Rheological properties of polyvinyl chloride. Parts II-unstable flow

1964 ◽  
Vol 4 (2) ◽  
pp. 133-136
Author(s):  
C. L. Sieglaff
Keyword(s):  
Rheological Properties ◽  
Polyvinyl Chloride ◽  
Unstable Flow

Annular Frictional Pressure Losses During Drilling—Predicting the Effect of Drillstring Rotation

2014 ◽  
Vol 136 (3) ◽  
Author(s):  
Arild Saasen
Keyword(s):  
Rheological Properties ◽  
Pressure Loss ◽  
Drilling Fluid ◽  
Axial Flow ◽  
Drilling Fluids ◽  
Unstable Flow ◽  
Pressure Losses ◽  
Shear Dependent Viscosity ◽  
Water Based ◽  
Dependent Viscosity

Controlling the annular frictional pressure losses is important in order to drill safely with overpressure without fracturing the formation. To predict these pressure losses, however, is not straightforward. First of all, the pressure losses depend on the annulus eccentricity. Moving the drillstring to the wall generates a wider flow channel in part of the annulus which reduces the frictional pressure losses significantly. The drillstring motion itself also affects the pressure loss significantly. The drillstring rotation, even for fairly small rotation rates, creates unstable flow and sometimes turbulence in the annulus even without axial flow. Transversal motion of the drillstring creates vortices that destabilize the flow. Consequently, the annular frictional pressure loss is increased even though the drilling fluid becomes thinner because of added shear rate. Naturally, the rheological properties of the drilling fluid play an important role. These rheological properties include more properties than the viscosity as measured by API procedures. It is impossible to use the same frictional pressure loss model for water based and oil based drilling fluids even if their viscosity profile is equal because of the different ways these fluids build viscosity. Water based drilling fluids are normally constructed as a polymer solution while the oil based are combinations of emulsions and dispersions. Furthermore, within both water based and oil based drilling fluids there are functional differences. These differences may be sufficiently large to require different models for two water based drilling fluids built with different types of polymers. In addition to these phenomena washouts and tool joints will create localised pressure losses. These localised pressure losses will again be coupled with the rheological properties of the drilling fluids. In this paper, all the above mentioned phenomena and their consequences for annular pressure losses will be discussed in detail. North Sea field data is used as an example. It is not straightforward to build general annular pressure loss models. This argument is based on flow stability analysis and the consequences of using drilling fluids with different rheological properties. These different rheological properties include shear dependent viscosity, elongational viscosity and other viscoelastic properties.

Changes in rheological properties of polyvinyl chloride plastisols with storage time

2020 ◽  
Vol 137 (37) ◽  
pp. 49105
Author(s):  
Yubi Ji ◽  
Anjiang Tang ◽  
Zhao Yang ◽  
Heng Luo ◽  
Hong Tan
Keyword(s):  
Rheological Properties ◽  
Polyvinyl Chloride ◽  
Storage Time

scholarly journals Anti-Gnawing, Thermo-Mechanical and Rheological Properties of Polyvinyl Chloride: Effect of Capsicum Oleoresin and Denatonium Benzoate

2021 ◽  
Vol 6 (1) ◽  
pp. 8
Author(s):  
Laongdaw Techawinyutham ◽  
Arnuparb Prasarnsri ◽  
Suchart Siengchin ◽  
Rapeephun Dangtungee ◽  
Sanjay Mavinkere Rangappa
Keyword(s):  
Weight Loss ◽  
Rheological Properties ◽  
Polyvinyl Chloride ◽  
Loss Modulus ◽  
Zinc Stearate ◽  
Toxic Substances ◽  
Elongation At Break ◽  
Denatonium Benzoate ◽  
Chloride Effect ◽  
Level Of Significance

