scholarly journals Use of N -methyliminodiacetic acid boronate esters in suzuki-miyaura cross-coupling polymerizations of triarylamine and fluorene monomers

2017 ◽  
Vol 55 (17) ◽  
pp. 2798-2806 ◽  
Author(s):  
Andrew B. Foster ◽  
Viktor Bagutski ◽  
Josue I. Ayuso-Carrillo ◽  
Martin J. Humphries ◽  
Michael J. Ingleson ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Boronate Esters ◽  
Methyliminodiacetic Acid

scholarly journals Cyclopentadithiophene polymers synthesised via Suzuki-Miyaura polymerisation of MIDA boronate esters

2020 ◽  
Vol 1 ◽  
Author(s):  
Josue Ayuso-Carrillo
Keyword(s):  
Conjugated Polymers ◽  
Organic Electronics ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Reaction Conditions ◽  
Boronate Esters ◽  
Boronate Ester ◽  
Cross Coupling Reaction ◽  
Synthetic Routes ◽  
Methyliminodiacetic Acid

AbstractCyclopentadithiophene (CPDT), a Csp3-bridged bithiophene heteroaromatic unit, displays interesting properties when it is embedded in the repeating units of π-conjugated polymers, and they are applied in organic electronics devices. Common synthetic routes to CPDT-derived polymers rely on toxic methodologies whilst alternative non-toxic strategies such as the Suzuki-Miyaura reaction have been less studied. In this report we demonstrate that the use of a N-methyliminodiacetic acid (MIDA) boronate ester-derived CPDT monomer allows the efficient formation of poly(cyclopentadithiophene) homopolymer under Suzuki-Miyaura cross-coupling reaction conditions. Thus, the use of MIDA boronate esters might be extended to other organic units to design and construct a plethora of π-conjugated polymers.

ChemInform Abstract: One-Pot C-N/C-C Cross-Coupling of Methyliminodiacetic Acid Boronyl Arenes Enabled by Protective Enolization.

ChemInform ◽  
2013 ◽  
Vol 44 (12) ◽  
pp. no-no
Author(s):  
Jonathan E. Grob ◽  
Michael A. Dechantsreiter ◽  
Ritesh B. Tichkule ◽  
Michael K. Connolly ◽  
Ayako Honda ◽  
...  
Keyword(s):  
Cross Coupling ◽  
One Pot ◽  
Methyliminodiacetic Acid

NHC Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling Reactions of Aryl Boronate Esters with Perfluorobenzenes

2016 ◽  
Vol 81 (13) ◽  
pp. 5789-5794 ◽  
Author(s):  
Jing Zhou ◽  
Johannes H. J. Berthel ◽  
Maximilian W. Kuntze-Fechner ◽  
Alexandra Friedrich ◽  
Todd B. Marder ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Coupling Reactions ◽  
Boronate Esters ◽  
Cross Coupling Reactions

Micelle-Enabled Suzuki–Miyaura Cross-Coupling of Heteroaryl Boronate Esters

2018 ◽  
Vol 83 (14) ◽  
pp. 7523-7527 ◽  
Author(s):  
Pengfei Guo ◽  
Hao Zhang ◽  
Jianguang Zhou ◽  
Fabrice Gallou ◽  
Michael Parmentier ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Boronate Esters

Raman and SERS Spectroscopy of N-Methyliminodiacetic Acid (MIDA)-Protected Boronate Esters

2010 ◽  
Author(s):  
Dana N. Reinemann ◽  
Ashley M. Wright ◽  
Jonathan D. Wolfe ◽  
Gregory S. Tschumper ◽  
Nathan I. Hammer ◽  
...  
Keyword(s):  
Boronate Esters ◽  
Methyliminodiacetic Acid
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