Asymmetric hydroformylation of vinyl acetate catalyzed by zeolite-supported gelatin-Co-Ru complex

2001 ◽  
Vol 12 (11-12) ◽  
pp. 693-696 ◽  
Author(s):  
Xi Zhang ◽  
Bing Han ◽  
Mei-Yu Huang ◽  
Ying-Yan Jiang
Keyword(s):  
Vinyl Acetate ◽  
Ru Complex ◽  
Asymmetric Hydroformylation

Asymmetric hydroformylation of vinyl acetate by use of chiral bis(triarylphosphite)-rhodium(I) complexes

1992 ◽  
Vol 3 (5) ◽  
pp. 583-586 ◽  
Author(s):  
Nozomu Sakai ◽  
Kyoko Nozaki ◽  
Kazushi Mashima ◽  
Hidemasa Takaya
Keyword(s):  
Vinyl Acetate ◽  
Asymmetric Hydroformylation

Asymmetric hydroformylation of vinyl acetate with DIOP-type ligands

1981 ◽  
Vol 46 (22) ◽  
pp. 4422-4427 ◽  
Author(s):  
Charles F. Hobbs ◽  
W. S. Knowles
Keyword(s):  
Vinyl Acetate ◽  
Asymmetric Hydroformylation

scholarly journals The Asymmetric Hydroformylation of Vinyl Acetate

1979 ◽  
Vol 52 (9) ◽  
pp. 2735-2736 ◽  
Author(s):  
Yoshihisa Watanabe ◽  
Take-aki Mitsudo ◽  
Yukio Yasunori ◽  
Junichi Kikuchi ◽  
Yoshinobu Takegami
Keyword(s):  
Vinyl Acetate ◽  
Asymmetric Hydroformylation

Asymmetric Hydroformylation of Vinyl Acetate:  Application in the Synthesis of Optically Active Isoxazolines and Imidazoles

2007 ◽  
Vol 9 (14) ◽  
pp. 2665-2668 ◽  
Author(s):  
P. J. Thomas ◽  
Alex T. Axtell ◽  
Jerzy Klosin ◽  
Wei Peng ◽  
Cynthia L. Rand ◽  
...  
Keyword(s):  
Vinyl Acetate ◽  
Optically Active ◽  
Asymmetric Hydroformylation

ChemInform Abstract: THE ASYMMETRIC HYDROFORMYLATION OF VINYL ACETATE

1980 ◽  
Vol 11 (1) ◽  
Author(s):  
Y. WATANABE ◽  
T. MITSUDO ◽  
Y. YASUNORI ◽  
J. KIKUCHI ◽  
Y. TAKEGAMI
Keyword(s):  
Vinyl Acetate ◽  
Asymmetric Hydroformylation

Inhibition of Radical-Initiated Vinyl Acetate Polymerisation by Tobacco Smoke Fractions

1974 ◽  
Vol 7 (5) ◽  
Author(s):  
M.A. Nisbet ◽  
S. Schmeller
Keyword(s):  
Benzoyl Peroxide ◽  
Vinyl Acetate ◽  
Tobacco Smoke ◽  
Boiling Point ◽  
Water Bath ◽  
Measuring Time ◽  
Time Required

AbstractBoth the vapour and particulate phases of tobacco smoke have been shown to retard benzoyI-peroxide-initiated polymerisation of vinyl acetate by interception of the radicals involved in the polymerisation process. The extent of inhibition of polymerisation by test compounds is estimated by measuring time taken for a mixture of monomer and benzoyl peroxide, immersed in a water-bath at 70°C, to reach a spontaneous boil and comparing it with the time required for a similar mixture with added retarder to reach boiling point. Units are expressed as minutes of inhibition per part per million of inhibitor × 10

Three-Phase Electrochemistry of a Highly Lipophilic Neutral Ru-Complex Having a Tridentate Bis(benzimidazolate)pyridine Ligand

2020 ◽  
Author(s):  
Vishwanath R.S ◽  
Masa-aki Haga ◽  
Takumi Watanabe ◽  
Emilia Witkowska Nery ◽  
Martin Jönsson-Niedziolka
Keyword(s):  
Redox Potential ◽  
Organic Phase ◽  
Electron Donor ◽  
Ion Transfer ◽  
Neutral Complex ◽  
Pyridine Ligand ◽  
Electrochemical Testing ◽  
Ru Complex ◽  
Three Phase ◽  
Exceptional Stability

Here we describe the synthesis and electrochemical testing of a heteroleptic bis(tridentate) ruthenium(II) complex [Ru<sup>II</sup>(LR)(L)]<sup>0</sup> (LR =2,6-bis(1-(2-octyldodecan)benzimidazol-2-yl)pyridine, L = 2,6-bis(benzimidazolate)pyridine). It is a neutral complex which undergoes a quasireversible oxidation and reduction at relatively low potential. The newly synthetized compound was used for studies of ion-transfer at the three-phase junction because of the sensitivity of this method to cation expulsion. The [Ru<sup>II</sup>(LR)(L)]<sup>0</sup> shows exceptional stability during cycling and is sufficiently lipophilic even after oxidation to persist in the organic phase also using very hydrophilic anions such as Cl<sup>−</sup>. Given its low redox potential and strong lipophilicity this compound will be of interest as an electron donor in liquid-liquid electrochemistry.

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