Reversible addition-fragmentation chain-transfer (RAFT) copolymerization of vinylidene chloride and methyl acrylate

2002 ◽  
Vol 51 (10) ◽  
pp. 1117-1122 ◽  
Author(s):  
Romain Severac ◽  
Patrick Lacroix-Desmazes ◽  
Bernard Boutevin
Keyword(s):  
Methyl Acrylate ◽  
Chain Transfer ◽  
Vinylidene Chloride ◽  
Reversible Addition

Reversible addition-fragmentation chain transfer copolymerization of methyl methacrylate and methyl acrylate

2014 ◽  
Vol 87 (5) ◽  
pp. 640-645 ◽  
Author(s):  
B. N. Ionychev ◽  
Yu. D. Semchikov ◽  
N. A. Kopylova ◽  
E. S. Andreeva ◽  
S. D. Zaitsev
Keyword(s):  
Methyl Methacrylate ◽  
Methyl Acrylate ◽  
Chain Transfer ◽  
Reversible Addition

A Bipedal Silica-Immobilized Azo-Initiator for Surface-Confined Radical Polymerizations

2009 ◽  
Vol 62 (11) ◽  
pp. 1473 ◽  
Author(s):  
Robert Rotzoll ◽  
Philipp Vana
Keyword(s):  
Electron Microscopy ◽  
Molecular Weight ◽  
Scanning Electron Microscopy ◽  
Methyl Acrylate ◽  
Chain Transfer ◽  
Molecular Weights ◽  
Surface Initiated Polymerization ◽  
Reversible Addition ◽  
Azo Initiator ◽  
Scanning Electron

The present study introduces the silica-anchored azo-initiator 4,4′-azobis(4-cyano-N-(3″-triethoxysilylpropyl)-valeric amide) (ACTA) for the surface-initiated polymerization of methyl acrylate (MA) with and without additional grafted reversible addition–fragmentation chain transfer (RAFT) agents 1,4-bis(3′-trimethoxysilylpropyltrithiocarbonylmethyl)benzene and 1,6-bis(o,p-2′-trimethoxysilylethylbenzyltrithiocarbonyl)hexane. While the sole use of silica-linked ACTA produced grafted poly(methyl acrylate) (pMA) of high molecular weight, due to a 2D Trommsdorff effect, the polymerization in combination with the fixed RAFT agents exhibited living behaviour with increasing molecular weights during polymerization. Silica-pMA hybrids were further analyzed via thermogravimetric analysis and scanning electron microscopy, which revealed significant differences between the three approaches.

Access to Chain Length Dependent Termination Rate Coefficients of Methyl Acrylate via Reversible Addition−Fragmentation Chain Transfer Polymerization

2005 ◽  
Vol 38 (7) ◽  
pp. 2595-2605 ◽  
Author(s):  
Alexander Theis ◽  
Achim Feldermann ◽  
Nathalie Charton ◽  
Martina H. Stenzel ◽  
Thomas P. Davis ◽  
...  
Keyword(s):  
Chain Length ◽  
Methyl Acrylate ◽  
Chain Transfer ◽  
Rate Coefficients ◽  
Termination Rate ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

Origin of Inhibition Effects in the Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization of Methyl Acrylate

2002 ◽  
Vol 35 (22) ◽  
pp. 8300-8306 ◽  
Author(s):  
Sébastien Perrier ◽  
Christopher Barner-Kowollik ◽  
John F. Quinn ◽  
Philipp Vana ◽  
Thomas P. Davis
Keyword(s):  
Methyl Acrylate ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Reversible Addition
Sign in / Sign up

Export Citation Format

Share Document