scholarly journals Effective Mechanical Responses of a Class of 2D Chiral Materials

2020 ◽  
Vol 257 (10) ◽  
pp. 2070037
Author(s):  
Yun-Che Wang ◽  
Tsai-Wen Ko ◽  
Xuejun Ren
Keyword(s):  
Mechanical Responses ◽  
Chiral Materials

Effective Mechanical Responses of a Class of 2D Chiral Materials

2020 ◽  
Vol 257 (10) ◽  
pp. 2000277
Author(s):  
Yun-Che Wang ◽  
Tsai-Wen Ko ◽  
Xuejun Ren
Keyword(s):  
Mechanical Responses ◽  
Chiral Materials

Self-Assembly of a Chiral Cubic Three-Connected Net from the High Symmetry Molecules C60 and SnI4

2020 ◽  
Author(s):  
Daniel B. Straus ◽  
Robert J. Cava
Keyword(s):  
Organic Synthesis ◽  
Self Assembly ◽  
Van Der Waals ◽  
Van Der Waals Forces ◽  
High Symmetry ◽  
Molecular Chirality ◽  
Chiral Materials ◽  
Self Assembled ◽  
Chiral Centers

The design of new chiral materials usually requires stereoselective organic synthesis to create molecules with chiral centers. Less commonly, achiral molecules can self-assemble into chiral materials, despite the absence of intrinsic molecular chirality. Here, we demonstrate the assembly of high-symmetry molecules into a chiral van der Waals structure by synthesizing crystals of C<sub>60</sub>(SnI<sub>4</sub>)<sub>2</sub> from icosahedral buckminsterfullerene (C<sub>60</sub>) and tetrahedral SnI4 molecules through spontaneous self-assembly. The SnI<sub>4</sub> tetrahedra template the Sn atoms into a chiral cubic three-connected net of the SrSi<sub>2</sub> type that is held together by van der Waals forces. Our results represent the remarkable emergence of a self-assembled chiral material from two of the most highly symmetric molecules, demonstrating that almost any molecular, nanocrystalline, or engineered precursor can be considered when designing chiral assemblies.

Split beam method for determining mode shapes of cantilever beams under multiple loading conditions

2021 ◽  
pp. 107754632110276
Author(s):  
Jun-Jie Li ◽  
Shuo-Feng Chiu ◽  
Sheng D Chao
Keyword(s):  
Operation Mode ◽  
Point Contact ◽  
Mode Shapes ◽  
Cantilever Beams ◽  
Loading Conditions ◽  
Mechanical Responses ◽  
Relative Contribution ◽  
Resonance Frequencies ◽  
Beam Method ◽  
Multiple Loading

We have developed a general method, dubbed the split beam method, to solve Euler–Bernoulli equations for cantilever beams under multiple loading conditions. This kind of problem is, in general, a difficult inhomogeneous eigenvalue problem. The new idea is to split the original beam into two (or more) effective beams, each of which corresponds to one specific load and bears its own Young’s modulus. The mode shape of the original beam can be obtained by linearly superposing those of the effective beams. We apply the split beam method to simulating mechanical responses of an atomic force microscope probe in the “dynamical” operation mode, under which there are a stabilizing force at the positioner and a point-contact force at the tip. Compared with traditional analytical or numerical methods, the split beam method uses only a few number of basis functions from each effective beam, so a very fast convergence rate is observed in solving both the resonance frequencies and the mode shapes at the same time. Moreover, by examining the superposition coefficients, the split beam method provides a physical insight into the relative contribution of an individual load on the beam.

scholarly journals The spin selectivity effect in chiral materials

APL Materials ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 040902
Author(s):  
D. H. Waldeck ◽  
R. Naaman ◽  
Y. Paltiel
Keyword(s):  
Chiral Materials

scholarly journals Design and Characterization of Microscale Auxetic and Anisotropic Structures Fabricated by Multiphoton Lithography

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 446
Author(s):  
Ioannis Spanos ◽  
Zacharias Vangelatos ◽  
Costas Grigoropoulos ◽  
Maria Farsari
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Mechanical Performance ◽  
Element Analysis ◽  
Mechanical Responses ◽  
Multiphoton Lithography ◽  
Anisotropic Structures ◽  
Scanning Electron

The need for control of the elastic properties of architected materials has been accentuated due to the advances in modelling and characterization. Among the plethora of unconventional mechanical responses, controlled anisotropy and auxeticity have been promulgated as a new avenue in bioengineering applications. This paper aims to delineate the mechanical performance of characteristic auxetic and anisotropic designs fabricated by multiphoton lithography. Through finite element analysis the distinct responses of representative topologies are conveyed. In addition, nanoindentation experiments observed in-situ through scanning electron microscopy enable the validation of the modeling and the observation of the anisotropic or auxetic phenomena. Our results herald how these categories of architected materials can be investigated at the microscale.

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