First NiII–LnIII Coordination Polymers Constructed by Using [Ni(bpca)2] as a Building Block [Hbpca = bis(2-pyridylcarbonyl)amine]: Synthesis, Crystal Structures and Magnetic Properties

2007 ◽  
Vol 2007 (35) ◽  
pp. 5533-5540 ◽  
Author(s):  
Augustin M. Madalan ◽  
Kevin Bernot ◽  
Fabrice Pointillart ◽  
Marius Andruh ◽  
Andrea Caneschi
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Building Block

scholarly journals New Cyanido-Bridged Heterometallic 3d-4f 1D Coordination Polymers: Synthesis, Crystal Structures and Magnetic Properties

2021 ◽  
Vol 7 (5) ◽  
pp. 57
Author(s):  
Diana Dragancea ◽  
Ghenadie Novitchi ◽  
Augustin M. Mădălan ◽  
Marius Andruh
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Building Block ◽  
Condensation Reaction ◽  
Slow Relaxation ◽  
Block Approach

Three new 1D cyanido-bridged 3d-4f coordination polymers, {[Gd(L)(H2O)2Fe(CN)6]·H2O}n (1GdFe), {[Dy(L)(H2O)2Fe(CN)6]·3H2O}n (2DyFe), and {[Dy(L)(H2O)2Co(CN)6]·H2O}n (3DyCo), were assembled following the building-block approach (L = pentadentate bis-semicarbazone ligand resulting from the condensation reaction between 2,6-diacetyl-pyridine and semicarbazide). The crystal structures consist of crenel-like LnIII-MIII alternate chains, with the LnIII ions connected by the hexacyanido metalloligands through two cis cyanido groups. The magnetic properties of the three complexes have been investigated. Field-induced slow relaxation of the magnetization was observed for compounds 2DyFe and 3DyCo. Compound 3DyCo is a new example of chain of Single Ion Magnets.

Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties

Polyhedron ◽  
2014 ◽  
Vol 79 ◽  
pp. 129-137 ◽  
Author(s):  
Danica Čechová ◽  
Alena Martišková ◽  
Zdeňka Padělková ◽  
Lukáš Gal’a ◽  
L’ubor Dlháň ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
One Dimensional

One-dimensional and two-dimensional coordination polymers constructed from copper(II) nodes and polycarboxylato spacers: Synthesis, crystal structures and magnetic properties

Polyhedron ◽  
2008 ◽  
Vol 27 (2) ◽  
pp. 574-582 ◽  
Author(s):  
Cristian D. Ene ◽  
Floriana Tuna ◽  
Oscar Fabelo ◽  
Catalina Ruiz-Pérez ◽  
Augustin M. Madalan ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Two Dimensional ◽  
One Dimensional
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