Molecular simulation of the glass transition and proton conductivity of 2,2′-benzidinedisulfonic acid and 4,4′-diaminodiphenylether-2,2′-disulfonic acid-based copolyimides as polyelectrolytes for fuel cell applications

2006 ◽  
Vol 55 (8) ◽  
pp. 872-882 ◽  
Author(s):  
Naiping Hu ◽  
Rongrong Chen ◽  
Andrew Hsu
Keyword(s):  
Glass Transition ◽  
Fuel Cell ◽  
Molecular Simulation ◽  
Proton Conductivity ◽  
Disulfonic Acid

Novel Sulfonated Polyimides as Polyelectrolytes for Fuel Cell Application. 2. Synthesis and Proton Conductivity of Polyimides from 9,9-Bis(4-aminophenyl)fluorene-2,7-disulfonic Acid

2002 ◽  
Vol 35 (17) ◽  
pp. 6707-6713 ◽  
Author(s):  
Xiaoxia Guo ◽  
Jianhua Fang ◽  
Tatsuya Watari ◽  
Kazuhiro Tanaka ◽  
Hidetoshi Kita ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Proton Conductivity ◽  
Disulfonic Acid ◽  
Fuel Cell Application ◽  
Sulfonated Polyimides

scholarly journals PEMBUATAN DAN KARAKTERISASI MEMBRAN KOMPOSIT KITOSAN-SODIUM ALGINAT TERFOSFORILASI SEBAGAI PROTON EXCHANGE MEMBRANE FUEL CELL (PEMFC)

2016 ◽  
Vol 1 (1) ◽  
pp. 14
Author(s):  
Siti Wafiroh ◽  
Suyanto Suyanto ◽  
Yuliana Yuliana
Keyword(s):  
Fuel Cell ◽  
Sodium Alginate ◽  
Proton Conductivity ◽  
Composite Membrane ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Methanol Permeability ◽  
Water Swelling ◽  
Exchange Membrane

AbstrakDi era globalisasi ini, kebutuhan bahan bakar fosil semakin meningkat dan ketersediannya semakin menipis. Oleh karena itu, dibutuhkan bahan bakar alternatif seperti Proton Exchange Membrane Fuel Cell (PEMFC). Tujuan dari penelitian ini adalah membuat dan mengkarakterisasi membran komposit kitosan-sodium alginat dari rumput laut coklat (Sargassum sp.) terfosforilasi sebagai Proton Exchange Membrane Fuel Cell (PEMFC). PEM dibuat dengan 4 variasi perbandingan konsentrasi antara kitosan dengan sodium alginat 8:0, 8:1, 8:2, dan 8:4 (b/b). Membran komposit kitosan-sodium alginat difosforilasi dengan STPP 2N. Karakterisasi PEM meliputi: uji tarik, swelling air, kapasitas penukar ion, FTIR, SEM, permeabilitas metanol, dan konduktivitas proton. Berdasarkan hasil analisis tersebut, membran yang optimal adalah perbandingan 8:1 (b/b) dengan nilai modulus young sebesar 0,0901 kN/cm2, swelling air sebesar 19,14 %, permeabilitas metanol sebesar 72,7 x 10-7, dan konduktivitas proton sebesar 4,7 x 10-5 S/cm. Membran komposit kitosan-sodium alginat terfosforilasi memiliki kemampuan yang cukup baik untuk bisa diaplikasikan sebagai membran polimer elektrolit dalam PEMFC. Kata kunci: kitosan, sodium alginat, terfosforilasi, PEMFC  AbstractIn this globalization era, the needs of fossil fuel certainly increases, but its providence decreases. Therefore, we need alternative fuels such as Proton Exchange Membrane Fuel Cell (PEMFC). The purpose of this study is preparationand characterization of phosphorylated chitosan-sodium alginate composite membrane from brown seaweed (Sargassum sp.) as Proton Exchange Membrane Fuel Cell (PEMFC). PEM is produced with 4 variations of concentration ratio between chitosan and sodium alginate 8:0, 8:1, 8:2, and 8:4 (w/w). Chitosan-sodium alginate composite membrane phosphorylated with 2 N STPP. The characterization of PEM include: tensile test, water swelling, ion exchange capacity, FTIR, SEM, methanol permeability, and proton conductivity. Based on the analysis result, the optimal membrane is ratio of 8:1 (w/w) with the value of Young’s modulus about 0.0901 kN/cm2, water swelling at 19.14%, methanol permeability about 72.7 x 10-7, and proton conductivity about 4.7 x 10-5 S/cm. The phosphorylated chitosan-sodium alginate composite membrane has good potentials for the application of the polymer electrolyte membrane in PEMFC. Keywords: chitosan, sodium alginate, phosphorylated, PEMFC

Proton Exchange Membrane Development and Processing for Fuel Cell Application

2007 ◽  
Vol 539-543 ◽  
pp. 1327-1331
Author(s):  
Philippe Bébin ◽  
Hervé Galiano
Keyword(s):  
Fuel Cell ◽  
Proton Conductivity ◽  
Proton Conduction ◽  
Proton Exchange ◽  
Membrane Properties ◽  
Organic Polymer ◽  
Polysulfone Membrane ◽  
Sulfonated Polysulfone ◽  
Membrane Processing ◽  
Conductive Fillers

