scholarly journals Recent Progress in the Development of Aromatic Polymer-Based Proton Exchange Membranes for Fuel Cell Applications

Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1061 ◽  
Author(s):  
Raja Rafidah R. S. ◽  
Rashmi W. ◽  
Khalid M. ◽  
Wong W. Y. ◽  
Priyanka J.
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Proton Conductivity ◽  
Elevated Temperatures ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Polymer Chains ◽  
Membrane Electrode ◽  
Aryl Ether

Proton exchange membranes (PEMs) play a pivotal role in fuel cells; conducting protons from the anode to the cathode within the cell’s membrane electrode assembles (MEA) separates the reactant fuels and prevents electrons from passing through. High proton conductivity is the most important characteristic of the PEM, as this contributes to the performance and efficiency of the fuel cell. However, it is also important to take into account the membrane’s durability to ensure that it canmaintain itsperformance under the actual fuel cell’s operating conditions and serve a long lifetime. The current state-of-the-art Nafion membranes are limited due to their high cost, loss of conductivity at elevated temperatures due to dehydration, and fuel crossover. Alternatives to Nafion have become a well-researched topic in recent years. Aromatic-based membranes where the polymer chains are linked together by aromatic rings, alongside varying numbers of ether, ketone, or sulfone functionalities, imide, or benzimidazoles in their structures, are one of the alternatives that show great potential as PEMs due totheir electrochemical, mechanical, and thermal strengths. Membranes based on these polymers, such as poly(aryl ether ketones) (PAEKs) and polyimides (PIs), however, lack a sufficient level of proton conductivity and durability to be practical for use in fuel cells. Therefore, membrane modifications are necessary to overcome their drawbacks. This paper reviews the challenges associated with different types of aromatic-based PEMs, plus the recent approaches that have been adopted to enhance their properties and performance.

scholarly journals Electrochemical Performance Improvement of the Catalyst of the Methanol Micro-Fuel Cell Using Carbon Nanotubes

2019 ◽  
Author(s):  
Mohammad Kazemi Nasrabadi ◽  
Amir Ebrahimi-Moghadam ◽  
Mohammad Hosein Ahmadi ◽  
Ravinder Kumar ◽  
Narjes Nabipour
Keyword(s):  
Carbon Nanotubes ◽  
Fuel Cells ◽  
Fuel Cell ◽  
Carbon Black ◽  
Oxidation Reaction ◽  
High Energy ◽  
Proton Exchange ◽  
Operating Conditions ◽  
High Energy Density ◽  
Methanol Oxidation Reaction

Due to low working temperature, high energy density and low pollution, proton exchange fuel cells have been investigated under different operating conditions in different applications. Using platinum catalysts in methanol fuel cells leads to increasing the cost of this kind of fuel cell which is considered as a barrier to the commercialism of this technology. For this reason, a lot of efforts have been made to reduce the loading of the catalyst required on different supports. In this study, carbon black (CB) and carbon nanotubes (CNT) have been used as catalyst supports of the fuel cell as well as using the double-metal combination of platinum-ruthenium (PtRu) as anode electrode catalyst and platinum (Pt) as cathode electrode catalyst. The performance of these two types of electro-catalyst in the oxidation reaction of methanol has been compared based on electrochemical tests. Results showed that the carbon nanotubes increase the performance of the micro-fuel cell by 37% at maximum power density, compared to the carbon black. Based on thee-electrode tests of chronoamperometry and voltammetry, it was found that the oxidation onset potential of methanol for CNT has been around 20% less than CB, leading to the kinetic improvement of the oxidation reaction. The current density of methanol oxidation reaction increased up to 62% in CNT sample compared to CB supported one, therefore the active electrochemical surface area of the catalyst has been increased up to 90% by using CNT compared to CB which shows the significant rise of the electrocatalytic activity in CNT supported catalyst. Moreover, the resistance of the CNT supported sample to poisonous intermediate species has been found 3% more than CB supported one. According to the chronoamperometry test results, it was concluded that the performance and sustainability of the CNT electro-catalyst show remarkable improvement compared to CB electro-catalyst in the long term.

A Simplified Three-Dimensional CFD Approach for PEMFC and DMFC Design

2003 ◽  
Author(s):  
C. W. Hong ◽  
C. H. Cheng ◽  
K. Fei
Keyword(s):  
Transport Phenomenon ◽  
Fuel Cells ◽  
Fuel Cell ◽  
Performance Test ◽  
Direct Methanol Fuel Cells ◽  
Proton Exchange ◽  
Design Tool ◽  
Cathode Side ◽  
Membrane Electrode ◽  
Crossover Effect

This paper describes the fundamental theory, algorithm and computation methods to predict the performance of proton exchange membrane fuel cells (PEMFC) and direct methanol fuel cells (DMFC) using a simplified computational fluid dynamics (CFD) approach. Based on the common transport phenomenon inside both fuel cells, the mass, momentum, energy and species equations were derived. Darcy laws were employed to simplify the momentum equation and also to linearize the species equation. The mathematical model was solved in various flow channel designs and some membrane electrode assembly (MEA) options. The major concern is mainly on the cathode side, in the PEMFC case, that dominates the performance deterioration due to potential loss in the flow field. In the case of DMFCs, both anode and cathode sides are simulated. The methanol crossover effect is also included. This virtual performance test bench plays an important role in the prototype fuel cell design. The computer aided design tool is proved to be useful in configuration designs. Additionally, it provides the detailed transport phenomenon inside the fuel cell stack.

