Viscoelastic behavior of polymers undergoing crosslinking reactions

2007 ◽  
Vol 35 (1) ◽  
pp. 71-76 ◽  
Author(s):  
J. Moacanin ◽  
J. J. Aklonis
Keyword(s):  
Viscoelastic Behavior ◽  
Crosslinking Reactions

scholarly journals Rotational Rheology of Wood Flour Composites Based on Recycled Polyethylene

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2226
Author(s):  
Antonella Patti ◽  
Gianluca Cicala ◽  
Stefano Acierno
Keyword(s):  
Wood Flour ◽  
Viscoelastic Behavior ◽  
Melt Mixing ◽  
Processing Technologies ◽  
Viscoelastic Moduli ◽  
Torque Measurements ◽  
Recycled Polyethylene ◽  
Potential Applications ◽  
Two Phases ◽  
Crosslinking Reactions

In this paper, we study the effect of the addition of wood flour as a filler in a recycled polyethylene (r-PE) in view of its potential applications in 3D printing. The composites, prepared by melt mixing, are characterized with torque measurements performed during the compounding, dynamic rotational rheology, and infrared spectroscopy. Data show that the introduction of wood results in increased viscosity and in sensible viscous heating during the compounding. The r-PE appear to be stable at temperatures up to 180 °C while at higher temperatures the material shows a rheological response characterized by time-increasing viscoelastic moduli that suggests a thermal degradation governed by crosslinking reactions. The compounds (with wood loading up to 50% in wt.) also shows thermal stability at temperatures up to 180 °C. The viscoelastic behavior and the infrared spectra of the r-PE matrix suggests the presence of branches in the macromolecular structure due to the process. Although the addition of wood particles determines increased viscoelastic moduli, a solid-like viscoelastic response is not shown even for the highest wood concentrations. This behavior, due to a poor compatibility and weak interfacial adhesion between the two phases, is however promising in view of common processing technologies as extrusion or injection molding.

scholarly journals An Investigation on the Thermally Induced Compatibilization of SBR and α-Methylstyrene/Styrene Resin

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1267
Author(s):  
Arnaud Wolf ◽  
João Paulo Cosas Fernandes ◽  
Chuanyu Yan ◽  
Reiner Dieden ◽  
Laurent Poorters ◽  
...  
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Solid State ◽  
Viscoelastic Properties ◽  
Viscoelastic Behavior ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Thermally Induced ◽  
And Performance ◽  
Crosslinking Reactions ◽  
Styrene Butadiene

The miscibility between two polymers such as rubbers and performance resins is crucial to achieve given targeted properties in terms of tire performances. To this aim, α-methylstyrene/styrene resin (poly(αMSt-co-St)) are used to modify the viscoelastic behavior of rubbers and to fulfill the requirements of the final applications. The initial aim of this work was to understand the influence of poly(αMSt-co-St) resins blended at different concentrations in a commercial styrene-butadiene rubber (SBR). Interestingly, while studying the viscoelastic properties of SBR blends with poly(αMSt-co-St), crosslinking of the rubber was observed under conditions where it was not expected to happen. Surprisingly, after the crosslinking reactions, the poly(αMSt-co-St) resin was irreversibly miscible with SBR at concentrations far above its immiscibility threshold. A detailed investigation involving characterization technics including solid state nuclear magnetic resonance led to the conclusion that poly(αMSt-co-St) is depolymerizing under heating and can graft onto the chains of SBR. It results in an irreversible compatibilization mechanism between the rubber and the resin.

Nonlinear Viscoelastic Finite Element Analysis of Adhesive Joints

1988 ◽  
Vol 16 (3) ◽  
pp. 146-170 ◽  
Author(s):  
S. Roy ◽  
J. N. Reddy
Keyword(s):  
Finite Element Analysis ◽  
Finite Element ◽  
Viscoelastic Behavior ◽  
Bonded Joints ◽  
Adhesively Bonded ◽  
Element Analysis ◽  
Adhesively Bonded Joints ◽  
Nonlinear Viscoelastic ◽  
Structural Failures ◽  
Updated Lagrangian

Abstract A good understanding of the process of adhesion from the mechanics viewpoint and the predictive capability for structural failures associated with adhesively bonded joints require a realistic modeling (both constitutive and kinematic) of the constituent materials. The present investigation deals with the development of an Updated Lagrangian formulation and the associated finite element analysis of adhesively bonded joints. The formulation accounts for the geometric nonlinearity of the adherends and the nonlinear viscoelastic behavior of the adhesive. Sample numerical problems are presented to show the stress and strain distributions in bonded joints.

