Quantum Chemical Investigation of Secondary Reactions in Poly(vinyl chloride) Free-Radical Polymerization

2012 ◽  
Vol 6 (8) ◽  
pp. 330-345 ◽  
Author(s):  
Danilo Cuccato ◽  
Marco Dossi ◽  
Davide Moscatelli ◽  
Giuseppe Storti
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Vinyl Chloride ◽  
Quantum Chemical ◽  
Free Radical Polymerization ◽  
Chemical Investigation ◽  
Quantum Chemical Investigation ◽  
Poly Vinyl Chloride ◽  
Secondary Reactions

Free radical polymerization of glycidyl methacrylate in plasticized Poly(vinyl chloride)

2008 ◽  
Vol 44 (10) ◽  
pp. 3177-3190 ◽  
Author(s):  
Carole Lainé ◽  
Véronique Bounor-Legaré ◽  
Christianne Monnet ◽  
Philippe Cassagnau
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Vinyl Chloride ◽  
Glycidyl Methacrylate ◽  
Free Radical Polymerization ◽  
Poly Vinyl Chloride

Ab Initio Study of Free-Radical Polymerization:  Defect Structures in Poly(vinyl chloride)

2007 ◽  
Vol 40 (4) ◽  
pp. 1321-1331 ◽  
Author(s):  
Karen Van Cauter ◽  
Bart J. Van Den Bossche ◽  
Veronique Van Speybroeck ◽  
Michel Waroquier
Keyword(s):  
Free Radical ◽  
Ab Initio ◽  
Radical Polymerization ◽  
Vinyl Chloride ◽  
Free Radical Polymerization ◽  
Defect Structures ◽  
Ab Initio Study ◽  
Poly Vinyl Chloride

A Comprehensive Kinetic Model for the Free-Radical Polymerization of Vinyl Chloride in the Presence of Monofunctional and Bifunctional Initiators

2004 ◽  
Vol 43 (20) ◽  
pp. 6382-6399 ◽  
Author(s):  
Apostolos Krallis ◽  
Costas Kotoulas ◽  
Stratos Papadopoulos ◽  
Costas Kiparissides ◽  
Jacques Bousquet ◽  
...  
Keyword(s):  
Free Radical ◽  
Kinetic Model ◽  
Radical Polymerization ◽  
Vinyl Chloride ◽  
Free Radical Polymerization ◽  
Bifunctional Initiators

scholarly journals The free radical polymerization of the vapours of certain vinyl derivatives

1946 ◽  
Vol 187 (1008) ◽  
pp. 37-53 ◽  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Vinyl Chloride ◽  
Free Radical Polymerization ◽  
Radical Mechanism ◽  
Methyl Radicals ◽  
Kinetic Methods ◽  
Free Radical Mechanism ◽  
Vinyl Derivatives ◽  
Styrene Butadiene

The free radical polymerization of the vapours of vinyl chloride, acrylic nitrile, styrene, butadiene and methyl isopropenyl ketone has been investigated using methyl radicals from photo-decomposing acetone. Although all the reactions do not exhibit ideal behaviour it is possible by the application of kinetic methods to measure the ratio of the propagation to the termination coefficients for these polymerization reactions. In this way relative values of the quantitative tendency for a molecule to polymerize by a free radical mechanism can be computed.

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