Carbon Spheres: Seeded Synthesis of Monodisperse Core-Shell and Hollow Carbon Spheres (Small 32/2016)

Small ◽  
2016 ◽  
Vol 12 (32) ◽  
pp. 4301-4301
Author(s):  
Luz Karime Gil-Herrera ◽  
Álvaro Blanco ◽  
Beatriz H. Juárez ◽  
Cefe López
2016 ◽  
Vol 52 (78) ◽  
pp. 11693-11696 ◽  
Author(s):  
Lei Liu ◽  
Shi-Da Xu ◽  
Qing Yu ◽  
Feng-Yun Wang ◽  
Hui-Ling Zhu ◽  
...  

Nitrogen-doped hollow carbon spheres with a wrinkled surface were synthesized through direct pyrolysis of core–shell structured graphene oxide–resol@melamine formaldehyde composites.


2014 ◽  
Vol 2 (18) ◽  
pp. 6343-6347 ◽  
Author(s):  
Zang Jun ◽  
Chen Jia-jia ◽  
Zhang Cheng-long ◽  
Qian Hang ◽  
Zheng Ming-sen ◽  
...  

A hierarchical core–shell MnO2/3D-ordered hollow carbon sphere composite was designed and synthesized by using hollow carbon spheres (HCS) as a carbon matrix.


Small ◽  
2016 ◽  
Vol 12 (32) ◽  
pp. 4357-4362 ◽  
Author(s):  
Luz Karime Gil-Herrera ◽  
Álvaro Blanco ◽  
Beatriz H. Juárez ◽  
Cefe López

Sensors ◽  
2018 ◽  
Vol 18 (12) ◽  
pp. 4429 ◽  
Author(s):  
Ruiping Luo ◽  
Zijie Feng ◽  
Guannan Shen ◽  
Yi Xiu ◽  
Yukun Zhou ◽  
...  

The present study investigated the synthesis of mesoporous hollow carbon spheres (MHCS) and magnetic mesoporous hollow carbon spheres with core-shell structures (Fe3O4@MHCS). Two acetylcholinesterase sensors (acetylcholinesterase/mesoporous hollow carbon spheres/glassy carbon electrode (AChE/MHCS/GCE) and acetylcholinesterase/core-shell magnetic mesoporous hollow carbon spheres/glassy carbon electrode (AChE/Fe3O4@MHCS/GCE) based on mesoporous carbon materials were prepared. Under the optimum conditions, using Malathion as the model compound, the developed biosensors showed a wide detection range, low detection limit, good reproducibility, and high stability. The AChE/MHCS/GCE electrochemical sensor response exhibited two good linear ranges at the incubation time of 10 min at the Malathion concentration ranges of 0.01 to 100 ppb and 100 to 600 ppb, with a detection limit of 0.0148 ppb (S/N = 3). The AChE/Fe3O4@MHCS/GCE electrochemical sensor that was operated with an incubation time of 12 min at the malathion concentration ranges between 0.01–50 ppb and 50–600 ppb had a detection limit of 0.0182 ppb (S/N = 3). Moreover, the AChE/MHCS/GCE and AChE/Fe3O4@MHCS/GCE biosensors were effective for the detection of real samples, and were demonstrated to be suitable for the field-testing of organophosphorus pesticide (OP) residues.


2018 ◽  
Vol 42 (16) ◽  
pp. 13619-13628 ◽  
Author(s):  
Hamed Akbarzadeh ◽  
Mohsen Abbaspour ◽  
Esmat Mehrjouei ◽  
Samira Ramezanzadeh

We have simulated bare Ag/Au nanoclusters and Ag/Au nanoclusters encapsulated into hollow carbon spheres (AgAu@C) with various structures (core–shell, hollow core–shell, rattle core–shell, and alloy nanoclusters) from 300 to 700 K.


MRS Advances ◽  
2020 ◽  
Vol 5 (57-58) ◽  
pp. 2961-2972
Author(s):  
P.C. Meléndez-González ◽  
E. Garza-Duran ◽  
J.C. Martínez-Loyola ◽  
P. Quintana-Owen ◽  
I.L. Alonso-Lemus ◽  
...  

In this work, low-Pt content nanocatalysts (≈ 5 wt. %) supported on Hollow Carbon Spheres (HCS) were synthesized by two routes: i) colloidal conventional polyol, and ii) surfactant-free Bromide Anion Exchange (BAE). The nanocatalysts were labelled as Pt/HCS-P and Pt/HCS-B for polyol and BAE, respectively. The physicochemical characterization of the nanocatalysts showed that by following both methods, a good control of chemical composition was achieved, obtaining in addition well dispersed nanoparticles of less than 3 nm TEM average particle size (d) on the HCS. Pt/HCS-B contained more Pt0 species than Pt/HCS-P, an effect of the synthesis method. In addition, the structure of the HCS remains more ordered after BAE synthesis, compared to polyol. Regarding the catalytic activity for the Oxygen Reduction Reaction (ORR) in 0.5 M KOH, Pt/HCS-P and Pt/HCS-B showed a similar performance in terms of current density (j) at 0.9 V vs. RHE than the benchmark commercial 20 wt. % Pt/C. However, Pt/HCS-P and Pt/HCS-B demonstrated a 6 and 5-fold increase in mass catalytic activity compared to Pt/C, respectively. A positive effect of the high specific surface area of the HCS and its interactions with metal nanoparticles and electrolyte, which promoted the mass transfer, increased the performance of Pt/HCS-P and Pt/HCS-B. The high catalytic activity showed by Pt/HCS-B and Pt/HCS-P for the ORR, even with a low-Pt content, make them promising cathode nanocatalysts for Anion Exchange Membrane Fuel Cells (AEMFC).


2021 ◽  
Vol 506 ◽  
pp. 230170
Author(s):  
Lantao Liu ◽  
Xiangyu Sun ◽  
Yue Dong ◽  
Dengke Wang ◽  
Zheng Wang ◽  
...  

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