Synthesis of fluorene-based high performance polymers. I. Poly(arylene thioether)s with excellent solubility and high refractive index

2007 ◽  
Vol 45 (14) ◽  
pp. 3073-3082 ◽  
Author(s):  
Surasak Seesukphronrarak ◽  
Shinichi Kawasaki ◽  
Kana Kobori ◽  
Toshikazu Takata
Keyword(s):  
Refractive Index ◽  
High Performance ◽  
High Refractive Index ◽  
High Performance Polymers

High-performance bifacial semitransparent organic photovoltaics featuring a decently transparent TeO2/Ag electrode

2021 ◽  
Author(s):  
Xin Liu ◽  
Yunsen Zhao ◽  
Jiangsheng Yu ◽  
Rihong Zhu
Keyword(s):  
Refractive Index ◽  
Organic Photovoltaics ◽  
High Performance ◽  
High Refractive Index ◽  
Transparent Electrodes ◽  
Tellurium Oxide ◽  
Ag Electrode ◽  
Limited Choice

The development of bifacial semitransparent organic photovoltaics (ST-OPVs) is hindered by the limited choice of proper rear transparent electrodes. Herein, tellurium oxide (TeO2) featuring a high refractive index and negligible...

scholarly journals Plasmonic Sensing Characteristics of Gold Nanorods with Large Aspect Ratios

Sensors ◽  
2018 ◽  
Vol 18 (10) ◽  
pp. 3458 ◽  
Author(s):  
Chao Zhuang ◽  
Yifan Xu ◽  
Ningsheng Xu ◽  
Jinxiu Wen ◽  
Huanjun Chen ◽  
...  
Keyword(s):  
Refractive Index ◽  
Gold Nanorods ◽  
High Performance ◽  
Near Infrared ◽  
High Refractive Index ◽  
Surface Enhanced Raman Spectroscopy ◽  
Sers Substrate ◽  
Refractive Index Sensitivity ◽  
Aspect Ratios ◽  
Plasmonic Sensing

Plasmonic gold nanorods play important roles in nowadays state-of-the-art plasmonic sensing techniques. Most of the previous studies and applications focused on gold nanorods with relatively small aspect ratios, where the plasmon wavelengths are smaller than 900 nm. Gold nanorods with large aspect ratios are predicted to exhibit high refractive-index sensitivity (Langmir 2008, 24, 5233–5237), which therefore should be promising for the development of high-performance plasmonic chemical- and bio-sensors. In this study, we developed gold nanorods with aspect ratios over 7.9, which exhibit plasmon resonances around 1064 nm. The refractive index (RI) sensitivity of these nanorods have been evaluated by varying their dielectric environment, whereby a sensitivity as high as 473 nm/RIU (refractive index unit) can be obtained. Furthermore, we have demonstrated the large-aspect-ratio nanorods as efficient substrate for surface enhanced Raman spectroscopy (SERS), where an enhancement factor (EF) as high as 9.47 × 108 was measured using 4-methylbenzenethiol (4-MBT) as probe molecule. Finally, a type of flexible SERS substrate is developed by conjugating the gold nanorods with the polystyrene (PS) polymer. The results obtained in our study can benefit the development of plasmonic sensing techniques utilized in the near-infrared spectral region.

scholarly journals Plasmonic Sensing Characteristics of Gold Nanorods with Large Aspect Ratios

2018 ◽  
Author(s):  
Chao Zhuang ◽  
Yifan Xu ◽  
Ningsheng Xu ◽  
Jinxiu Wen ◽  
Huanjun Chen ◽  
...  
Keyword(s):  
Refractive Index ◽  
Gold Nanorods ◽  
High Performance ◽  
Near Infrared ◽  
High Refractive Index ◽  
Surface Enhanced Raman Spectroscopy ◽  
Sers Substrate ◽  
Refractive Index Sensitivity ◽  
Aspect Ratios ◽  
Plasmonic Sensing