Anti-rodent polymer composites were prepared using non-toxic substances denatonium benzoate (DB) and capsicum oleroresin (CO) mixed with polyvinyl chloride (PVC) matrix. DB is mixed in zinc stearate (ZnSt) called DB/ZnSt, and CO, providing burning sensation, is impregnated in mesoporous silica named SiCO. There are three sets of sample: Blank, composites Set I and Set II. Set I consists of DB/ZnSt at concentration of 1.96 wt% and SiCO at concentration of 12.16 wt%, 14.47 wt%, 18.75 wt% and 23.53 wt%. Set II comprises SiCO at the same amount of Set I. The anti-rodent composites studied are anti-gnawing, surface morphology, thermo-mechanical and rheological properties. Anti-rodent testing is analyzed by one-way blocked analysis of variance (ANOVA) and compared with Tukey test with a 95% level of significance, presenting good anti-gnawing efficiency. The best rat-proof sample is II.4, consisting of SiCO 23.53 wt%, which presents percentage of weight loss from gnawing at 1.68% compared to weight loss of neat PVC at 59.74%. The addition of SiCO at concentration ranging from 12.16 to 23.53 wt% reduces tensile strength around 25–50%, elongation at break strength around 2–23%, shear storage modulus (G′) around 30%, shear loss modulus (G″) shear viscosity (η) and glass transition (Tg) around 43% compared to Blank. The increase in SiCO concentration slightly improves the thermal stability of PVC composites around 3%, but the addition of DB/ZnSt at 1.96 wt% slightly reduces those properties.

Annular Frictional Pressure Losses During Drilling: The Effect of Drillstring Rotation

2013 ◽  
Author(s):  
Arild Saasen
Keyword(s):  
Rheological Properties ◽  
Pressure Loss ◽  
Drilling Fluid ◽  
Axial Flow ◽  
Drilling Fluids ◽  
Unstable Flow ◽  
Pressure Losses ◽  
Shear Dependent Viscosity ◽  
Water Based ◽  
Dependent Viscosity

Controlling the annular frictional pressure losses is important in order to drill safely with overpressure without fracturing the formation. To predict these pressure losses, however, is not straightforward. First of all, the pressure losses depend on the annulus eccentricity. Moving the drillstring to the wall generates a wider flow channel in part of the annulus reducing the frictional pressure losses significantly. The drillstring motion itself also affects the pressure loss significantly. The drillstring rotation, even for fairly small rotation rates, creates unstable flow and sometimes turbulence in the annulus even without axial flow. Transversal motion of the drillstring creates vortices that de-stabilize the flow. Consequently, the annular frictional pressure loss is increased even though the drilling fluid becomes thinner because of added shear rate. Naturally, the rheological properties of the drilling fluid play an important role. These rheological properties include more properties than the viscosity as measured by API procedures. It is impossible to use the same frictional pressure loss model for water based and oil based drilling fluids even if their viscosity profile is equal because of the different ways these fluids build viscosity. Water based drilling fluids are normally constructed as a polymer solution while the oil based are combinations of emulsions and dispersions. Furthermore, within both water based and oil based drilling fluids there are functional differences. These differences may be sufficiently large to require different models for two water based drilling fluids built with different types of polymers. In addition to these phenomena washouts and tool joints will create localised pressure losses. These localised pressure losses will again be coupled with the rheological properties of the drilling fluids. In the paper, all the above mentioned different phenomena and their consequences for annular pressure losses will be discussed in detail. Application of Det norske field data will be used as an example. The data cannot be used to build general models. The arguments for this model restriction are based on flow stability analysis and the consequences of using drilling fluids with different rheological properties. These different rheological properties include shear dependent viscosity, elongational viscosity and other viscoelastic properties.

Effects of chitosan as biopolymer coupling agent on the thermal and rheological properties of polyvinyl chloride/wood flour composites

2014 ◽  
Vol 58 ◽  
pp. 392-399 ◽  
Author(s):  
Kaimeng Xu ◽  
Kaifu Li ◽  
Tuhua Zhong ◽  
Litao Guan ◽  
Chengping Xie ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Polyvinyl Chloride ◽  
Coupling Agent ◽  
Wood Flour
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