Morphologies of microparticles of partially neutralized sodium polyacrylate by inverse suspension polymerization

2017 ◽  
Vol 58 (9) ◽  
pp. 1564-1574
Author(s):  
Yunju Kim ◽  
Kyu Yong Choi
Keyword(s):  
Suspension Polymerization ◽  
Sodium Polyacrylate ◽  
Inverse Suspension Polymerization

Water-Flooding Fluid Diversion Copolymeric Microsphere Prepared by Inverse Suspension Polymerization

e-Polymers ◽  
2007 ◽  
Vol 7 (1) ◽  
Author(s):  
Huang Zhiyu ◽  
Lu Hongsheng ◽  
Zhang Tailiang
Keyword(s):  
Thermal Stability ◽  
High Temperature ◽  
Oil Recovery ◽  
High Salinity ◽  
Suspension Polymerization ◽  
Oil Reservoirs ◽  
Water Flooding ◽  
Toughness Index ◽  
Inverse Suspension Polymerization ◽  
Enhance Oil Recovery

Abstract In order to enhance oil recovery in high-temperature and high-salinity oil reservoirs, the copolymeric microspheres containing acrylamide (AM), acrylonitrile (AN) and AMPS was synthesized by inverse suspension polymerization. The copolymeric microsphere was very uniform and the size could be changed according to the condition of polymerization. The lab-scale studies showed that the copolymeric microsphere exhibit good salt-tolerance and thermal-stability when immersed in 20×105 mg/L NaCl(or KCl) solution, 7500 mg/L CaCl2 (or MgCl2) solution or 2000 mg/L FeCl3 solution, respectively. The copolymeric microsphere showed satisfactory absorbency rates. The sand-pipes experiments confirmed that the average toughness index was 1.059. It could enhance the oil recovery by about 3% compared with the corresponding irregular copolymeric particle.

Inverse suspension polymerization of acrylamide

1982 ◽  
Vol 18 (7) ◽  
pp. 639-645 ◽  
Author(s):  
M.V. Dimonie ◽  
C.M. Boghina ◽  
N.N. Marinescu ◽  
M.M. Marinescu ◽  
C.I. Cincu ◽  
...  
Keyword(s):  
Suspension Polymerization ◽  
Inverse Suspension Polymerization

Synthesis and Properties of Thermo- and pH-Sensitive Poly[(Sodium Humate)-(N-Isopropylacrylamide)-(Acrylic Acid)] Intelligent Hydrogel

2013 ◽  
Vol 781-784 ◽  
pp. 536-541
Author(s):  
Xiao Mi Zhou ◽  
Xiao Ran Sun ◽  
Guang Yue Li
Keyword(s):  
Acrylic Acid ◽  
Suspension Polymerization ◽  
Ammonium Persulfate ◽  
Continuous Phase ◽  
Ph Sensitive ◽  
Cross Linking ◽  
Swelling Ratio ◽  
Inverse Suspension Polymerization ◽  
Sensitive Characteristics ◽  
Intelligent Hydrogel

A novel intelligent hydrogel of poly(Humic acid - Nisopropylacrylamide - Acrylic acid) (P(NIPAAm-HA-AA)) was prepared at 70°C by inverse suspension polymerization. The reactions include uses N,N-methylene-bis-acrylamide (MBA) as a cross-linking agent, ammonium persulfate (KPS) as an initiator, cyclohexane as a continuous phase and span-65 as dispersant. The influence such as concentration of monomers and cross-linking agent, mole fraction of span-65 in mixed monomers, and temperature of polymerization on the property of resulting P(NIPAAm-HA-AA) hydrogels was investigated in detail. Fourier transform infrared (FTIR) demonstrated that NIPAAm, HA and AA was synthetized successfully. The results showed that the swelling ratio (SR) of modified hydrogel was improved significantly with the dosage of NIPAAm. It was also observed that the thermosensitive and pH sensitive characteristics was strongly affected by concentrations of NIPAAm. At last, we choose NIPAAm: HA=0.3.

Adsorption of Dyes from Acidic Wastewater by Crosslinked Chitosan Resin

2011 ◽  
Vol 399-401 ◽  
pp. 1363-1366
Author(s):  
Zhong Hua Huang ◽  
Yan Zou ◽  
Fang Yuan ◽  
Wei Jing Li ◽  
Xue Pu
Keyword(s):  
Activated Carbon ◽  
Suspension Polymerization ◽  
Low Cost ◽  
Inverse Suspension Polymerization ◽  
Crosslinked Chitosan ◽  
Acidic Wastewater ◽  
Chitosan Resin

A new low cost adsorbent crosslinked chitosan resin has been used to remove dyes from wastewater. The crosslinked chitosan resin was prepared using inverse suspension polymerization with methanal and epichlorhydrin (ECH) using pre-crosslinking and crosslinking techniques. As comparison, the adsoption ability of chitosan and activated carbon was also investigated.

Effect of the Ion Strengths in Different Salt Solutions on the Absorbencies of Poly(acrylic acid-co-acrylamide) Superabsorbent by Inverse Suspension Polymerization

2012 ◽  
Vol 550-553 ◽  
pp. 711-715
Author(s):  
Jian Jun Xie ◽  
Qing Xin Yao ◽  
Nian Zeng ◽  
Chu Ding
Keyword(s):  
Acrylic Acid ◽  
Metal Cation ◽  
Suspension Polymerization ◽  
The Self ◽  
Salt Solutions ◽  
Swelling Properties ◽  
Anionic Group ◽  
Inverse Suspension Polymerization ◽  
The Relationship ◽  
Poly Acrylic Acid

The absorbencies of poly(acrylic acid-co-acrylamide) (PAAM) are measured for the ion strengths of the salt solutions using the self-made PAAM by inverse suspension polymerization. The effects of various salt solutions on the swelling properties were studied systemically, and the relationship between the absorbency (Q) of PAAM and the concentrations of different salt solutions(c) could be expressed as Q=kcn. The absorbencies of PAAM decrease obviously with the ion strengths (less than 0.03mol/kg) and had no great change when the ion strengths were higher than 0.03mol/kg for the same solution systems. The absorbency decreased with an increase in charge of the metal cation. The absorbencies of the PAAM in the sodium solutions with different anion decreased with an increase of the ion strengths. However, the absorbencies increased with the increase in charge of the anionic group and were in order PO43->CO32->Cl-.

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