Plasmonic gold nanorods play important roles in nowadays state-of-the-art plasmonic sensing techniques. Most of the previous studies and applications focused on gold nanorods with relatively small aspect ratios, where the plasmon wavelengths are smaller than 900 nm. Gold nanorods with large aspect ratios are predicted to exhibit high refractive-index sensitivity (Langmir 2008, 24, 5233–5237.), which therefore should be promising for developing of high-performance plasmonic chemical- and bio-sensors. In this study, we developed gold nanorods with aspect ratios over 7.9, which exhibit plasmon resonances around 1064 nm. The refractive index (RI) sensitivity of these nanorods have been evaluated by varying their dielectric environment, whereby a sensitivity as high as 473 nm/RIU can be obtained. Furthermore, we have demonstrated the large-aspect-ratio nanorods as efficient substrate for surface enhanced Raman spectroscopy (SERS), where an enhancement factor (EF) as high as 9.47×108 was measured using 4-methylbenzenethiol (4-MBT) as probe molecule. Finally, a type of flexible SERS substrate is developed by conjugating the gold nanorods with the polystyrene (PS) polymer. The results obtained in our study can benefit the development of plasmonic sensing techniques utilized in the near-infrared spectral region.

High-performance lens antenna using high refractive index metamaterials

2018 ◽  
Vol 27 (8) ◽  
pp. 087802 ◽  
Author(s):  
Lai-Jun Wang ◽  
Qiao-Hong Chen ◽  
Fa-Long Yu ◽  
Xi Gao
Keyword(s):  
Refractive Index ◽  
High Performance ◽  
High Refractive Index ◽  
Lens Antenna

Two-stage self-seeding method for preparation of single crystals of poly(phenylene sulfide)

1989 ◽  
Vol 47 ◽  
pp. 368-369
Author(s):  
Sengshiu Chung ◽  
Peggy Cebe
Keyword(s):  
Single Crystals ◽  
High Performance ◽  
Dilute Solution ◽  
Two Stage ◽  
Annealing Behavior ◽  
High Performance Polymers ◽  
Seeding Method ◽  
Phenylene Sulfide

We are studying the crystallization and annealing behavior of high performance polymers, like poly(p-pheny1ene sulfide) PPS, and poly-(etheretherketone), PEEK. Our purpose is to determine whether PPS, which is similar in many ways to PEEK, undergoes reorganization during annealing. In an effort to address the issue of reorganization, we are studying solution grown single crystals of PPS as model materials.Observation of solution grown PPS crystals has been reported. Even from dilute solution, embrionic spherulites and aggregates were formed. We observe that these morphologies result when solutions containing uncrystallized polymer are cooled. To obtain samples of uniform single crystals, we have used two-stage self seeding and solution replacement techniques.

CHEMICAL CONVERSION OF 2.4.6-TRINITROTOLUENE (TNT) TO NEW HIGH PERFORMANCE POLYMERS

2002 ◽  
Vol 5 (1-6) ◽  
pp. 1031-1047
Author(s):  
A. L. Rusanov ◽  
L. G. Komarova ◽  
M. P. Prigozhina ◽  
V. A. Tartakovsky ◽  
S. A. Shevelev ◽  
...  
Keyword(s):  
High Performance ◽  
Chemical Conversion ◽  
High Performance Polymers

Accelerated Discovery of High-Refractive-Index Polyimides via First-Principles Molecular Modeling, Virtual High-Throughput Screening, and Data Mining

2019 ◽  
Author(s):  
Mohammad Atif Faiz Afzal ◽  
Mojtaba Haghighatlari ◽  
Sai Prasad Ganesh ◽  
Chong Cheng ◽  
Johannes Hachmann
Keyword(s):  
Data Mining ◽  
Refractive Index ◽  
High Throughput ◽  
First Principles ◽  
High Throughput Screening ◽  
Large Scale ◽  
Computational Study ◽  
High Refractive Index ◽  
Structural Features ◽  
Learning Program

<div>We present a high-throughput computational study to identify novel polyimides (PIs) with exceptional refractive index (RI) values for use as optic or optoelectronic materials. Our study utilizes an RI prediction protocol based on a combination of first-principles and data modeling developed in previous work, which we employ on a large-scale PI candidate library generated with the ChemLG code. We deploy the virtual screening software ChemHTPS to automate the assessment of this extensive pool of PI structures in order to determine the performance potential of each candidate. This rapid and efficient approach yields a number of highly promising leads compounds. Using the data mining and machine learning program package ChemML, we analyze the top candidates with respect to prevalent structural features and feature combinations that distinguish them from less promising ones. In particular, we explore the utility of various strategies that introduce highly polarizable moieties into the PI backbone to increase its RI yield. The derived insights provide a foundation for rational and targeted design that goes beyond traditional trial-and-error searches.</div>

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