Synthesis, thermal properties, and flame retardance of the epoxy-silsesquioxane hybrid resins

2007 ◽  
Vol 47 (3) ◽  
pp. 225-234 ◽  
Author(s):  
Tingli Lu ◽  
Tao Chen ◽  
Guozheng Liang
Polymer ◽  
2003 ◽  
Vol 44 (3) ◽  
pp. 565-573 ◽  
Author(s):  
Chuan-Shao Wu ◽  
Ying-Ling Liu ◽  
Keh-Ying Hsu

2011 ◽  
Vol 284-286 ◽  
pp. 365-368 ◽  
Author(s):  
Jing Zhu ◽  
Yong Wu ◽  
Lei Zhao ◽  
Hong Liang Wei ◽  
Hui Juan Chu ◽  
...  

Hexakis-(4-aminophenoxy)-cyclotriphosphazene (PN-NH2) was synthesized through nucleophilic substitution of the chloride atoms of hexachlorocyclotriphosphazene (HCCP) and reduction of the nitro group, and its chemical structure was characterized. As a curing agents for commercial epoxy resin Diglycidyl ether of bisphenol-A (DGEBA) PN-NH2 was compared with conventional curing agents 4,4-diaminodiphenylsulfone(DDS) and 4,4-diaminodiphenylmethane (DDM). The thermal properties and thermal degradation behaviors of these thermosetted resins were investigated by using thermogravimetric analysis (TGA). TGA studies demonstrated that the thermal properties of the PN-NH2-containing cured epoxy resin were higher than those of others. The phosphorus-nitrogen containing curing agent can result in a great improvement of the flame retardance for their thermosetted epoxy resins.


2014 ◽  
Vol 18 (5) ◽  
pp. 1603-1605 ◽  
Author(s):  
Wei Zhang ◽  
Tie-Ling Xing ◽  
Qiang-Hua Zhang ◽  
Guo-Qiang Chena

Wool fabric was treated with silica sol and phosphorus doped silica sol by sol-gel method in order to improve its thermal properties and flame retardance. The thermal stability, combustion behavior, and smoke suppression of the control and finished wool fabric were analyzed using thermogravimetric analysis, limited oxygen index, micro combustion calorimeter, and smoke chamber. The results showed that wool fabric treated by phosphorus doped silica sol had excellent thermal properties and flame retardance with higher final char residue and LOI value. Furthermore, heat release rate and smoke density results indicated the safety performance of the treated wool fabric on fire.


Author(s):  
Chin-Lung Chiang ◽  
Chen-Chi M. Ma ◽  
Hsu-Chiang Kuan ◽  
Hey Rey Chang ◽  
Shiu-Chun Lu

2003 ◽  
Vol 41 (15) ◽  
pp. 2354-2367 ◽  
Author(s):  
Ying-Ling Liu ◽  
Chuan-Shao Wu ◽  
Yie-Shun Chiu ◽  
Wen-Hsuan Ho

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