Synthetic Methodologies for Chelating Polymer Ligands: Recent Advances and Future Development

2018 ◽  
Vol 3 (46) ◽  
pp. 13234-13270 ◽  
Author(s):  
Gulzhian I. Dzhardimalieva ◽  
Igor E. Uflyand
2020 ◽  
Vol 8 (15) ◽  
pp. 4988-5014 ◽  
Author(s):  
Bing Wang ◽  
Zhi Bin Zhang ◽  
Shi Peng Zhong ◽  
Zhao Qiang Zheng ◽  
Ping Xu ◽  
...  

This review introduces recent advances in the materials, fabrication and application of pulsed-laser deposition for high performance photo-detectors from an overall perspective. Challenges and future development trends are also discussed.


Author(s):  
Praveen P. Singh ◽  
Vishal Srivastava

1,3-Dicyano-2,4,5,6-tetrakis(diphenylamino)-benzene has emerged as a powerful and attractive metal-free organophotocatalyst for organic transformation and is expected to contribute to a great extent toward the advancement and development of synthetic methodologies.


Tetrahedron ◽  
2018 ◽  
Vol 74 (8) ◽  
pp. 811-833 ◽  
Author(s):  
Rajpratap Kshatriya ◽  
Valmik P. Jejurkar ◽  
Satyajit Saha

2020 ◽  
Vol 8 (40) ◽  
pp. 20897-20924 ◽  
Author(s):  
Xue Yang ◽  
Suyuan Zhang ◽  
Peixian Li ◽  
Shuiying Gao ◽  
Rong Cao

In this review, we focus on the most recent advances made in visible-light-driven selective organic oxidation transformations and highlighted their reaction mechanisms. Moreover, we discuss the future development trends, challenges, and prospective outlook in detail.


Molecules ◽  
2020 ◽  
Vol 25 (7) ◽  
pp. 1675 ◽  
Author(s):  
Xiang Gao ◽  
Jiao Liu ◽  
Xin Zuo ◽  
Xinyue Feng ◽  
Ying Gao

Benzothiazoles have played an important role in the field of biochemistry and medicinal chemistry due to their highly pharmaceutical and biological activity. The development of synthetic processes is undoubtedly one of the most significant problems facing researchers. In this review paper, we provided recent advances in the synthesis of benzothiazole compounds related to green chemistry from condensation of 2-aminobenzenethiol with aldehydes/ketones/acids/acyl chlorides and the cyclization of thioamide or carbon dioxide (CO2) as raw materials, and the future development trend and prospect of the synthesis of benzothiazoles were anticipated.


2017 ◽  
Vol 4 (3) ◽  
pp. 303-325 ◽  
Author(s):  
Qinghe Liu ◽  
Chuanfa Ni ◽  
Jinbo Hu

Abstract The new millennium has witnessed the rapid development of synthetic organofluorine chemistry all over the world, and chemists in China have made significant contributions in this field. This review aims to provide a brief introduction to China's primary innovations from 2000 to early 2017, covering fluorination, fluoroalkylation, fluoromethylthiolation, fluoroolefination and polyfluoroarylation, as well as synthesis with fluorinated building blocks. Recent advances in the chemistry of difluorocarbene and the chemistry of carbon–fluorine bond activation are also discussed. As a conclusion, the review ends with some personal perspectives on the future development of China's synthetic organofluorine chemistry.


Molecules ◽  
2021 ◽  
Vol 26 (22) ◽  
pp. 7051
Author(s):  
Lei Zhou

The creation of new bonds via C-F bond cleavage of readily available per- or oligofluorinated compounds has received growing interest. Using such a strategy, a myriad of valuable partially fluorinated products can be prepared, which otherwise are difficult to make by the conventional C-F bond formation methods. Visible light photoredox catalysis has been proven as an important and powerful tool for defluorinative reactions due to its mild, easy to handle, and environmentally benign characteristics. Compared to the classical C-F activation that proceeds via two-electron processes, radicals are the key intermediates using visible light photoredox catalysis, providing new modes for the cleavage of C-F bonds. In this review, a summary of the visible light-promoted C-F bond cleavage since 2018 was presented. The contents were classified by the fluorosubstrates, including polyfluorinated arenes, gem-difluoroalkenes, trifluoromethyl arenes, and trifluoromethyl alkenes. An emphasis is placed on the discussion of the mechanisms and limitations of these reactions. Finally, my personal perspective on the future development of this rapidly emerging field was provided.


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