Palladium‐Catalyzed One‐Pot Coupling / Cyclization through Mo(CO) 6 as the Carbon Monoxide Donor: Synthesis of Quinazolinones

2020 ◽  
Vol 5 (25) ◽  
pp. 7332-7337
Author(s):  
Shou‐Wei Tao ◽  
Rui‐Qing Liu ◽  
Jing‐Ya Zhou ◽  
Yong‐Ming Zhu
Keyword(s):  
Carbon Monoxide ◽  
One Pot ◽  
Palladium Catalyzed

Synthesis of diversely substituted 2-(furan-3-yl)acetates from allenols through cascade carbonylations

2015 ◽  
Vol 51 (90) ◽  
pp. 16263-16266 ◽  
Author(s):  
Yan He ◽  
Xinying Zhang ◽  
Xuesen Fan
Keyword(s):  
Carbon Monoxide ◽  
One Pot ◽  
Novel Synthesis ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Novel synthesis of diversely substituted 2-(furan-3-yl)acetatesviapalladium-catalyzed one-pot multi-component reactions of allenols, aryl iodides, alcohols, and carbon monoxide has been developed. Moreover, the 2-(furan-3-yl)acetates obtained were found to be ready intermediates for the construction of the biologically significant naphtho[1,2-b]furan-5-ol scaffold.

Palladium-catalyzed carbonylation of 1,5-cyclooctadiene. Effects of temperature and pressure

1991 ◽  
Vol 56 (3) ◽  
pp. 663-672 ◽  
Author(s):  
Curtis B. Anderson ◽  
Rade Marković
Keyword(s):  
Carbon Monoxide ◽  
Oxidative Carbonylation ◽  
Influence Of Temperature ◽  
Carbonylation Reaction ◽  
Palladium Catalyzed ◽  
Effects Of Temperature ◽  
Temperature And Pressure

The influence of temperature and carbon monoxide pressure on the course of oxidative carbonylation reaction of 1,5-cyclooctadiene in the presence of the palladium(II) salts as a catalyst, was investigated.

Intermolecular C–H Amidation of Alkenes with Carbon Monoxide and Azides via Tandem Palladium Catalysis

Synthesis ◽  
2021 ◽  
Author(s):  
Zheng-Yang Gu ◽  
Yang Wu ◽  
Feng Jin ◽  
Bao Xiaoguang ◽  
Ji-Bao Xia
Keyword(s):  
Carbon Monoxide ◽  
Palladium Catalysis ◽  
Computational Studies ◽  
Organic Azides ◽  
Reaction Proceeds ◽  
Palladium Catalyzed ◽  
Directing Group ◽  
And Control

An atom- and step-economic intermolecular multi-component palladium-catalyzed C–H amidation of alkenes with carbon monoxide and organic azides has been developed for the synthesis of alkenyl amides. The reaction proceeds efficiently without an ortho-directing group on the alkene substrates. Nontoxic dinitrogen is generated as the sole by-product. Computational studies and control experiments have revealed that the reaction takes place via an unexpected mechanism by tandem palladium catalysis.

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