scholarly journals Iodine‐transfer polymerization and CuAAC “click” chemistry: A versatile approach toward poly(vinylidene fluoride)‐based amphiphilic triblock terpolymers

2020 ◽  
Vol 58 (1) ◽  
pp. 163-171
Author(s):  
Yogesh Patil ◽  
George Zapsas ◽  
Yves Gnanou ◽  
Nikos Hadjichristidis
Keyword(s):  
Click Chemistry ◽  
Vinylidene Fluoride ◽  
Poly Vinylidene Fluoride ◽  
Iodine Transfer ◽  
Triblock Terpolymers

Kinetic and mechanistic aspects of the iodine transfer copolymerization of vinylidene fluoride with 2,3,3,3-tetrafluoro-1-propene and functionalization into ω-hydroxy fluorinated copolymers

2016 ◽  
Vol 7 (39) ◽  
pp. 6099-6109 ◽  
Author(s):  
Sanjib Banerjee ◽  
Saad Zaghloul ◽  
Ali Alaaeddine ◽  
Bruno Ameduri
Keyword(s):  
Vinylidene Fluoride ◽  
Water Based ◽  
Poly Vinylidene Fluoride ◽  
Iodine Transfer ◽  
Fluorinated Copolymers

ω-Hydroxy functionalized poly(vinylidene fluoride) prepared in a water-based non-fluorinated solvent by iodine transfer copolymerization VDF and 1234yf.

Well-defined poly(vinylidene fluoride) (PVDF) based-dendrimers synthesized by click chemistry: enhanced crystallinity of PVDF and increased hydrophobicity of PVDF films

2016 ◽  
Vol 7 (36) ◽  
pp. 5625-5629 ◽  
Author(s):  
Enrique Folgado ◽  
Marc Guerre ◽  
Christian Bijani ◽  
Vincent Ladmiral ◽  
Anne-Marie Caminade ◽  
...  
Keyword(s):  
Click Chemistry ◽  
Analytical Methods ◽  
Vinylidene Fluoride ◽  
Poly Vinylidene Fluoride ◽  
Enhanced Crystallinity

This study reports the preparation of a novel fluorinated dendrimer bearing PVDF branches by click chemistry and its characterization by several analytical methods.

Piezoelectric β-polymorph formation of new textiles by surface modification with coating process based on interfacial interaction on the conformational variation of poly (vinylidene fluoride) (PVDF) chains

2020 ◽  
Vol 91 (3) ◽  
pp. 31301
Author(s):  
Nabil Chakhchaoui ◽  
Rida Farhan ◽  
Meriem Boutaldat ◽  
Marwane Rouway ◽  
Adil Eddiai ◽  
...  
Keyword(s):  
High Efficiency ◽  
Vinylidene Fluoride ◽  
Research Work ◽  
Research Area ◽  
Interfacial Interaction ◽  
Tetraethyl Orthosilicate ◽  
Poly Vinylidene Fluoride ◽  
Carbon Nanofillers ◽  
The Impact ◽  
Advanced Applications

Novel textiles have received a lot of attention from researchers in the last decade due to some of their unique features. The introduction of intelligent materials into textile structures offers an opportunity to develop multifunctional textiles, such as sensing, reacting, conducting electricity and performing energy conversion operations. In this research work nanocomposite-based highly piezoelectric and electroactive β-phase new textile has been developed using the pad-dry-cure method. The deposition of poly (vinylidene fluoride) (PVDF) − carbon nanofillers (CNF) − tetraethyl orthosilicate (TEOS), Si(OCH2CH3)4 was acquired on a treated textile substrate using coating technique followed by evaporation to transform the passive (non-functional) textile into a dynamic textile with an enhanced piezoelectric β-phase. The aim of the study is the investigation of the impact the coating of textile via piezoelectric nanocomposites based PVDF-CNF (by optimizing piezoelectric crystalline phase). The chemical composition of CT/PVDF-CNC-TEOS textile was detected by qualitative elemental analysis (SEM/EDX). The added of 0.5% of CNF during the process provides material textiles with a piezoelectric β-phase of up to 50% has been measured by FTIR experiments. These results indicated that CNF has high efficiency in transforming the phase α introduced in the unloaded PVDF, to the β-phase in the case of nanocomposites. Consequently, this fabricated new textile exhibits glorious piezoelectric β-phase even with relatively low coating content of PVDF-CNF-TEOS. The study demonstrates that the pad-dry-cure method can potentially be used for the development of piezoelectric nanocomposite-coated wearable new textiles for sensors and energy harvesting applications. We believe that our study may inspire the research area for future advanced applications.

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