The development of new proton exchange membranes for PEMFC has to be related to the membrane processing as it can change drastically the final properties of the material. Indeed, for the same material, a membrane prepared by a solvent-casting process has a lower lifetime than an extruded one. The proton conduction of the membrane can also be dependent on the membrane processing, especially when some removable plasticizers are used to perform the membrane extrusion. Some residual porosity, left in the material after removing the plasticizer, is suspected to enhance the proton conduction of the film. Fuel cell experiments have shown that extruded sulfonated polysulfone membrane can give the same performance as a Nafion® reference membrane whereas the proton conductivity of PSUs is twenty times lower than the Nafion® one. Additional improvements of the membrane properties can also be expected by adding some proton conductive fillers to the organic polymer. This approach enhances the proton conductivity of sulfonated polysulfone to values similar to Nafion®. On the other hand, when Nafion® is used as a matrix for the proton conductive fillers, a very significant improvement of fuel cell performance is obtained.

scholarly journals The Effect of Proton Conductivity of Fe–N–C–Based Cathode on PEM Fuel cell Performance

2020 ◽  
Vol 167 (8) ◽  
pp. 084501
Author(s):  
Tatyana Reshetenko ◽  
Günter Randolf ◽  
Madeleine Odgaard ◽  
Barr Zulevi ◽  
Alexey Serov ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Proton Conductivity ◽  
Pem Fuel Cell ◽  
Cell Performance ◽  
Fuel Cell Performance

scholarly journals Recent Progress in the Development of Aromatic Polymer-Based Proton Exchange Membranes for Fuel Cell Applications

Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1061 ◽  
Author(s):  
Raja Rafidah R. S. ◽  
Rashmi W. ◽  
Khalid M. ◽  
Wong W. Y. ◽  
Priyanka J.
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Proton Conductivity ◽  
Elevated Temperatures ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Polymer Chains ◽  
Membrane Electrode ◽  
Aryl Ether

Proton exchange membranes (PEMs) play a pivotal role in fuel cells; conducting protons from the anode to the cathode within the cell’s membrane electrode assembles (MEA) separates the reactant fuels and prevents electrons from passing through. High proton conductivity is the most important characteristic of the PEM, as this contributes to the performance and efficiency of the fuel cell. However, it is also important to take into account the membrane’s durability to ensure that it canmaintain itsperformance under the actual fuel cell’s operating conditions and serve a long lifetime. The current state-of-the-art Nafion membranes are limited due to their high cost, loss of conductivity at elevated temperatures due to dehydration, and fuel crossover. Alternatives to Nafion have become a well-researched topic in recent years. Aromatic-based membranes where the polymer chains are linked together by aromatic rings, alongside varying numbers of ether, ketone, or sulfone functionalities, imide, or benzimidazoles in their structures, are one of the alternatives that show great potential as PEMs due totheir electrochemical, mechanical, and thermal strengths. Membranes based on these polymers, such as poly(aryl ether ketones) (PAEKs) and polyimides (PIs), however, lack a sufficient level of proton conductivity and durability to be practical for use in fuel cells. Therefore, membrane modifications are necessary to overcome their drawbacks. This paper reviews the challenges associated with different types of aromatic-based PEMs, plus the recent approaches that have been adopted to enhance their properties and performance.

scholarly journals 9,10-ANTHRAQUINONE-2,6-DISULFONIC ACID DISODIUM SALT/ EPOXY GRAPHITE COMPOSITE FOR ANODE IN MICROBIAL FUEL CELL

2017 ◽  
Vol 79 (5-3) ◽  
Author(s):  
Mimi Hani Abu Bakar ◽  
Neil F Pasco ◽  
Ravi Gooneratne ◽  
Kim Byung Hong
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Conductive Filler ◽  
Internal Resistance ◽  
Disodium Salt ◽  
Disulfonic Acid ◽  
Graphite Composite ◽  
Design Flexibility ◽  
Matrix Surface ◽  
The Matrix

Properties such as electrical conductivity, low resistivity, chemicals and corrosion resistance are mostly found in carbon based materials. Epoxy resin is excellent for electrical insulation and can be used as a conductor with the addition of conductive filler. Combinations of carbon and epoxy show qualities of a conductive electrode, mechanically strong with design flexibility and thus makes them suitable as electrodes in microbial fuel cell (MFC). In this study, graphite-epoxy composites were fabricated with multi-walled carbon nanotube (MWCNT) embedded in the matrix surface. 9,10-Anthraquinone-2,6-disulfonic acid disodium salt/polypyrrole (PPy/AQDS) was used as mediator, covalently electrografted on electrode’s surface. Electrochemical stability of anodes during continuous operation were measured in air-cathode MFCs. It appears that maximum power in MFC could be increased up to 42% with surface modification using PPy/AQDS. Internal resistance (Rint) could be reduced up to 66% with the inclusion of MWCNT. These findings show that a one-day fabrication of a-ready-to-use conductive electrode is possible for graphite content between 70-80% (w/w).

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