Synthesis of poly(arylene ether ketone)s bearing skeletal crown ether units for cation exchange membranes

2015 ◽  
Vol 53 (23) ◽  
pp. 2786-2793 ◽  
Author(s):  
Bram Zoetebier ◽  
Sinem Tas ◽  
G. Julius Vancso ◽  
Kitty Nijmeijer ◽  
Mark A. Hempenius
Keyword(s):  
Crown Ether ◽  
Cation Exchange ◽  
Arylene Ether ◽  
Ether Ketone

scholarly journals Ion-Selective Ionic Polymer Metal Composite (IPMC) Actuator Based on Crown Ether Containing Sulfonated Poly(Arylene Ether Ketone)

2016 ◽  
Vol 302 (4) ◽  
pp. 1600381 ◽  
Author(s):  
Sinem Tas ◽  
Bram Zoetebier ◽  
Ozlem Sardan Sukas ◽  
Muharrem Bayraktar ◽  
Mark Hempenius ◽  
...  
Keyword(s):  
Crown Ether ◽  
Metal Composite ◽  
Ionic Polymer Metal Composite ◽  
Ionic Polymer ◽  
Arylene Ether ◽  
Polymer Metal ◽  
Ether Ketone ◽  
Sulfonated Poly

scholarly journals Monovalent cation selective crown ether containing poly(arylene ether ketone)/SPEEK blend membranes

RSC Advances ◽  
2016 ◽  
Vol 6 (60) ◽  
pp. 55635-55642 ◽  
Author(s):  
Sinem Tas ◽  
Bram Zoetebier ◽  
Mark A. Hempenius ◽  
G. Julius Vancso ◽  
Kitty Nijmeijer
Keyword(s):  
Crown Ether ◽  
Main Chain ◽  
Monovalent Cation ◽  
Arylene Ether ◽  
Ether Ether Ketone ◽  
Monovalent Ions ◽  
Poly Ether Ether Ketone ◽  
Blend Membranes ◽  
Ether Ketone ◽  
Sulfonated Poly

Crown ether units incorporated in the poly(arylene ether ketone) (PAEK) main chain enhance the miscibility of PAEK with sulfonated poly(ether ether ketone) (SPEEK). The resulting blend membranes enable the separation of monovalent ions.

Enhanced CO2 permeability of thermal crosslinking membrane via sulfonation/desulfonation of phenolphthalein-based cardo poly(arylene ether ketone)

2020 ◽  
Vol 598 ◽  
pp. 117824 ◽  
Author(s):  
Ruisong Xu ◽  
Lin Li ◽  
Mengjie Hou ◽  
Jiajia Xue ◽  
Yuzhe Liu ◽  
...  
Keyword(s):  
Arylene Ether ◽  
Thermal Crosslinking ◽  
Ether Ketone

scholarly journals Sulfonated Binaphthyl-Containing Poly(arylene ether ketone)s with Rigid Backbone and Excellent Film-Forming Capability for Proton Exchange Membranes

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1287 ◽  
Author(s):  
Wenmeng Zhang ◽  
Shaoyun Chen ◽  
Dongyang Chen ◽  
Zhuoliang Ye
Keyword(s):  
Mechanical Properties ◽  
Proton Conductivity ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Thermal Stabilities ◽  
Chemical Structures ◽  
Arylene Ether ◽  
Film Forming ◽  
Ether Ketone ◽  
Microscopic Morphology

Sterically hindered (S)-1,1′-binaphthyl-2,2′-diol had been successfully copolymerized with 4,4′-sulfonyldiphenol and 4,4′-difluorobenzophenone to yield fibrous poly(arylene ether ketone)s (PAEKs) containing various amounts of binaphthyl unit, which was then selectively and efficiently sulfonated using ClSO3H to yield sulfonated poly(arylene ether ketone)s (SPAEKs) with ion exchange capacities (IECs) ranging from 1.40 to 1.89 mmol·g−1. The chemical structures of the polymers were confirmed by 2D 1H–1H COSY NMR and FT-IR. The thermal properties, water uptake, swelling ratio, proton conductivity, oxidative stability and mechanical properties of SPAEKs were investigated in detail. It was found that the conjugated but non-coplanar structure of binaphthyl unit endorsed excellent solubility and film-forming capability to SPAEKs. The SPAEK-50 with an IEC of 1.89 mmol·g−1 exhibited a proton conductivity of 102 mS·cm−1 at 30 °C, much higher than that of the state-of-the-art Nafion N212 membrane and those of many previously reported aromatic analogs, which may be attributed to the likely large intrinsic free volume of SPAEKs created by the highly twisted chain structures and the desirable microscopic morphology. Along with the remarkable water affinity, thermal stabilities and mechanical properties, the SPAEKs were demonstrated to be promising proton exchange membrane (PEM) candidates for potential membrane separations.

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