Water sorption and water-resistance properties of poly(vinyl alcohol)/clay nanocomposite films: Effects of chemical structure and morphology

2014 ◽  
Vol 36 (4) ◽  
pp. 660-667 ◽  
Author(s):  
Mijin Lim ◽  
Dowan Kim ◽  
Haksoo Han ◽  
Sher Bahadar Khan ◽  
Jongchul Seo
Keyword(s):  
Vinyl Alcohol ◽  
Water Sorption ◽  
Chemical Structure ◽  
Water Resistance ◽  
Nanocomposite Films ◽  
Poly Vinyl Alcohol ◽  
Structure And Morphology

scholarly journals Water Resistance of Photosensitive Poly(Vinyl Alcohol) Films.

2001 ◽  
Vol 14 (2) ◽  
pp. 293-294 ◽  
Author(s):  
Yoichi Shindo ◽  
Masatoshi Hasegawa ◽  
Junichi Kawanobe ◽  
Kazuo Inoue
Keyword(s):  
Vinyl Alcohol ◽  
Water Resistance ◽  
Poly Vinyl Alcohol

High barrier graphene oxide nanosheet/poly(vinyl alcohol) nanocomposite films

2012 ◽  
Vol 409-410 ◽  
pp. 156-163 ◽  
Author(s):  
Hua-Dong Huang ◽  
Peng-Gang Ren ◽  
Jun Chen ◽  
Wei-Qin Zhang ◽  
Xu Ji ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Vinyl Alcohol ◽  
Nanocomposite Films ◽  
Poly Vinyl Alcohol ◽  
Graphene Oxide Nanosheet

Novel pH-Sensitive Poly(Vinyl Alcohol) Based Polyampholyte as Pervaporation Membrane

2016 ◽  
Vol 852 ◽  
pp. 979-983
Author(s):  
Ping Rui Meng ◽  
Liang Bo Li
Keyword(s):  
Aqueous Solution ◽  
Vinyl Alcohol ◽  
Water Resistance ◽  
Graft Copolymerization ◽  
Sodium Acrylate ◽  
Poly Vinyl Alcohol ◽  
Permeate Flux ◽  
Ft Ir ◽  
Ethanol Aqueous Solution ◽  
Poly Acrylamide

Sodium acrylate (NaAA) and acrylamide (AM) were grafted onto poly (vinyl alcohol) (PVA) using potassium persulfate as an initiator, Graft copolymerization namely poly (vinyl alcohol)-g-poly (acrylamide/sodium acrylate) (PVA-g-PAM/SAC). The poly (vinyl alcohol)-g-poly (vinylamine/sodium acrylate) (PVAMC) was prepraed by Hofmann rearrangement.The PVAMC homogeneous membrane was characterized by fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM).The water resistance of the PVAMC membranes is the best when pH of the PVAMC solutions was 4, at that time the numbers of-NH3+ and-COO- groups trended to be equal, so the isoelectric point was pH=4. At 90 °C the pervaporation of PVAMC composite membrane was tested and showed that the separation factor and the permeate flux were about 1001 and 1341 g/(m2·h) for 90wt% ethanol aqueous solution, and they were about 1297 and 1040 g/(m2·h) for 90wt% isopropanol aqueous solution.

Properties of Poly(Vinyl Alcohol)/Chitosan Nanocomposite Films Reinforced with Oil Palm Empty Fruit Bunch Amorphous Lignocellulose Nanofibers

2018 ◽  
Vol 26 (8) ◽  
pp. 3316-3333 ◽  
Author(s):  
Achmad Solikhin ◽  
Yusuf Sudo Hadi ◽  
Muh Yusram Massijaya ◽  
Siti Nikmatin ◽  
Shigehiko Suzuki ◽  
...  
Keyword(s):  
Oil Palm ◽  
Vinyl Alcohol ◽  
Nanocomposite Films ◽  
Poly Vinyl Alcohol ◽  
Empty Fruit Bunch ◽  
Lignocellulose Nanofibers

Radiation – induced preparation of polyaniline/poly vinyl alcohol nanocomposites and their properties

2019 ◽  
Vol 107 (8) ◽  
pp. 725-735
Author(s):  
Hoda H. Saleh ◽  
Rehab Sokary ◽  
Zakaria I. Ali
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
High Resolution ◽  
Vinyl Alcohol ◽  
Oxidative Polymerization ◽  
Nanocomposite Films ◽  
Poly Vinyl Alcohol ◽  
Transmission Electron ◽  
Scanning Electron

Abstract Polyaniline (PANI) nanoparticles and PANI/poly vinyl alcohol (PVA) nanocomposite films were synthesized by the oxidative polymerization of aniline and ammonium peroxodisulfate (APS), as an oxidizing agent in aqueous medium. The PANI/PVA nanocomposite films were exposed to γ-irradiation after oxidative polymerization. Synthesized polyaniline (PANI) nanoparticles and PANI/PVA nanocomposite films were characterized by attenuated total reflectance infrared spectroscopy (FTIR-ATR), X-ray diffraction, high resolution scanning electron microscopy, (HRSEM) high resolution transmission electron microscopy, (HRTEM) and UV-VIS absorption spectroscopy. Energy band gap of PANI nanofibers was determined from Tauc’s plots which equal 4.2 eV. Scanning electron microscopy images show that chemically synthesized of polyaniline has nanofibers structure and irradiated PANI/PVA nanocomposite have a mixture of nanorod and nanosphere structures. The transmission electron microscopy show that chemically synthesized of polyaniline has average length in the range 34 ± 10 nm with less wide distribution, where as the irradiated PANI/PVA nanocomposite has coreshell structure.

Sign in / Sign up

Export Citation Format

Share Document