal Raman spectra were recorded for both Pr6Mo10O39 phases.

Crystal structure and thermal decomposition kinetics of a 2D coordination polymer of cadmium(II)

2008 ◽  
Vol 61 (20) ◽  
pp. 3237-3244 ◽  
Author(s):  
Ying-Xia Zhou ◽  
Si-Yin Liu ◽  
Xiao-Qing Shen ◽  
Hong-Yun Zhang ◽  
Ya-Hui Yu
Keyword(s):  
Crystal Structure ◽  
Thermal Decomposition ◽  
Coordination Polymer ◽  
Decomposition Kinetics ◽  
Thermal Decomposition Kinetics ◽  
Kinetics Of

scholarly journals Ferrocene-containing energetic compounds as ammonium perchlorate thermal decomposition ballistic modifiers

2017 ◽  
Vol 0 (17) ◽  
pp. 75-85
Author(s):  
Виктория В. Дороган ◽  
Елена Ю. Нестерова ◽  
Елена С. Косицина
Keyword(s):  
Thermal Decomposition ◽  
Ammonium Perchlorate ◽  
Energetic Compounds ◽  
Ballistic Modifiers

Preparation, Crystal Structure, and Thermal Decomposition of the Four-coordinated Zinc Compound Based on 1,5-Diaminotetrazole

2013 ◽  
Vol 639 (7) ◽  
pp. 1248-1253 ◽  
Author(s):  
Bi-Dong Wu ◽  
Fu-Gang Li ◽  
Tong-Lai Zhang ◽  
Li Yang ◽  
Zun-Ning Zhou ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thermal Decomposition ◽  
Zinc Compound
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