Preparation and Structure Analysis of Three New Copper Complexes of Mellitic Acid With 4,4′‐Bipyridine and 1,3‐ bis (4‐pyridyl)Propane

2018 ◽  
Vol 3 (3) ◽  
pp. 855-858 ◽  
Author(s):  
Manishkumar R. Shimpi ◽  
Lopamudra Giri ◽  
Venkateswara Rao Pedireddi
1994 ◽  
Vol 49 (10) ◽  
pp. 1410-1414 ◽  
Author(s):  
Rolf W. Saalfrank ◽  
Oliver Struck ◽  
Karl Peters ◽  
Hans Georg von Schnering

Abstract Depolymerisation of a copper(II)/pyrrolidine-based 2D -polymer 2 by 4,4′-bipyridyl [molar ratio: 2 (CuL2) : 1 (Bipy)] and recrystallisation of the reaction product leads to two visually distinguishable crystal charges, composed of dark green octahedra meso-4 and light green rod-shaped crystals racem-5. Separation of the conglomerate of the morphologically different crystals is accomplished by pick out. The structure of the dinuelear complex racem-5 has been established unambigously by X-ray structure analysis. EPR and susceptibility measurements of mixtures of complex meso-4 and racem-5 indicate that there is no interaction be­tween the two copper(II) centres.


2007 ◽  
Vol 46 (13) ◽  
pp. 5137-5139 ◽  
Author(s):  
Satoshi Abe ◽  
Takafumi Ueno ◽  
Pattubala A. N. Reddy ◽  
Seiji Okazaki ◽  
Tatsuo Hikage ◽  
...  

1999 ◽  
Vol 54 (3) ◽  
pp. 337-340 ◽  
Author(s):  
Henri Brunner ◽  
Manfred Muschiol ◽  
Thomas Neuhierl ◽  
Bernhard Nuber

The reaction of CuCl with [CP2MoH2] yields the complex [Cu(Cp2MoH2)2Cl]. An X-ray structure analysis shows that the coordination of the copper(I) ion by two [CP2MoH2] ligands and the chloride ion is pseudo-trigonal planar. The hydride ligands were located by using difference Fourier methods. A manifold of reactions took place when an aqueous solution of CUSO4 was treated with a solution of [Cp2MoH2] in dichloromethane in a 1:2 molar ratio. The X-ray structure analysis established a polymeric structure of the complex [Cu(Cp2MoH2)2Cu(Cp2MoH2)SO4]n with two different copper centers.


Author(s):  
M. Iwatsuki ◽  
Y. Kokubo ◽  
Y. Harada ◽  
J. Lehman

In recent years, the electron microscope has been significantly improved in resolution and we can obtain routinely atomic-level high resolution images without any special skill. With this improvement, the structure analysis of organic materials has become one of the interesting targets in the biological and polymer crystal fields.Up to now, X-ray structure analysis has been mainly used for such materials. With this method, however, great effort and a long time are required for specimen preparation because of the need for larger crystals. This method can analyze average crystal structure but is insufficient for interpreting it on the atomic or molecular level. The electron microscopic method for organic materials has not only the advantage of specimen preparation but also the capability of providing various information from extremely small specimen regions, using strong interactions between electrons and the substance. On the other hand, however, this strong interaction has a big disadvantage in high radiation damage.


1997 ◽  
Vol 94 ◽  
pp. 1695-1714 ◽  
Author(s):  
P Lesot ◽  
F Perez ◽  
P Judeinstein ◽  
JP Bayle ◽  
H Allouchi ◽  
...  

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