Structural analysis of O-glycopeptides employing negative- and positive-ion multi-stage mass spectra obtained by collision-induced and electron-capture dissociations in linear ion trap time-of-flight mass spectrometry

2007 ◽  
Vol 21 (5) ◽  
pp. 691-698 ◽  
Author(s):  
Kisaburo Deguchi ◽  
Hiroki Ito ◽  
Takashi Baba ◽  
Atsumu Hirabayashi ◽  
Hiroaki Nakagawa ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Structural Analysis ◽  
Electron Capture ◽  
Mass Spectra ◽  
Ion Trap ◽  
Time Of Flight ◽  
Linear Ion Trap ◽  
Flight Mass Spectrometry ◽  
Multi Stage ◽  
Positive Ion

Application of Liquid Chromatography/Quadrupole-Linear Ion Trap Mass Spectrometry and Time-of-Flight Mass Spectrometry to the Determination of Pharmaceuticals and Related Contaminants in Wastewater

2007 ◽  
Vol 79 (24) ◽  
pp. 9372-9384 ◽  
Author(s):  
María Jesús Martínez Bueno ◽  
Ana Agüera ◽  
María José Gómez ◽  
María Dolores Hernando ◽  
Juan Francisco García-Reyes ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Liquid Chromatography ◽  
Ion Trap ◽  
Time Of Flight ◽  
Ion Trap Mass Spectrometry ◽  
Linear Ion Trap ◽  
Flight Mass Spectrometry ◽  
Quadrupole Linear Ion Trap

Capillary ionic liquid electrospray: beam compositional analysis by orthogonal time-of-flight mass spectrometry

2021 ◽  
Vol 928 ◽  
Author(s):  
S.W. Miller ◽  
J.R. Ulibarri-Sanchez ◽  
B.D. Prince ◽  
R.J. Bemish
Keyword(s):  
Mass Spectrometry ◽  
Mass Spectra ◽  
Time Of Flight ◽  
Ion Source ◽  
High Mass ◽  
Atomic Mass Unit ◽  
Flow Rates ◽  
Charged Species ◽  
Flight Mass Spectrometry ◽  
Jet Breakup

Orthogonal time-of-flight mass spectrometry has been used to characterize the kinetic energy and charged species distributions from an in vacuo electrospray ion source for four different ionic liquids at volumetric flow rates between 0.3 and 3.3 nanolitres per second. In all cases, the mass spectra revealed charged species consisting of singly charged and multiply charged ions as well as two broad, unresolved droplet distributions occurring in the 104 to 106 atomic mass unit per charge range. The mean jet velocity and mean jet breakup potential were established from analysis of the energy profile of the high mass-to-charge droplets. At the jet breakup point, we find the energy loss and the jet diameter flow rate dependence of the electrospray beam to be similar to that determined by Gamero-Castaño (Phys. Fluids, vol. 20, 2008, 032103; Phys. Rev. Fluids, vol. 8, 2021, 013701) for 1-ethyl-3-methylimidazolium bis(trifluromethylsulfonyl)imide at similar volumetric flow rates. Similar trends are observed for all four liquids over the flow regime. A jet instability analysis revealed that jet electrification and viscous effects drive the jet breakup from the case of an uncharged, inviscid jet; jet breakup occurs at droplet and jet radius ratios that deviate from 1.89. Using the analytically determined ratio and the beam profile, different species are modelled to reconstruct the mass spectra; primary droplets constitute only a fraction of the total species present. The populations of the species are discussed.

scholarly journals Metabolic profiling putatively identifies plasma biomarkers of male infertility using UPLC-ESI-IT-TOFMS

RSC Advances ◽  
2018 ◽  
Vol 8 (46) ◽  
pp. 25974-25982 ◽  
Author(s):  
F. J. Zeng ◽  
H. C. Ji ◽  
Z. M. Zhang ◽  
J. K. Luo ◽  
H. M. Lu ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Liquid Chromatography ◽  
Male Infertility ◽  
Electrospray Ionization ◽  
Metabolic Profiling ◽  
Ion Trap ◽  
Time Of Flight ◽  
Ultra Performance Liquid Chromatography ◽  
Flight Mass Spectrometry ◽  
Potential Biomarkers

Ultra-performance liquid chromatography-electrospray ionization-ion trap-time of flight mass spectrometry combined with chemometrics methods was used to discover potential biomarkers of male infertility based on untargeted plasma metabolomics.

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