The Progress of Hybrid Proton Exchange Membranes Prepared by SPAEKs for Direct Methanol Fuel Cells

2012 ◽  
Vol 512-515 ◽  
pp. 1442-1445
Author(s):  
Hai Dan Lin ◽  
He Zhang ◽  
Xiao Ying Yang
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Direct Methanol Fuel Cells ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Layer By Layer ◽  
Aryl Ether ◽  
Fuel Cell Performance ◽  
Nanocomposite Layer ◽  
Direct Methanol

This review summarizes efforts in developing proton exchange membranes (PEMs) with excellent electrochemical fuel cell performance prepared by SPAEK in proton exchange membrane fuel cell (PEMFC) applications. Over the past few decades, much polyelectrolyte has been extensively studied to improve the properties as alternatives with lower cost and considerable performances for PEMFC. Sulfonated poly(aryl ether ketone) (SPAEK), fell into this category, which offers the attribute of adjustable proton conductivity, excellent mechanical and thermal stability. The discussion will cover crosslinking, organic-inorganic nanocomposite, layer-by-layer approaches.

scholarly journals Measurements Based Analysis of the Proton Exchange Membrane Fuel Cell Operation in Transient State and Power of Own Needs

Energies ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 498
Author(s):  
Andrzej Wilk ◽  
Daniel Węcel
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Transient State ◽  
Experimental Tests ◽  
Cell System ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Variable Load ◽  
Exchange Membrane

Currently, fuel cells are increasingly used in industrial installations, means of transport, and household applications as a source of electricity and heat. The paper presents the results of experimental tests of a Proton Exchange Membrane Fuel Cell (PEMFC) at variable load, which characterizes the cell’s operation in real installations. A detailed analysis of the power needed for operation fuel cell auxiliary devices (own needs power) was carried out. An analysis of net and gross efficiency was carried out in various operating conditions of the device. The measurements made show changes in the performance of the fuel cell during step changing or smooth changing of an electric load. Load was carried out as a change in the current or a change in the resistance of the receiver. The analysis covered the times of reaching steady states and the efficiency of the fuel cell system taking into account auxiliary devices. In the final part of the article, an analysis was made of the influence of the fuel cell duration of use on obtained parameters. The analysis of the measurement results will allow determination of the possibility of using fuel cells in installations with a rapidly changing load profile and indicate possible solutions to improve the performance of the installation.

Optimization of the Operating Parameters of a Proton Exchange Membrane Fuel Cell for Maximum Power Density

2005 ◽  
Vol 2 (2) ◽  
pp. 121-135 ◽  
Author(s):  
A. Mawardi ◽  
F. Yang ◽  
R. Pitchumani
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Power Density ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Optimum Operating ◽  
Design Parameters ◽  
Membrane Thickness ◽  
Exchange Membrane

The performance of fuel cells can be significantly improved by using optimum operating conditions that maximize the power density subject to constraints. Despite its significance, relatively scant work is reported in the open literature on the model-assisted optimization of fuel cells. In this paper, a methodology for model-based optimization is presented by considering a one-dimensional nonisothermal description of a fuel cell operating on reformate feed. The numerical model is coupled with a continuous search simulated annealing optimization scheme to determine the optimum solutions for selected process constraints. Optimization results are presented over a range of fuel cell design parameters to assess the effects of membrane thickness, electrode thickness, constraint values, and CO concentration on the optimum operating conditions.

Thermodynamic Analysis of the Performance of an Irreversible PEMFC

2018 ◽  
Vol 388 ◽  
pp. 350-360 ◽  
Author(s):  
Chang Jie Li ◽  
Ye Liu ◽  
Zhe Shu Ma
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Pem Fuel Cells ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Operating Pressure ◽  
Controllable Factors ◽  
Temperature Operating ◽  
Exchange Membrane

An irreversible model of proton exchange membrane fuel cells working at steady-state is established, in which the irreversibility resulting from overpotentials, internal currents and leakage currents are taken into account．In this paper, the irreversibility of fuel cell is expounded mainly from electrochemistry. The general performance characteristic curves are generated including output voltage, output power and output efficiency. In addition, the irreversibility of a class of PEMFC is studied by changing the operating conditions (controllable factors) of the fuel cell, including effect of operating temperature, operating pressure and leakage current. The results provide a theoretical basis for both the operation and optimal design of real PEM fuel cells．

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