Influence of κ-Carrageenan, Modified Starch and Inulin Addition on Rheological and Sensory Properties of Non-fat and Non-added Sugar Dairy Dessert

2020 ◽  
Vol 16 (4) ◽  
pp. 462-469
Author(s):  
Zhaleh Sheidaei ◽  
Bahareh Sarmadi ◽  
Seyede M. Hosseini ◽  
Fardin Javanmardi ◽  
Kianoush Khosravi-Darani ◽  
...  
Keyword(s):  
Storage Modulus ◽  
Loss Modulus ◽  
Viscoelastic Behavior ◽  
Textural Properties ◽  
Complex Viscosity ◽  
Sensory Properties ◽  
Modified Starch ◽  
Consumer Health ◽  
Added Sugar ◽  
Textural Parameters

<P>Background: The high amounts of fat, sugar and calorie existing in dairy desserts can lead to increase the risk of health problems. Therefore, the development of functional and dietary forms of these products can help the consumer health. </P><P> Objective: This study aims to investigate the effects of &#954;-carrageenan, modified starch and inulin addition on rheological and sensory properties of non-fat and non-added sugar dairy dessert. </P><P> Methods: In order to determine the viscoelastic behavior of samples, oscillatory test was carried out and the values of storage modulus (G′), loss modulus (G″), loss angle tangent (tan &#948;) and complex viscosity (&#951;*) were measured. TPA test was used for analysis of the desserts’ texture and textural parameters of samples containing different concentrations of carrageenan, starch and inulin were calculated. </P><P> Results: All treatments showed a viscoelastic gel structure with the storage modulus higher than the loss modulus values. Increasing amounts of &#954;-carrageenan and modified starch caused an increase in G′ and G″ as well as &#951;* and a decrease in tan &#948;. Also, firmness and cohesiveness were enhanced. The trained panelists gave the highest score to the treatment with 0.1% &#954;-carrageenan, 2.5% starch and 5.5% inulin (sucralose as constant = 0.25%) and this sample was the best treatment with desirable attributes for the production of non-fat and non-added sugar dairy dessert. </P><P> Conclusion: It can be concluded that the concentration of &#954;-carrageenan and starch strongly influenced the rheological and textural properties of dairy desserts, whereas the inulin content had little effect on these attributes.</P>

scholarly journals Thermo-Viscoelastic Response of 3D Braided Composites Based on a Novel FsMsFE Method

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 271
Author(s):  
Jun-Jun Zhai ◽  
Xiang-Xia Kong ◽  
Lu-Chen Wang
Keyword(s):  
Finite Element ◽  
Cell Model ◽  
Structural Parameters ◽  
Thermal Relaxation ◽  
Viscoelastic Behavior ◽  
Unit Cell ◽  
Time Dependent ◽  
3D Braided Composites ◽  
Equivalent Time ◽  
Representative Unit Cell

A homogenization-based five-step multi-scale finite element (FsMsFE) simulation framework is developed to describe the time-temperature-dependent viscoelastic behavior of 3D braided four-directional composites. The current analysis was performed via three-scale finite element models, the fiber/matrix (microscopic) representative unit cell (RUC) model, the yarn/matrix (mesoscopic) representative unit cell model, and the macroscopic solid model with homogeneous property. Coupling the time-temperature equivalence principle, multi-phase finite element approach, Laplace transformation and Prony series fitting technology, the character of the stress relaxation behaviors at three scales subject to variation in temperature is investigated, and the equivalent time-dependent thermal expansion coefficients (TTEC), the equivalent time-dependent thermal relaxation modulus (TTRM) under micro-scale and meso-scale were predicted. Furthermore, the impacts of temperature, structural parameters and relaxation time on the time-dependent thermo-viscoelastic properties of 3D braided four-directional composites were studied.

scholarly journals A Highly Versatile Polymer Network Based on Liquid Crystalline Dendrimers

2021 ◽  
Vol 22 (11) ◽  
pp. 5740
Author(s):  
Ramón Cervera-Procas ◽  
José-Luis Serrano ◽  
Ana Omenat
Keyword(s):  
Smart Materials ◽  
Liquid Crystalline ◽  
Organic Dyes ◽  
Polymer Network ◽  
Viscoelastic Behavior ◽  
Diverse Range ◽  
Polymeric Systems ◽  
System A ◽  
Porous Microstructure ◽  
Solvent Molecules

Highly functional macromolecules with a well-defined architecture are the key to designing efficient and smart materials, and these polymeric systems can be tailored for specific applications in a diverse range of fields. Herein, the formation of a new liquid crystalline polymeric network based on the crosslinking of dendrimeric entities by the CuI-catalyzed variant of the Huisgen 1,3-dipolar cycloaddition of azides and alkynes to afford 1,2,3-triazoles is reported. The polymeric material obtained in this way is easy to process and exhibits a variety of properties, which include mesomorphism, viscoelastic behavior, and thermal contraction. The porous microstructure of the polymer network determines its capability to absorb solvent molecules and to encapsulate small molecules, like organic dyes, which can be released easily afterwards. Moreover, all these properties may be easily tuned by modifying the chemical structure of the constituent dendrimers, which makes this system a very interesting one for a number of applications.

Mesomechanical prediction of viscoelastic behavior of asphalt concrete considering effect of aggregate shape

2021 ◽  
Vol 274 ◽  
pp. 122096
Author(s):  
Yiren Sun ◽  
Zhuang Zhang ◽  
Xin Wei ◽  
Cong Du ◽  
Mingyang Gong ◽  
...  
Keyword(s):  
Asphalt Concrete ◽  
Viscoelastic Behavior ◽  
Aggregate Shape
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