Effect of plasma treatment and electron beam radiations on the strength of nanofilled adhesive-bonded joints

2010 ◽  
Vol 50 (8) ◽  
pp. 1505-1511 ◽  
Author(s):  
H.M.S. Iqbal ◽  
S. Bhowmik ◽  
J.A. Poulis ◽  
R. Benedictus
2014 ◽  
Vol 611-612 ◽  
pp. 1484-1493 ◽  
Author(s):  
Chiara Mandolfino ◽  
Enrico Lertora ◽  
Carla Gambaro

For an effective application of polymers, it is essential to have good adhesion behaviour to ensure good mechanical properties and durable components. Unfortunately, in general terms, polymers are characterized by high chemical inertness, which leads to very low surface energy values and, consequently, poor adhesive properties; this is particularly true for polyolefins. In this study, the effects of low pressure plasma treatment on surface roughness of polyethylene and polypropylene samples and on shear properties of adhesive bonded joints based on these substrates have been investigated. In particular, the optimization of three plasma process parameters, exposure time, voltage and working gas, were studied performing roughness measurement, contact angle evaluation and lap-shear tests. The experimental results show that the optimized plasma process may remarkably change the surface morphology, increasing wettability properties of the surfaces and shear strength of the bonded joints. These good properties remain almost unchanged even after some days of storage in the laboratory.


Polymers ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 616
Author(s):  
Jacek Tyczkowski ◽  
Jacek Balcerzak ◽  
Jan Sielski ◽  
Iwona Krawczyk-Kłys

Studies on the surface modification of commercial styrene-butadiene-styrene (SBS) rubber with different carbon black (CB) nanofiller content (10–80 parts per hundred parts of rubber (phr)) performed by low-pressure oxygen plasma are presented in this paper. The adhesion properties of the rubber were determined by the peel test for adhesive-bonded joints prepared with a water-based polyurethane (PU) adhesive. The chemical structure and morphology of the SBS rubber surface before and after plasma treatment were investigated by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM), respectively. The peel tests showed that the plasma treatment significantly improved the strength of adhesive-bonded joints in the entire range of CB tested, revealing a clear maximum for approximately 50 phr of CB. It was also found that as a result of plasma treatment, functional groups that are responsible for the reactions with the PU adhesive, such as C−OH and C=O, were formed, and their concentration, similar to the peel strength, showed maximum values for approximately 50 phr CB. The occurrence of these maxima was explained using the bound rubber model.


2016 ◽  
Vol 93 (10) ◽  
pp. 737-755 ◽  
Author(s):  
A. Hutchinson ◽  
Y. Liu ◽  
Y. Lu

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