RAFT copolymerization of methacrylic acid and poly(ethylene glycol) methyl ether methacrylate in the presence of a hydrophobic chain transfer agent in organic solution and in water

2009 ◽  
Vol 47 (12) ◽  
pp. 3045-3055 ◽  
Author(s):  
David Rinaldi ◽  
Thierry Hamaide ◽  
Christian Graillat ◽  
Franck D'Agosto ◽  
Roger Spitz ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Methyl Ether ◽  
Methacrylic Acid ◽  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Poly Ethylene Glycol ◽  
Organic Solution ◽  
Hydrophobic Chain ◽  
Poly Ethylene ◽  
Glycol Methyl Ether

scholarly journals Facile preparation of hybrid vesicles loaded with silica nanoparticles via aqueous photoinitiated polymerization-induced self-assembly

RSC Advances ◽  
2017 ◽  
Vol 7 (37) ◽  
pp. 23114-23121 ◽  
Author(s):  
Jianbo Tan ◽  
Dongdong Liu ◽  
Xuechao Zhang ◽  
Chundong Huang ◽  
Jun He ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Silica Nanoparticles ◽  
Methyl Ether ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Chain Transfer ◽  
Poly Ethylene Glycol ◽  
Facile Preparation ◽  
Poly Ethylene ◽  
Glycol Methyl Ether

We report a photoinitiated dispersion polymerization of 2-hydroxypropyl methacrylate (HPMA) in the presence of silica nanoparticles using a poly(ethylene glycol) methyl ether (mPEG) macromolecular chain transfer agent (macro-CTA).

Thermoresponsive copolymers of methacrylic acid and poly(ethylene glycol) methyl ether methacrylate

2005 ◽  
Vol 43 (23) ◽  
pp. 6095-6104 ◽  
Author(s):  
Janevieve A. Jones ◽  
Noel Novo ◽  
Kendra Flagler ◽  
Christina D. Pagnucco ◽  
Steve Carew ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Methyl Ether ◽  
Methacrylic Acid ◽  
Poly Ethylene Glycol ◽  
Poly Ethylene ◽  
Glycol Methyl Ether

scholarly journals Synthesis of Michael Acceptor Ionomers of Poly(4-Sulfonated Styrene-co-Poly(ethylene Glycol) Methyl Ether Acrylate)

2009 ◽  
Vol 62 (11) ◽  
pp. 1496 ◽  
Author(s):  
Steevens N. S. Alconcel ◽  
Gregory N. Grover ◽  
Nicholas M. Matsumoto ◽  
Heather D. Maynard
Keyword(s):  
Ethylene Glycol ◽  
Methyl Ether ◽  
Chain Transfer ◽  
Solvent System ◽  
Poly Ethylene Glycol ◽  
Polymer Backbone ◽  
Water Solvent ◽  
Michael Acceptor ◽  
Poly Ethylene ◽  
Glycol Methyl Ether

Ionomers containing sodium 4-styrene sulfonate (4SS) and poly(ethylene glycol) methyl ether acrylate (PEGA) were synthesized by reversible addition–fragmentation chain transfer (RAFT) polymerization. The polymerization was mediated by 1-phenylethyl dithiobenzoate chain transfer agent in a dimethylformamide/water solvent system. Well-defined copolymers of pPEGA-co-4SS were produced with molecular weights ranging from 10 to 40 kDa and polydispersity indices of 1.06–1.18 by gel permeation chromatography against monodisperse poly(methyl methacrylate) standards. After polymerization, the dithioester was reduced and trapped in situ with divinyl sulfone to produce a well-defined, semitelechelic pPEGA-co-4SS Michael acceptor polymer. UV-visible, infrared, and 1H NMR spectroscopy confirmed that the integrity of the polymer backbone was maintained and that the vinyl sulfone was successfully incorporated at the chain end.

Magnetite nanoparticles stabilized with polymeric bilayer of poly(ethylene glycol) methyl ether–poly(ɛ-caprolactone) copolymers

Polymer ◽  
2008 ◽  
Vol 49 (18) ◽  
pp. 3950-3956 ◽  
Author(s):  
Siraprapa Meerod ◽  
Gamolwan Tumcharern ◽  
Uthai Wichai ◽  
Metha Rutnakornpituk
Keyword(s):  
Ethylene Glycol ◽  
Methyl Ether ◽  
Magnetite Nanoparticles ◽  
Poly Ethylene Glycol ◽  
Poly Ethylene ◽  
Glycol Methyl Ether

The role of hydrogen bonding in alginate/poly(acrylamide-co-dimethylacrylamide) and alginate/poly(ethylene glycol) methyl ether methacrylate-based tough hybrid hydrogels

RSC Advances ◽  
2015 ◽  
Vol 5 (71) ◽  
pp. 57678-57685 ◽  
Author(s):  
Zhi Wei Low ◽  
Pei Lin Chee ◽  
Dan Kai ◽  
Xian Jun Loh
Keyword(s):  
Hydrogen Bonding ◽  
Elastic Modulus ◽  
Ethylene Glycol ◽  
Methyl Ether ◽  
Poly Ethylene Glycol ◽  
Hybrid Hydrogels ◽  
Poly Ethylene ◽  
Glycol Methyl Ether ◽  
Poly Acrylamide

Hybrid hydrogels, with an elastic modulus and compressive toughness of 350 kPa and 70 J m−3, was synthesized and reported here.

The Influences of Monomer Structure and Solvent on the Radical Copolymerization of Tertiary Amine and PEGylated Methacrylates

2021 ◽  
Author(s):  
Priscila Quiñonez-Angulo ◽  
Robin Hutchinson ◽  
Angel Licea-Claverie ◽  
Enrique Saldivar ◽  
Ivan Zapata-Gonzalez
Keyword(s):  
Ethylene Glycol ◽  
Methyl Ether ◽  
Tertiary Amine ◽  
Radical Copolymerization ◽  
Poly Ethylene Glycol ◽  
Ethyl Methacrylate ◽  
Monomer Structure ◽  
Poly Ethylene ◽  
Glycol Methyl Ether

Tertiary Amine Methacrylates (TAMAs), such as 2-(N,N-diethylamino)ethyl methacrylate (DEAEMA) and 2-(N,N-dimethylamino)ethyl methacrylate (DMAEMA), and PEGylated (macro)monomers, such as 2-ethoxyethyl methacrylate (EEMA1) and poly(ethylene glycol) methyl ether methacrylates with 9 and...

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