Chiroptically Active Plasmonic Nanoparticles Having Hidden Helicity and Reversible Aqueous Solvent Effect on Chiroptical Activity

Small ◽  
2016 ◽  
Vol 12 (42) ◽  
pp. 5902-5909 ◽  
Author(s):  
Junjun Liu ◽  
Lin Yang ◽  
Zhifeng Huang
Keyword(s):  
Solvent Effect ◽  
Plasmonic Nanoparticles ◽  
Aqueous Solvent ◽  
Aqueous Solvent Effect

A powerful aqueous solvent effect in an intramolecular Diels-Alder cyclisation

2004 ◽  
Vol 2004 (9) ◽  
pp. 608-610 ◽  
Author(s):  
Nikolai Kuhnert ◽  
Peter G. Sammes ◽  
Graham Smith ◽  
Robert W. Ward
Keyword(s):  
Solvent Effect ◽  
Diels Alder ◽  
Aqueous Solvent ◽  
Aqueous Solvent Effect

A Powerful Aqueous Solvent Effect in an Intramolecular Diels?Alder Cyclization.

ChemInform ◽  
2005 ◽  
Vol 36 (12) ◽  
Author(s):  
Nikolai Kuhnert ◽  
Peter G. Sammes ◽  
Graham Smith ◽  
Robert W. Ward
Keyword(s):  
Solvent Effect ◽  
Diels Alder ◽  
Aqueous Solvent ◽  
Aqueous Solvent Effect

Kinetic Solvent Effects in Organic Reactions

2017 ◽  
Author(s):  
Belinda Slakman ◽  
Richard West
Keyword(s):  
Solvent Effect ◽  
Reaction Kinetics ◽  
Computational Methods ◽  
High Throughput ◽  
Kinetic Modeling ◽  
Solvent Effects ◽  
Reaction Rates ◽  
Prior Work ◽  
Solvent Phase ◽  
High Throughput Manner

<div> <div> <div> <p>This article reviews prior work studying reaction kinetics in solution, with the goal of using this information to improve detailed kinetic modeling in the solvent phase. Both experimental and computational methods for calculating reaction rates in liquids are reviewed. Previous studies, which used such methods to determine solvent effects, are then analyzed based on reaction family. Many of these studies correlate kinetic solvent effect with one or more solvent parameters or properties of reacting species, but it is not always possible, and investigations are usually done on too few reactions and solvents to truly generalize. From these studies, we present suggestions on how best to use data to generalize solvent effects for many different reaction types in a high throughput manner. </p> </div> </div> </div>

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