Two Novel Cobalt(II) Coordination Polymers Based on the Herbicide Glyphosate as a Building Block and their Magnetic Properties

2008 ◽  
Vol 634 (11) ◽  
pp. 1991-1995 ◽  
Author(s):  
Guang-Fan Han ◽  
Hui-Zhou Luo ◽  
Qiong Ye ◽  
Ren-Gen Xiong
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Building Block ◽  
Herbicide Glyphosate

scholarly journals New Cyanido-Bridged Heterometallic 3d-4f 1D Coordination Polymers: Synthesis, Crystal Structures and Magnetic Properties

2021 ◽  
Vol 7 (5) ◽  
pp. 57
Author(s):  
Diana Dragancea ◽  
Ghenadie Novitchi ◽  
Augustin M. Mădălan ◽  
Marius Andruh
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Building Block ◽  
Condensation Reaction ◽  
Slow Relaxation ◽  
Block Approach

Three new 1D cyanido-bridged 3d-4f coordination polymers, {[Gd(L)(H2O)2Fe(CN)6]·H2O}n (1GdFe), {[Dy(L)(H2O)2Fe(CN)6]·3H2O}n (2DyFe), and {[Dy(L)(H2O)2Co(CN)6]·H2O}n (3DyCo), were assembled following the building-block approach (L = pentadentate bis-semicarbazone ligand resulting from the condensation reaction between 2,6-diacetyl-pyridine and semicarbazide). The crystal structures consist of crenel-like LnIII-MIII alternate chains, with the LnIII ions connected by the hexacyanido metalloligands through two cis cyanido groups. The magnetic properties of the three complexes have been investigated. Field-induced slow relaxation of the magnetization was observed for compounds 2DyFe and 3DyCo. Compound 3DyCo is a new example of chain of Single Ion Magnets.

scholarly journals Two-electron redox-active tricyano iron(ii) complex with 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine as a building block for coordination polymers

2018 ◽  
Vol 47 (38) ◽  
pp. 13402-13407 ◽  
Author(s):  
Takuya Shiga ◽  
Haruka Miyamoto ◽  
Graham N. Newton ◽  
Hiroki Oshio
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Building Block ◽  
Building Unit ◽  
Redox Active

A new tricyano iron(ii) building unit and three coordination polymers were synthesized, and their structures and magnetic properties were investigated.

The Influence of Diamagnetic Substrates Absorption on Magnetic Properties of Porous Coordination Polymers

2013 ◽  
Vol 3 (2) ◽  
pp. 144-160 ◽  
Author(s):  
Sergey Kolotilov ◽  
Mikhail Kiskin ◽  
Igor Eremenko ◽  
Vladimir Novotortsev
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Porous Coordination Polymers

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

scholarly journals Two Co(II) coordination polymers: magnetic properties and application values against chronic subdural hematoma

2021 ◽  
Vol 24 (1) ◽  
pp. 199-207
Author(s):  
Jing-Sen Chen ◽  
Sheng-Long Cao ◽  
Hai-Ying Hu ◽  
Juan Shen ◽  
Yu-Jun Qi
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Subdural Hematoma ◽  
Chronic Subdural Hematoma
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